Cecilio Quesada

Origin of the Rheic Ocean: Rifting along a Neoproterozoic suture?

The Rheic Ocean is widely believed to have formed in the Late Cambrian–Early Ordovician as a result of the drift of peri-Gondwanan terranes, such as Avalonia and Carolina, from the northern margin of Gondwana, and to have been consumed in the Devonian Carboniferous by continent-continent collision during the formation of Pangea. Other peri-Gondwanan terranes (e.g., Armorica, Ossa-Morena, northwest Iberia, Saxo-Thuringia, Moldanubia) remained along the Gondwanan margin at the time of Rheic Ocean formation. Differences in the Neoproterozoic histories of these peri-Gondwanan terranes suggest the location of the Rheic Ocean rift may have been inherited from Neoproterozoic lithospheric structures formed by the accretion and dispersal of peri-Gondwanan terranes along the northern Gondwanan margin prior to Rheic Ocean opening. Avalonia and Carolina have Sm-Nd isotopic characteristics indicative of recycling of a juvenile ca. 1 Ga source, and they were accreted to the northern Gondwanan margin prior to voluminous late Neoproterozoic arc magmatism. In contrast, Sm-Nd isotopic characteristics of most other peri-Gondwanan terranes closely match those of Eburnian basement, suggesting they reflect recycling of ancient (2 Ga) West African crust. The basements of terranes initially rifted from Gondwana to form the Rheic Ocean were those that had previously accreted during Neoproterozoic orogenesis, suggesting the rift was located near the suture between the accreted terranes and cratonic northern Gondwana. Opening of the Rheic Ocean coincided with the onset of subduction beneath the Laurentian margin in its predecessor, the Iapetus Ocean, suggesting geodynamic linkages between the destruction of the Iapetus Ocean and the creation of the Rheic Ocean.

Neoproterozoic - early Palaeozoic tectonostratigraphy and palaeogeography of the peri-Gondwanan terranes: Amazonian v. West African connections

Abstract Within the Appalachian–Variscan orogen of North America and southern Europe lie a collection of terranes that were distributed along the northern margin of West Gondwana in the late Neoproterozoic and early Palaeozoic. These peri-Gondwanan terranes are characterized by voluminous late Neoproterozoic (c. 640–570 Ma) arc magmatism and cogenetic basins, and their tectonothermal histories provide fundamental constraints on the palaeogeography of this margin and on palaeocontinental reconstructions for this important period in Earth history. Field and geochemical studies indicate that arc magmatism generally terminated diachronously with the formation of a transform margin, leading by the Early–Middle Cambrian to the development of a shallow-marine platform–passive margin characterized by Gondwanan fauna. However, important differences exist between these terranes that constrain their relative palaeogeography in the late Neoproterozoic and permit changes in the geometry of the margin from the late Neoproterozoic to the Early Cambrian to be reconstructed. On the basis of basement isotopic composition, the terranes can be subdivided into: (1) Avalonian-type (e.g. West Avalonia, East Avalonia, Meguma, Carolinia, Moravia–Silesia), which developed on juvenile, c. 1.3–1.0 Ga crust originating within the Panthalassa-like Mirovoi Ocean surrounding Rodinia, and which were accreted to the northern Gondwanan margin by c. 650 Ma; (2) Cadomian-type (e.g. North Armorican Massif, Ossa–Morena, Saxo-Thuringia, Moldanubia), which formed along the West African margin by recycling ancient (c. 2.0–2.2 Ga) West African crust; (3) Ganderian-type (e.g. Ganderia, Florida, the Maya terrane and possible the NW Iberian domain and South Armorican Massif), which formed along the Amazonian margin of Gondwana by recycling Avalonian and older Amazonian basement; and (4) cratonic terranes (e.g. Oaxaquia and the Chortis block), which represent displaced Amazonian portions of cratonic Gondwana. These contrasts imply the existence of fundamental sutures between these terranes prior to c. 650 Ma. Derivation of the Cadomian-type terranes from the West African craton is further supported by detrital zircon data from their Neoproterozoic–Ediacaran clastic rocks, which contrast with such data from the Avalonian- and Ganderian-type terranes that suggest derivation from the Amazonian craton. Differences in Neoproterozoic and Ediacaran palaeogeography are also matched in some terranes by contrasts in Cambrian faunal and sedimentary provenance data. Platformal assemblages in certain Avalonian-type terranes (e.g. West Avalonia and East Avalonia) have cool-water, high-latitude fauna and detrital zircon signatures consistent with proximity to the Amazonian craton. Conversely, platformal assemblages in certain Cadomian-type terranes (e.g. North Armorican Massif, Ossa–Morena) show a transition from tropical to temperate waters and detrital zircon signatures that suggest continuing proximity to the West African craton. Other terranes (e.g. NW Iberian domain, Meguma) show Avalonian-type basement and/or detrital zircon signatures in the Neoproterozoic, but develop Cadomian-type signatures in the Cambrian. This change suggests tectonic slivering and lateral transport of terranes along the northern margin of West Gondwana consistent with the transform termination of arc magmatism. In the early Palaeozoic, several peri-Gondwanan terranes (e.g. Avalonia, Carolinia, Ganderia, Meguma) separated from West Gondwana, either separately or together, and had accreted to Laurentia by the Silurian–Devonian. Others (e.g. Cadomian-type terranes, Florida, Maya terrane, Oaxaquia, Chortis block) remained attached to Gondwana and were transferred to Laurussia only with the closure of the Rheic Ocean in the late Palaeozoic.

Geodynamic setting and geochemical signatures of Cambrian–Ordovician rift-related igneous rocks (Ossa-Morena Zone, SW Iberia)

Abstract An important rifting event, accompanied by massive igneous activity, is recorded in the Ossa-Morena Zone of the SW Iberian Massif (European Variscan Orogen). It likely culminated in the formation of a new oceanic basin (Rheic ocean?), remnants of which appear presently accreted at the southern margin of the Ossa-Morena Zone. Rifting propagated diachronously across the zone from the Early Cambrian to the Late Ordovician, but by Early Ordovician time, the existence of a significant tract of new ocean is evidenced by a breakup unconformity. Although early stages of rifting were not accompanied by mantle-derived igneous activity, a pronounced increase of the geothermal gradient is indicated by partial melting of metasedimentary protoliths in the upper and middle crust, and by coeval core-complex formation. Geochemistry of the main volume of igneous rocks, emplaced some million years later during more mature stages of rifting, suggests an origin in a variably enriched asthenospheric source, similar to that of many OIB, from which subsequent petrogenetic processes produced a wide range of compositions, from basalt to rhyolite. A tectonic model involving collision with, and subsequent overriding of, a MOR is proposed to account for the overall evolution, a present-day analogue for which lies in the overriding of the East Pacific Rise by North America and the rifting of Baja California.

Electromagnetic imaging of Variscan crustal structures in SW Iberia: the role of interconnected graphite

Abstract The western part of the Iberian Peninsula (Iberian Massif) is the best exposed fragment of the Variscan orogen in Europe. Its southern half was generated by an oblique collision between three continental terranes belonging to the margins of Laurassia (Avalonia) – the South Portuguese Zone (SPZ) – and Gondwana – the Ossa Morena Zone (OMZ) and the Central Iberian Zone (CIZ). The boundaries between them are considered to be suture zones. A 200 km long magnetotelluric profile across the three Variscan terranes was done in a NNE direction, approximately perpendicular to the main tectonic features. The results of two-dimensional inversion of the MT dataset reveal high-conductivity zones coinciding with the transitions SPZ/OMZ and OMZ/CIZ. These conductive bodies related to the sutures at depth were interpreted as graphite enrichments along shear planes formed due to the overall transpressive regime. A high-conductivity layer extending along the whole OMZ was found at a depth of 15–25 km, the top of which spatially correlates with a broad reflector detected by a recently acquired deep seismic reflection profile. The high conductivity was interpreted as caused by the Precambrian Serie Negra graphite-rich rocks. Carbon and oxygen X-ray mapping with electron microprobe on polished sections of Serie Negra samples from OMZ revealed the presence of interconnected graphite, which supports the hypothesis that graphite is determinant for the high conductivity. Two graphite types, which help to record the geological evolution, were identified: graphite accumulations in the schistosity surfaces produced by folding and metamorphism, and metallic films of graphite developed along late faults. The conductive layer shows blobs of higher conductivity suggesting macro-anisotropy. Additional mylonitisation and shearing produced by thrusting at depth can be the origin of these zones of enhanced conductivity, given that the detachment level is located within the Serie Negra. Several high-resistivity features were found in the upper crust, related to Devonian and Carboniferous successions and probably to some unexposed plutons in the SPZ and the Palaeozoic series of OMZ plus some granitic intrusions. In the CIZ, a high-resistivity zone extending to the whole crust is correlated with extensive late Variscan granite intrusions.

Tectonothermal evolution of the Badajoz-Cordóba shear zone (SW Iberia): characteristics and 40Ar/39Ar mineral age constraints

Field characteristics indicate that the Badajoz-Cordoba shear zone has had a long, polyphase tectonothermal evolution. 40Ar/39Ar cooling ages recorded within central, ductile sectors of the Badajoz-Cordoba shear zone range from ca. 370 to 360 Ma (amphibole) and 340 to 330 Ma (muscovite). These are interpreted to date post-metamorphic cooling through contrasting temperatures required for intracrystalline retention of argon following a regionally significant Variscan tectonothermal overprint. These results combined with field relationships indicate that the Badajoz-Cordoba shear zone experienced at least 15 km of uplift relative to adjacent areas during late Paleozoic sinistral transpression. The data also indicate that individual structural units within the shear zone experienced contrasting uplift histories (both in total amount and rate). The 40Ar/39Ar cooling ages indicate complete Variscan rejuvenation of all older intracrystalline argon systems within central sectors of the Badajoz-Cordoba shear zone.

Tectonic escape of a crustal fragment during the closure of the Rheic Ocean: U–Pb detrital zircon data from the Late Palaeozoic Pulo do Lobo and South Portuguese zones, southern Iberia

Abstract: The Pulo do Lobo Zone, which crops out immediately north of the allochthonous South Portuguese Zone in southern Iberia, is classically interpreted as a polydeformed accretionary complex developed along the southern margin of the Gondwanan parautochthon (Ossa–Morena Zone), during the late Palaeozoic closure of the Rheic Ocean. This closure was a major event during the amalgamation of Pangaea. U–Pb laser ablation inductively coupled mass spectrometry dating of detrital zircons from late Palaeozoic Devono-Carboniferous clastic units in the South Portuguese Zone and Pulo do Lobo Zone yield contrasting age populations and attest to the exotic nature of both zones. Detrital zircons from the South Portuguese Zone display populations typical of detritus derived from either Gondwana (Ossa–Morena Zone), or peri-Gondwanan terranes. In contrast, rocks from the Pulo do Lobo Zone contain populations consistent with derivation from Baltica, Laurentia or recycled early Silurian deposits along the Laurentian margin. An example of one such deposit is the Southern Uplands terrane of the British Caledonides. Taken together, these data can be reconciled by a model involving tectonic transport of a crustal fragment that was laterally equivalent to the Southern Uplands terrane between the allochthonous South Portuguese Zone and Gondwana as a result of an early Devonian collision between an Iberian indenter with Laurussia. Supplementary material: U–Pb data tables, concordia diagrams, methods and representative back-scattered electron images are available at http://www.geolsoc.org.uk/SUP18441.

U-Pb age constraints on Variscan magmatism and Ni-Cu-PGE metallogeny in the Ossa-Morena Zone (SW Iberia)

New U–Pb zircon ages from the Santa Olalla Igneous Complex have been obtained, which improve the knowledge of the precise timing of Variscan magmatism in the Ossa–Morena Zone, SW Iberia. This complex has a special relevance as it hosts the most important Ni–Cu–platinum group element (PGE) mineralization in Europe: the Aguablanca deposit. U–Pb zircon ages have been obtained for seven samples belonging to the Santa Olalla Igneous Complex and spatially related granites. With the exception of the Cala granite (352 ± 4 Ma), which represents an older intrusion, the bulk of samples yield ages that cluster around 340 ± 3 Ma: the Santa Olalla tonalite (341.5 ± 3 Ma), the Sultana hornblende tonalite (341 ± 3 Ma), a mingling area at the contact between the Aguablanca and Santa Olalla stocks (341 ± 1.5 Ma), the Garrote granite (339 ± 3 Ma), the Teuler granite (338 ± 2 Ma), and dioritic dykes from the Aguablanca stock (338.6 ± 0.8 Ma). The Bodonal–Cala porphyry, which has also been dated (530 ± 3 Ma), comprises a group of sub-volcanic rhyolitic intrusions belonging to the Bodonal–Cala volcano-sedimentary complex, which hosts the igneous rocks. The knowledge that emplacement of the Aguablanca deposit was related to episodic transtensional tectonic stages during the Variscan orogeny will be fundamental in future mineral exploration in the Ossa–Morena Zone.

Precambrian successions in SW Iberia: their relationship to ‘Cadomian’ orogenic events

Abstract Despite extensive reworking in Devonian and Carboniferous times, two major deformational events taking place in late Precambrian times may be recognized in the SW Iberian Massif. These have been collectively referred to as ‘Cadomian’ or ‘Pan-African’. The Precambrian successions may be subdivided into pre-orogenic and syn-orogenic groups on the basis of their tectonostratigraphic evolution with respect to the Cadomian orogeny. The pre-orogenic successions (roughly mid-upper Riphean) represent different parts of a miogeoclinal wedge, the basement of which is not known as yet. Polyphase deformation and variable degrees of metamorphism accompanied the first Cadomian event. The syn-orogenic successions (roughly upper Riphean-Vendian) were laid down during and after the first Cadomian event and were in turn deformed and slightly metamorphosed by the second single-phased deformation. These correspond to two distinct types: calc-alkaline igneous successions and flysch-like deposits, that can be interpreted respectively as an orogenic continental arc suite and a foreland basin fill, on the basis of their geochemical and sedimentological characteristics.

Origin and emplacement of the Aguablanca magmatic Ni-Cu-(PGE) sulfide deposit, SW Iberia: A multidisciplinary approach

A model is proposed for the origin and emplacement of the ca. 341 Ma Aguablanca magmatic Ni-Cu-(platinum group element [PGE]) sulfi de deposit (SW Iberia) integrating petrological, geochemical, structural, and geophysical data. The Aguablanca deposit occurs in an unusual geodynamic context for this ore type (an active plate margin) as an exotic , magmatic subvertical breccia located at the northern part of the coeval gabbronorite Aguablanca stock (341 ± 1.5 Ma). Structural and gravity data show that mineralized breccia occurs inside the inferred feeder zone for the stock adjacent to the Cherneca ductile shear zone, a Variscan sinistral transpressional structure. The orientation of the feeder zone corresponds to that expected for tensional fractures formed within the strain fi eld of the adjacent Cherneca ductile shear. Two distinctive stages are established for the origin and emplacement of the deposit: (1) initially, the ore-forming processes are attributed to magma emplacement in the crust, assimilation of crustal S, and segregation and gravitational settling of sulfi de melt (a scenario similar to most plutonic Ni-Cu sulfi de ores), and (2) fi nal emplacement of the Ni-Cu sulfi de-bearing rocks by multiple melt injections controlled by successive opening events of tensional fractures related to the Cherneca ductile shear zone.

Rheic Ocean mafic complexes: overview and synthesis

Abstract The Rheic Ocean formed during the Late Cambrian–Early Ordovician when peri-Gondwanan terranes (e.g. Avalonia) drifted from the northern margin of Gondwana, and was consumed during the collision between Laurussia and Gondwana and the amalgamation of Pangaea. Several mafic complexes, from the Acatlán Complex in Mexico to the Bohemian Massif in eastern Europe, have been interpreted to represent vestiges of the Rheic Ocean. Most of these complexes are either Late Cambrian–Early Ordovician or Late Palaeozoic in age. Late Cambrian–Early Ordovician complexes are predominantly rift-related continental tholeiites, derived from an enriched c. 1.0 Ga subcontinental lithospheric mantle, and are associated with crustally-derived felsic volcanic rocks. These complexes are widespread and virtually coeval along the length of the Gondwanan margin. They reflect magmatism that accompanied the early stages of rifting and the formation of the Rheic Ocean, and they remained along the Gondwanan margin to form part of a passive margin succession as Avalonia and other peri-Gondwanan terranes drifted northward. True ophiolitic complexes of this age are rare, a notable exception occurring in NW Iberia where they display ensimatic arc geochemical affinities. These complexes were thrust over, or extruded into, the Gondwanan margin during the Late Devonian–Carboniferous collision between Gondwana and Laurussia (Variscan orogeny). The Late Palaeozoic mafic complexes (Devonian and Carboniferous) preserve many of the lithotectonic and/or chemical characteristics of ophiolites. They are characterized by derivation from an anomalous mantle which displays time-integrated depletion in Nd relative to Sm. Devonian ophiolites pre-date closure of the Rheic Ocean. Although their tectonic setting is controversial, there is a consensus that most of them reflect narrow tracts of oceanic crust that originated along the Laurussian margin, but were thrust over Gondwana during Variscan orogenesis. The relationship of the Carboniferous ophiolites to the Rheic Ocean sensu stricto is unclear, but some of them apparently formed in a strike-slip regimes within a collisional setting directly related to the final stages of the closure of the Rheic Ocean.