Céline Duwig

Uptake of arsenic by New Zealand watercress (Lepidium sativum).

Watercress (Lepidium sativum) is consumed as a vegetable, especially by the indigenous community in New Zealand. An investigation was carried out on the accumulation of arsenic by watercress, following earlier reports of inordinate arsenic concentrations in some aquatic macrophytes collected from the Waikato River, North Island, New Zealand. The Waikato River and some other aquatic systems in Taupo Volcanic Zone, New Zealand have elevated arsenic concentrations due to geothermal activity. Watercress, river water and sediment samples were collected from 27 sites along the Waikato river and analysed for arsenic. Greenhouse trials with watercress grown in beakers containing added arsenic were conducted to confirm the ability of this species to accumulate arsenic. At a number of sites, the concentration of arsenic in both the water and the watercress samples exceeded the World Health Organisation (WHO) limit for drinking water (0.01 mg l(-1)) and foodstuffs (2 mg kg(-1) on a fresh weight basis). The average leaf and stem arsenic concentrations were, respectively, 29.0 and 15.9 mg kg(-1) on a fresh weight basis. Plants grown in solutions of >0.4 mg l(-1) arsenic concentration had fresh weight arsenic concentrations above the WHO limit. Despite these higher concentrations, arsenic levels in plants grown under greenhouse conditions were approximately fivefold lower than in plants growing in the Waikato River, possibly because under natural conditions, the watercress is rooted in sediment containing on average approximately 35 mg kg(-1) arsenic. It is recommended that watercress from the Waikato River, or other areas with elevated water arsenic concentrations, should not be consumed.

Mineralogical, chemical and charge properties of Geric Ferralsols from New Caledonia

The mineralogical, chemical and surface charge properties of Geric Ferralsols of New Caledonia were examined. These soils, which corresponded to two soil mantles formed either on ultramafic rocks or volcanic ejecta and ashes, were respectively dominated by iron and aluminium oxides. The electric charge characteristics were studied by measuring retention of Ca (2+) and Cl- different pH values ranging from 3 to 7. The cation exchange capacity (CEC,) increased with soil organic carbon and pH and varied from 0 to 35 cmol(c) kg(-1) soil. The anion exchange capacity (AEC) reached 4.25 cmol(c) kg(-1) soil in Bo horizons at pH 4. The magnitude of the CECT and AEC variations was modelled according to CECT = 10(a1pH) * 10(B1) and AEC = - 10(a2pH) * 10(B2). Parameters a(1) and a(2) were low for samples with high organic carbon (from 0.10 to 0.19 and from - 0.44 to - 0.66, respectively) and could increase to 1.25 and - 0.39, respectively, when organic carbon content decreased. The parameters a(1) and a(2) could be also useful to regroup soil types according to the nature of the properties that can be manipulated for their management

Nitrate leaching through oxisols of the Loyalty Islands (New Caledonia) under intensified agricultural practices

For the uplifted coral atolls of the Loyalty Islands (New Caledonia), the prime source of potable water is the freshwater lenses that underlie the islands. The recent adoption of more-intensive agricultural practices, particularly the use of nitrogeneous fertilizers, may, however, represent a threat for these fragile Pacific ecosystems. To assess the risk posed by nitrate leaching, experiments have been conducted on the permeable oxisols of the island of Mare, using both cropped and bare soil sites. Drainage below the root zone was found to be very important, about 50% of the rainfall, even on the cropped site. The soils are thin and permeable, and the frequent tropical storms have high rainfall intensities. Nitrate fertilizers thus have potential to be leached, in large amounts, even up to 100% of the nitrate supply, especially if fertilizers are not supplied according to weather conditions and in concert with the plants ability to extract them.

Measuring transient solute transport through the vadoze zone using time domain reflectometry

Time domain reflectometry (TDR) was used to monitor the transport of conservative tracers in the field under transient water flow in a controlled experiment under a kiwifruit vine. A mixed pulse of chloride and bromide was applied to the soil surface of a 16 m2 plot that had been isolated from the surrounding orchard soil. The movement of this solute pulse was monitored by TDR. A total of 63 TDR probes were installed into the plot for daily measurements of both the volumetric water content (θ) and the bulk soil electrical conductivity (σa). These TDR-measured σa were converted into pore water electrical conductivities (σw) and solute concentrations using various θ–σa–σw relationships that were established in the laboratory on repacked soil. The depth-wise field TDR measurements were compared with destructive measurement of the solute concentrations at the end of the experiment. These results were also compared with predictions using a deterministic model of water and solute transport based on Richards’ equation, and the convection–dispersion equation. TDR was found to give a good indication of the shape of the solute profile with depth, but the concentration of solute was under- or over-estimated by up to 50%, depending on the θ–σa–σw relationships used. Thus TDR can be used to monitor in situ transport of contaminants. However, only rough estimates of the electrical conductivity of the soil solution can so far be obtained by TDR.

Nitrate Sorption in a Mexican Allophanic Andisol using Intact and Packed Columns

Abstract Contamination of groundwater by nitrate is a worldwide environmental issue. A better knowledge of nitrate sorption characteristics by soils contributes to efficient fertilizer use and prevents aquifer contamination. In volcanic soils, nitrate sorption is induced by variable charges due to the presence of amorphous materials and aluminum (Al) and iron (Fe) oxides. Anion transport in packed and intact columns was investigated in a Mexican Allophanic Andisol, under different permanent flow regimes in unsaturated conditions and several NO3 −‐N and Br− input concentrations. In the packed columns, the NO3 −‐N adsorption in the soil was nonlinear. In the intact columns, the retardation coefficient variation was directly correlated to the increase of amorphous material with depth. The presence of preferential flow in the intact columns significantly increased the mobility and velocity of nitrate moving through the columns, whereas in the packed columns, NO3 −‐N fate was only affected by soil chemical composition and mineralogy.

How Uncontrolled Urban Expansion Increases the Contamination of the Titicaca Lake Basin (El Alto, La Paz, Bolivia)

Cities in developing countries encounter rapid waves of social transformation and economic development where the environment is mostly a neglected aspect. The Katari watershed encompasses mining areas, El Alto city (one of the fastest growing urban areas in South America and the biggest in the Altiplano) as well as agricultural areas. Its outlet is Cohana Bay, one of the most polluted areas of Lake Titicaca. Here we propose an integrative approach (hydrological, physicochemical, chemical and bacterial data) to understand the pollution problem of this developing area, in which a variety of anthropogenic activities takes place. Both mining and urban areas appear to be sources of metal pollution. Nutrient and bacterial contaminations are mainly related to urban and industrial discharges. These situations have impacts in the basin from the mining area down to Cohana Bay of Lake Titicaca. Pollutant concentration patterns are highly influenced by seasonal hydrology variations. The poor quality of surface waters in the basin represents a risk for human and animal populations, as well as for the quality of aquifers located underneath El Alto city.

Biotic nitrosation of diclofenac in a soil aquifer system (Katari watershed, Bolivia)

Up till now, the diclofenac (DCF) transformation into its nitrogen-derivatives, N-nitroso-DCF (NO-DCF) and 5-nitro-DCF (NO2-DCF), has been mainly investigated in wastewater treatment plant under nitrification or denitrification processes. This work reports, for the first time, an additional DCF microbial mediated nitrosation pathway of DCF in soil under strictly anoxic conditions probably involving codenitrification processes and fungal activities. This transformation pathway was investigated by using field observations data at a soil aquifer system (Katari watershed, Bolivia) and by carrying out soil slurry batch experiments. It was also observed for diphenylamine (DPA). Field measurements revealed the occurrence of NO-DCF, NO2-DCF and NO-DPA in groundwater samples at concentration levels in the 6-68s/L range. These concentration levels are more significant than those previously reported in wastewater treatment plant effluents taking into account dilution processes in soil. Interestingly, the p-benzoquinone imine of 5-OH-DCF was also found to be rather stable in surface water. In laboratory batch experiments under strictly anoxic conditions, the transformation of DCF and DPA into their corresponding N-nitroso derivatives was well correlated to denitrification processes. It was also observed that NO-DCF evolved into NO2-DCF while NO-DPA was stable. In vitro experiments showed that the Fisher-Hepp rearrangement could not account for NO2-DCF formation. One possible mechanism might be that NO-DCF underwent spontaneous NO loss to give the resulting intermediates diphenylaminyl radical or nitrenium cation which might evolve into NO2-DCF in presence of NO2 radical or nitrite ion, respectively.

2,4‐D Movement in Allophanic Soils from Two Contrasting Climatic Regions

Abstract Allophanic top‐ and subsoils from the Mexican and Newzealand Central Volcanic Plateau, as well as a nonallophanic sandy loam soil, were sampled to study the impact of organic matter and allophane content on 2,4‐D fate. High sorption rates were found, especially in the two topsoils from Mexico and New Zealand, with distribution coefficient (K d ) obtained from displacement experiments in packed columns equal to 7.61 and 8.43 L kg−1 respectively. 2,4‐Dichlorophenoxyacetic acid transfer through the soil columns was found to be in chemical nonequilibrium and was well predicted using a two‐site sorption model. For the two allophanic top soils, K d obtained from batch was very different to the K d obtained from column experiments. Either the equilibrium could not be reached in batch or the two‐site model was not able to describe the wide range of sorption sites present in the highly reactive organic matter and allophane components.

Visualization and Characterization of Heterogeneous Water Flow in Double-Porosity Media by Means of X-ray Computed Tomography

Three-dimensional visualization of dynamic water transport process in soil by computed tomography (CT) technique is still limited by its low temporal resolution. In order to monitor dynamically water transport in soil, a compromise has to be found between water flow velocity and CT acquisition time. Furthermore, an efficient image analysis method is necessary. In this work, we followed the water transport in three dimensions by CT imaging across a double-porosity media constituted of two distinct materials, i.e. sand and porous clay spheres. The CT acquisition parameters were adjusted to the water pore velocity so that we succeeded to register the water front displacement per time range of 25 min. We also used the image subtraction method to extract water distribution evolution with time with a space resolution of