Chan Min Yoo

Origin and modification of early dolomites in cyclic shallow platform carbonates, Yeongheung Formation (middle Ordovician), Korea

Abstract The middle Ordovician Yeongheung Formation, Korea, consists of numerous metre-scale, shallowing-upward cycles, which were deposited on a shallow-marine carbonate platform. Depositional sequences developed on the inner platform were completely dolomitized regardless of constituting lithology, whereas those developed on the outer platform were partially dolomitized. The amount of replacement dolomite within a metre-scale, shallowing-upward peritidal cycle decreases downward from the peritidal cycle cap in the partially dolomitized depositional sequences. The cross-platform distribution of dolomites and their stratigraphic position in the sequences suggest that the Yeongheung dolomite formed syndepositionally. The common existence of pseudomorphs of evaporite minerals and nodules in the Yeongheung Formation indicates that dolomitization of the Yeongheung Formation occurred in a sabkha-type tidal-flat environment. It also occurred during each cycle of deposition influenced by high-frequency sea-level oscillations. The present-day Yeongheung replacement dolomites are characterized by near-stoichiometric to stoichiometric composition (49.9 to 52.1 CaCO3 mole%), and low strontium concentration (52 to 133 ppm). The δ18O value of the replacement dolomites ranges from −7.7 to −5.2‰ (PDB); this is much depleted relative to that of contemporary sabkha-type dolomites. These geochemical characteristics of Yeongheung dolomite indicate significant post-depositional modification. The common existence of oomolds, leached skeletal grains and dissolved evaporites in the Yeongheung Formation illustrates invasion of meteoric water into the sediments. Recrystallization of Yeongheung dolomites in the infiltrated meteoric water at slightly elevated temperatures during shallow burial resulted in lighter δ18O values and lower strontium concentration.

Sr‐Nd isotope composition and clay mineral assemblages in eolian dust from the central Philippine Sea over the last 600 kyr: Implications for the transport mechanism of Asian dust

Dust transport to the tropical/subtropical northwestern Pacific over the past 600 kyr was investigated using radiogenic isotopes (87Sr/86Sr and eNd), together with the clay mineral composition, of eolian dust preserved in a sediment core obtained from the Philippine Sea (12°30′N, 134°60′E). These data revealed the influence of two prevailing dust sources, namely, the Asian deserts and nearby volcanic arcs (e.g., the Luzon Arc), with average contributions of around 70% and 30%, respectively, from each. The clay mineral composition of the core resembled dust from the central Asian deserts (CADs; e.g., the Taklimakan Desert) as in the north-central Pacific, but published aerosol data collected near the study site during winter/spring have the mineralogical signature of dust originating from the East Asian deserts (EADs). These data indicate that the relative contribution of EAD dust increases with the northeasterly surface winds associated with the East Asian Winter Monsoon (EAWM) during winter/spring, but the Prevailing Westerlies and Trade Winds that carry dust from the CADs is the dominant transport agent in the overall dust budget of the study site. The results of this study contradict the prevailing view that direct dust transport by the EAWM winds in spring dominates the annual flux of eolian dust in the northwest Pacific.

Cyclic sedimentation across a Middle Ordovician carbonate ramp (Duwibong Formation), Korea

SummaryThe Middle Ordovician Duwibong Formation (about 100 m thick), Korea, comprises various lithotypes deposited across a carbonate ramp. Their stacking patterns constitute several kinds of meter-scale, shallowing-upward carbonate cycles. Lithofacies associations are grouped into four depositional facies: deep- to mid-ramp, shoal-complex, lagoonal, and tidal-flat facies. These facies are composed of distinctive depositional cycles: deep subtidal, shallow subtidal, restricted marine, and peritidal cycles, respectively. The subtidal cycles are capped by subtidal lithofacies and indicate incomplete shallowing to the peritidal zone. The restricted marine and peritidal cycles are capped by tidal flat lithofacies and show evidence of subaerial exposure. These cycles were formed by higher frequency sea-level fluctuations with durations of 120 ky (fifth order), which were superimposed on the longer term sea-level events, and by sediment redistribution by storm-induced currents and waves. The stratigraphic succession of the Duwibong Formation represents a general regressive trend. The vertical facies change records the transition from a deep- to mid-ramp to shoal, to lagoon, into a peritidal zone. The depositional system of the Duwibong Formation was influenced by frequent storms, especially on the deep ramp to mid-ramp seaward of ooid shoals. The storm deposits comprise about 20% of the Duwibong sequence.

Depositional cyclicity of the Middle Ordovician Yeongheung Formation, Korea

The Middle Ordovician Yeongheung Formation consists of numerous meter-scale, shallowing-upward cycles, which were deposited on a shallow-marine carbonate platform. Two types of shallowing-upward cycles, peritidal and shallow subtidal cycles, are recognized in the Yeongheung Formation. The peritidal cycles are composed of shallow subtidal lithofacies capped by tidal-flat lithofacies, whereas the shallow subtidal cycles are entirely subtidal lithofacies with no tidal-flat caps or subaerial exposure features. Stacking of shallow subtidal cycles, the similtaneous development of peritidal and subtidal cycles on different parts of the carbonate platform, and persistent vertical stacking of meter-scale, shallowing-upward cycles suggest that most of the cycles were formed in response to high-frequency eustatic sea level oscillations.On the basis of stacking of shallowing-upward cycles, at least five third-order transgressive-regressive depositional sequences occur in the Yeongheung Formation Among them, four third-order depositional sequences are recognized in the succession of the Late Llanvirn age. The third-order sea level flutuation signals in the Yeongheung Formation are different from those of the worldwide sedimentary records which contain, at most, two third-order sea level changes. This discrepancy between eustatic signals may be related to the depositional setting, where broad, flat carbonate platform environments are more sensitive to relative sea level change rather than slope or craton margin settings. Based on the sea level history recorded in Yeongheung shallow carbonate platform deposits, it needs to reconsider the eustatic sea level curve during the Llanvirn.

Textural and geochemical characteristics of Fe−Mn crusts from four seamounts near the Marshall Islands, western Pacific

Textural and geochemical properties of ferromanganese crust (Fe−Mn crust) samples from four adjacent seamounts near the Marshall Islands were investigated to delineate the paleoceanographic condition on their growth history. The Fe−Mn crust samples of this study show four distinct layers (layers 1 to 4 from top to bottom). The uppermost layer 1 is massive and black, and is enriched in hydrogenetic elements such as Mn, Co, Ni, and Mo. The next layer 2 is porous and filled with sediment. Detrital (Al, Rb, and Ti) and biogenic (Cu, Zn, and Ba) elements are enriched in layer 2. The layers 3 and 4 are phosphatized layers which are impregnated with carbonate fluorapatite (CFA), and therefore their primary mineralogy and geochemistry were not preserved. The property of layer 2 suggested that this layer had grown under the condition of high biogenic and detrital flux. Such a condition may be met in the Inter-tropical Convergence Zone (ITCZ) where the northeast and southeast trade winds meet. Considering the present location and paleotracking of seamounts, layer 2 appears to have formed when these seamounts were beneath the ITCZ. On the other hand, layer 1 may have started to grow after the seamounts moved out of the ITCZ with the northwestward movement of the Pacific plate. Our study indicates that the Fe−Mn crusts can be used to trace the paleolocation of ITCZ when precise age determination and information on the plate movement are provided.

Terrestrial biome distribution in the Late Neogene inferred from a black carbon record in the northeastern equatorial Pacific.

The appearance and expansion of C4 plants in the Late Cenozoic was a dramatic example of terrestrial ecological change. The fire hypothesis, which suggests fire as a major cause of C4 grassland is gaining support, yet a more detailed relationship between fire and vegetation-type change remains unresolved. We report the content and stable carbon isotope record of black carbon (BC) in a sediment core retrieved from the northeastern equatorial Pacific that covers the past 14.3 million years. The content record of BC suggests the development process of a flammable ecosystem. The stable carbon isotope record of BC reveals the existence of the Late Miocene C4 expansion, the ‘C4 maximum period of burned biomass’ during the Pliocene to Early Pleistocene, and the collapse of the C4 in the Late Pleistocene. Records showing the initial expansion of C4 plants after large fire support the role of fire as a destructive agent of C3-dominated forest, yet the weak relationships between fire and vegetation after initial expansion suggest that environmental advantages for C4 plants were necessary to maintain the development of C4 plants during the late Neogene. Among the various environmental factors, aridity is likely most influential in C4 expansion.

Evaluation of Resuspended Sediments to Sinking Particles by Benthic Disturbance in the Clarion-Clipperton Nodule Fields

The geochemical properties of sinking particles and sediments in the Clarion-Clipperton Zone were examined to develop a quantitative indicator with which to evaluate the contribution of sediment resuspended by nodule mining activity to sinking particles. The ratio of lithogenic material to organic carbon varies from ∼3 in sinking particles to ∼211 in sediments. This ratio is easily measured and is not easily affected by degradation and/or dissolution in the water column. A mixing model indicates that the ratio may be used as a potential proxy for estimating the contribution of resuspended sediment derived from mining operations to sinking particles.

Movement of the Intertropical Convergence Zone during the mid‐pleistocene transition and the response of atmospheric and surface ocean circulations in the central equatorial Pacific

This paper investigates the causes of a brief, but prominent, cooling episode (1.1–0.8 Ma) that occurred in the equatorial upwelling region of the Atlantic and Pacific during the mid-Pleistocene transition (MPT) using temporal changes in dust provenance, regional hydrology, and surface productivity recorded in a deep-sea sediment core from the central equatorial Pacific. The 87Sr/86Sr and ɛNd values of the inorganic silicate fraction indicate deposition of dust from Australia and Central/South America before 0.8 Ma, but a gradual increase in Asian dust deposition after 0.8 Ma. The change in dust provenance was accompanied by an increased dust flux and a decrease in surface productivity and salinity. These changes can be explained by the southward movement of the Intertropical Convergence Zone (ITCZ) and North Equatorial Counter Current (NECC) and the direct influence of these features on the site after 0.8 Ma. Our results, together with previously published Atlantic data, suggest the northward position of the ITCZ between 1.1 and 0.9 Ma, and the southward position thereafter. The meridional movement of the ITCZ is in phase with the cooling and warming trend in upwelling regions in the equatorial Pacific and Atlantic, which suggests strengthening of southeast trades relative to its northern counterpart between 1.1 and 0.9 Ma as a plausible cause of this brief cooling event. The southward movement of the ITCZ from 0.9 to 0.8 Ma indicates more significant cooling in the Northern Hemisphere (NH) than in the Southern Hemisphere, which is supportive of the interpretation that the NH ice sheet expanded significantly and stabilized after 0.9 Ma.

Southward shift of the Intertropical Convergence Zone due to Northern Hemisphere cooling at the Oligocene-Miocene boundary

The Mi-1 glaciation (ca. 23 Ma), which marks the Oligocene-Miocene boundary, was an aberrant cooling event that led to a build-up of the Antarctic ice sheet, which reached the near-modern volume (or greater) from its ephemeral or partial existence. An increase of ∼1‰ in the δ18O of benthic foraminifera during this interval has been attributed to the development of Antarctic ice sheets and deep-water cooling. Without definitive evidence, Northern Hemisphere (NH) glaciation has not been a material consideration for the δ18O increase. Here we investigate the interhemispheric temperature contrast during Mi-1, with the movement of the Intertropical Convergence Zone (ITCZ) at a site (10°31′N) in the East Pacific (Integrated Ocean Drilling Program Site U1333), to understand NH cooling and the possibility of NH glaciation. The measured 143Nd/144Nd, 87Sr/86Sr, and clay mineral compositions of eolian dust fractions indicate unequivocally the deposition of Asian dust during Mi-1, and of Central American and South American dust before and after Mi-1. This is attributed to the southward displacement of the ITCZ over Site U1333 during Mi-1. The ITCZ shifts toward the warmer hemisphere. Thus our results suggest that the cooling during Mi-1 was more significant in the NH than in the Southern Hemisphere, which underwent a sudden expansion of continental ice sheets. Our data call for a forcing mechanism to drive significant NH cooling during this episode. Based on the available data, we propose that the widespread growth of NH ice sheets and/or changes in the production of North Atlantic–origin deep water could be possible causes of the NH cooling at that time.

Paleo-latitude of the Intertropical Convergence Zone in the Northeast Pacific during Late Cenozoic

The Intertropical Convergence Zone (ITCZ), where the southeast and northeast trade winds converge, is the effective climatological barrier that separates the southern and northern hemispheres in dust budget. Asian and N. American dusts dominate in the Pacific north of the ITCZ, while Central and S. American dust prevails south of the ITCZ. In order to understand the nature of latitudinal and depth-related variations of mineral composition in terms of relative position to the ITCZ, deep-sea core sediments were collected from 9 o N to 17 o N at a 2 o interval along the 131.5 o W meridian and analyzed for mineral composition. The amount of illite in surface sedime nts decreases gradually from 65% at 17 o N to 31% at 9 o N. In contrast, smectite increases from 11% to 56% southward. The observed mineralogical variation toward the ITCZ is attributed to the increased supply of volcaniclastic material transported via the southeast trade winds from the Central and South America source regions. Smectite-illite transition, a phenomenon that the amount of smectite increases over illite, occurs at around 10 o N, the northern margin of the ITCZ. This result indicates that the change in latitudinal position of the ITCZ in geologic past could be recorded as a form of smectite-illite transition in deep-sea cores. The studied cores show down-core variation of mineral composition from illite-rich at the surface to smect ite-rich clay suit at depths , similar to the latitudinal variation. The smectite-ill ite transitions observed in these core s are likely the records of changes in latitudinal position of the ITCZ. The depth and age of smectite-illite transition is getting shallower and younger toward equator, implying that the ITCZ was located farther north during late Tertiary and has shifted southward to the present position of 5 o N-10 o N.