Catherine E. Hughes

Factors controlling stable isotope composition of precipitation in arid conditions: an observation network in the Tianshan Mountains, central Asia

Approximately one-third of the Earths arid areas are distributed across central Asia. The stable isotope composition of precipitation in this region is affected by its aridity, therefore subject to high evaporation and low precipitation amount. To investigate the factors controlling stable water isotopes in precipitation in arid central Asia, an observation network was established around the Tianshan Mountains in 2012. Based on the 1052 event-based precipitation samples collected at 23 stations during 2012–2013, the spatial distribution and seasonal variation of δD and δ18O in precipitation were investigated. The values of δD and δ18O are relatively more enriched in the rainfall dominant summer months (from April to October) and depleted in the drier winter months (from November to March) with low D-excess due to subcloud evaporation observed at many of the driest low elevation stations. The local meteoric water line (LMWL) was calculated to be δD=7.36δ18O – 0.50 (r2=0.97, p<0.01) based on the event-based samples, and δD=7.60δ18O+2.66 (r2=0.98, p<0.01) based on the monthly precipitation-weighted values. In winter, the data indicate an isotopic rain shadow effect whereby rainout leads to depletion of precipitation in the most arid region to the south of the Tianshan Mountains. The values of δ18O significantly correlate with air temperature for each station, and the best-fit equation is established as δ18O=0.78T – 16.01 (r2=0.73, p<0.01). Using daily air temperature and precipitation derived from a 0.5° (latitude)×0.5° (longitude) gridded data set, an isoscape of δ18O in precipitation was produced based on this observed temperature effect.

Evaporative isotope enrichment as a constraint on reach water balance along a dryland river

Abstract Deuterium and oxygen-18 enrichment in river water during its transit across dryland region is found to occur systematically along evaporation lines with slopes of close to 4 in 2H–18O space, largely consistent with trends predicted by the Craig–Gordon model for an open-water dominated evaporating system. This, in combination with reach balance assessments and derived runoff ratios, strongly suggests that the enrichment signal and its variability in the Barwon–Darling river, Southeastern Australia is acquired during the process of evaporation from the river channel itself, as enhanced by the presence of abundant weirs, dams and other storages, rather than reflecting inherited enrichment signals from soil water evaporation in the watershed. Using a steady-state isotope mass balance analysis based on monthly 18O and 2H, we use the isotopic evolution of river water to re-construct a perspective of net exchange between the river and its contributing area along eight reaches of the river during a drought period from July 2002 to December 2003, including the duration of a minor flow event. The resulting scenario, which uses a combination of climatological averages and available real-time meteorological data, should be viewed as a preliminary test of the application rather than as a definitive inventory of reach water balance. As expected for a flood-driven dryland system, considerable temporal variability in exchange is predicted. While requiring additional real-time isotopic data for operational use, the method demonstrates potential as a non-invasive tool for detecting and quantifying water diversions, one that can be easily incorporated within existing water quality monitoring activities.

Precipitation stable isotope variability and sub‐cloud evaporation processes in a semi‐arid region.

Cop Abstract: The stable isotopic (H/H and O/O) composition of precipitation has been used for a variety of hydrological and paleoclimate studies, a starting point for which is the behaviour of stable isotopes in modern precipitation. To this end, daily precipitation samples were collected over a 7-year period (2008–2014) at a semi-arid site located at the Macquarie Marshes, New South Wales (Australia). The samples were analysed for stable isotope composition, and factors affecting the isotopic variability were investigated. The best correlation between δO of precipitation was with local surface relative humidity. The reduced major axis precipitation weighted local meteoric water line was δH= 7.20 δO + 9.1. The lower slope and intercept (when compared with the Global Meteoric Water Line) are typical for a warm dry climate, where subcloud evaporation of raindrops is experienced. A previously published model to estimate the degree of subcloud evaporation and the subsequent isotopic modification of raindrops was enhanced to include the vertical temperature and humidity profile. The modelled results for raindrops of 1.0mm radius showed that on average, the measured D-excess (=δH 8 δO) was 19.8‰ lower than that at the base of the cloud, and 18% of the moisture was evaporated before ground level (smaller effects were modelled for larger raindrops). After estimating the isotopic signature at the base of the cloud, a number of data points still plotted below the global meteoric water line, suggesting that some of the moisture was sourced from previously evaporated water. Back trajectory analysis estimated that 38% of the moisture was sourced over land. Precipitation samples for which a larger proportion of the moisture was sourced over land were O and H-enriched in comparison to samples for which the majority of the moisture was sourced over the ocean. The most common weather systems resulting in precipitation were inland trough systems; however, only East Coast Lows contributed to a significant difference in the isotopic values. Copyright

Trench 'bathtubbing' and surface plutonium contamination at a legacy radioactive waste site.

Radioactive waste containing a few grams of plutonium (Pu) was disposed between 1960 and 1968 in trenches at the Little Forest Burial Ground (LFBG), near Sydney, Australia. A water sampling point installed in a former trench has enabled the radionuclide content of trench water and the response of the water level to rainfall to be studied. The trench water contains readily measurable Pu activity (∼12 Bq/L of 239+240Pu in 0.45 μm-filtered water), and there is an associated contamination of Pu in surface soils. The highest 239+240Pu soil activity was 829 Bq/kg in a shallow sample (0–1 cm depth) near the trench sampling point. Away from the trenches, the elevated concentrations of Pu in surface soils extend for tens of meters down-slope. The broader contamination may be partly attributable to dispersion events in the first decade after disposal, after which a layer of soil was added above the trenched area. Since this time, further Pu contamination has occurred near the trench-sampler within this added layer. The water level in the trench-sampler responds quickly to rainfall and intermittently reaches the surface, hence the Pu dispersion is attributed to saturation and overflow of the trenches during extreme rainfall events, referred to as the ‘bathtub’ effect.

Climate Change and Groundwater

Human civilisations have for millennia depended on the stability of groundwater resources to survive dry or unreliable climates. While groundwater supplies are buffered against short-term effects of climate variability, they can be impacted over longer time frames through changes in rainfall, temperature, snowfall, melting of glaciers and permafrost and vegetation and land-use changes. Groundwater provides an archive of past climate variation by recording changes in recharge amount or the chemical and isotopic evolutionary history of a groundwater system. For example, in the Sahara desert of North Africa, radiocarbon dating of groundwater shows that a highly arid climate prevailed during the last ice age followed by more humid conditions up until approximately 4000 years ago. In northern America and Europe, massive meltwater recharge of aquifers that occurred as a result of the same ice age approximately 15,000–20,000 years ago has left distinctive stable isotope signatures that remain today. The groundwater response to future climate change will be exacerbated by the heavy reliance that present day societies continue to place on groundwater, and the extensive modifications we have made to natural hydrological regimes. Models of groundwater response to climate change predict both increases and decreases in groundwater recharge and groundwater quality. Outcomes will be dependent on geographic location, and hydrological, biological and behavioural feedback mechanisms as natural systems and human civilisations struggle to cope with both climate change and our increasing demand for water.

Rainfall isotope variations over the Australian continent – Implications for hydrology and isoscape applications

This paper presents a continental scale interpretation of δ2H and δ18O in Australian precipitation, incorporating historical GNIP data at seven sites (1962-2002) and 8-12 years of new monthly data from 15 sites from 2003 to 2014. The more than doubling of stations and the significant time series duration allow for an improved analysis of Australian precipitation isotopes. Local meteoric water lines were developed for each site, and for the Australian continent. When the annual precipitation weighted values were used, the Australian meteoric water line was δ2H = 8.3 δ18O + 14.1‰. Precipitation amount was found to be a stronger driver of precipitation isotopes than temperature at most sites, particularly those affected by tropical cyclones and the monsoon. Latitude, elevation and distance from the coast were found to be stronger drivers of spatial variability than temperature or rainfall amount. Annual isoscapes of δ2H, δ18O and deuterium excess were developed, providing an improved tool to estimate precipitation isotope inputs to hydrological systems. Because of the complex climate, weather and oceanic moisture sources affecting Australia, regional groupings were used instead of the climate zone approach and additional data was included to improve the coverage in data poor regions. Regression equations for the isoscape were derived using latitude, altitude and distance from the coast as predictor variables. We demonstrate how this isoscape can be used as a tool for interpreting groundwater recharge processes using examples from across Queensland and New South Wales, including the Murray Darling Basin. Groundwater isotopes at sites where direct local recharge occurs are similar to rainfall, but for inland sites, which are often arid or semi-arid, a disconnect between shallow groundwater and local rainfall is observed; the departure in deuterium excess for these sites increases with aridity and distance from the headwaters where flooding originates.

Measurement of tributyl phosphate (TBP) in groundwater at a legacy radioactive waste site and its possible role in contaminant mobilisation

At many legacy radioactive waste sites, organic compounds have been co-disposed, which may be a factor in mobilisation of radionuclides at these sites. Tri-butyl phosphate (TBP) is a component of waste streams from the nuclear fuel cycle, where it has been used in separating actinides during processing of nuclear fuels. Analyses of ground waters from the Little Forest Legacy Site (LFLS) in eastern Australia were undertaken using solid-phase extraction (SPE) followed by gas chromatographic mass spectrometry (GCMS). The results indicate the presence of TBP several decades after waste disposal, with TBP only being detected in the immediate vicinity of the main disposal area. TBP is generally considered to degrade in the environment relatively rapidly. Therefore, it is likely that its presence is due to relatively recent releases of TBP, possibly stemming from leakage due to container degradation. The ongoing presence and solubility of TBP has the potential to provide a mechanism for nuclide mobilisation, with implications for long term management of LFLS and similar legacy waste sites.

Nuclear Techniques for Monitoring Sediment Dynamics in the Coastal Zone

The knowledge of sediment transport in the coastal region is of vital importance to the management of this critical interface between land and sea, where most of the world population lives. For the assessment of sediment behaviour, hydraulic and sediment measurements, bathymetric survey, mathematical and physical models, are applied. Sediment tracers provide a unique capability for understanding sediment transport assisting in sediment management which cannot be obtained any other way, whether conventional monitoring or physical and numerical models because tracers integrate all the hydrodynamic actions in time and space. Computational fluid dynamics (CFD) is now an essential tool for the management of the natural systems and is increasingly used to study the fate and behaviour of particulates and contaminants. Tracer techniques are often employed to validate hydrodynamic models to enhance confidence in the predictive value of the models. In-situ detection afforded by the use of a radioactive tracer allows accurate quantitative determination of the rate of sediment transport, compared with other tracer methods. Also, it is cost effective and safe: its radiological impact to the environment is minimal. Several case studies, performed in different regions of the world, are presented.