Charles M. Wynn

Detection of condensed-phase explosives via laser-induced vaporization, photodissociation, and resonant excitation

We investigate the remote detection of explosives via a technique that vaporizes and photodissociates the condensed-phase material and detects the resulting vibrationally excited NO fragments via laser-induced fluorescence. The technique utilizes a single 7 ns pulse of a tunable laser near 236.2 nm to perform these multiple processes. The resulting blue-shifted fluorescence (226 nm) is detected using a photomultiplier and narrowband filter that strongly block the scatter of the pump laser off the solid media while passing the shorter wavelength photons. Various nitro-bearing compounds, including 2,6-dinitrotoluene (DNT), 2,4,6-trinitrotoluene (TNT), pentaerythritol tetranitrate (PETN), and hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) were detected with a signal-to-noise of 25 dB. The effects of laser fluence, wavelength, and sample morphology were examined.

Noncontact detection of homemade explosive constituents via photodissociation followed by laser-induced fluorescence

Noncontact detection of the homemade explosive constituents urea nitrate, nitromethane and ammonium nitrate is achieved using photodissociation followed by laser-induced fluorescence (PD-LIF). Our technique utilizes a single ultraviolet laser pulse (approximately 7 ns) to vaporize and photodissociate the condensed-phase materials, and then to detect the resulting vibrationally-excited NO fragments via laser-induced fluorescence. PD-LIF excitation and emission spectra indicate the creation of NO in vibrationally-excited states with significant rotational energy, useful for low-background detection of the parent compound. The results for homemade explosives are compared to one another and 2,6-dinitrotoluene, a component present in many military explosives.

Noncontact optical detection of explosive particles via photodissociation followed by laser-induced fluorescence

High-sensitivity (ng/cm²) optical detection of the explosive 2,4,6-trinitrotoluene (TNT) is demonstrated using photodissociation followed by laser-induced fluorescence (PD-LIF). Detection occurs rapidly, within 6 laser pulses (~7 ns each) at a range of 15 cm. Dropcasting is used to create calibrated samples covering a wide range of TNT concentrations; and a correspondence between fractional area covered by TNT and PD-LIF signal strength is observed. Dropcast data are compared to that of an actual fingerprint. These results demonstrate that PD-LIF could be a viable means of rapidly and remotely scanning surfaces for trace explosive residues.

Trace aerosol detection and identification by dynamic photoacoustic spectroscopy

Dynamic photoacoustic spectroscopy (DPAS) is a high sensitivity technique for standoff detection of trace vapors. A field-portable DPAS system has potential as an early warning provider for gaseous-based chemical threats. For the first time, we utilize DPAS to successfully detect the presence of trace aerosols. Aerosol identification via long-wavelength infrared (LWIR) spectra is demonstrated. We estimate the sensitivity of our DPAS system to aerosols comprised of silica particles is comparable to that of SF(6) gas based on a signal level per absorbance unit metric for the two materials. The implications of these measurements are discussed.

A numerical study of shock waves generated through laser ablation of explosives

Shock waves resulting from irradiation of energetic materials with a pulsed ultraviolet laser source have been shown to be an effective indicator for explosives detection. Here, the features of shock wave propagation are explored theoretically. The initial stage of the shock motion is simulated as a one-dimensional process. As the nonlinear wave expands to form a blast wave, a system of conservation equations, simplified to the Euler equations, is employed to model wave propagation. The Euler equations are solved numerically by the 5th order weighted essentially non-oscillatory finite difference scheme with the time integration carried out using the 3rd order total variation diminishing Runge Kutta method. The numerical results for the shock wave evolution are compared with those obtained from experiments with a meltcast 2,6-dinitrotoluene sample. The calculations lay a theoretical foundation for a recently investigated technique for photoacoustically sensing explosives using a vibrometer.

Non-contact laser ultrasound concept for biomedical imaging

The potential of a fully noncontact, standoff, laserultrasound system that acquires ultrasonic images within biological tissue is examined. A pulsed laser converts optical energy into ultrasound via photoacoustic mechanisms, while laser Doppler vibrometry measures emerging ultrasonic waves at the tissue surface. Differing from photoacoustic tomography (PAT), which maps spatial variations in tissue-optical absorptivity in the acoustic near field, the laser ultrasound (LUS) approach developed here, is driven by shallow, non-varying optical absorptivity that creates a laterally consistent acoustic source enabling ultrasound propagation well into the far field. LUS acoustic wave generation is explored in tissue and bone including longitudinal, shear, and Rayleigh wave components. Using information from LUS wave types can yield 1) tissue and bone anatomical images and 2) mechanical property distributions that apply to the emerging field of medical elastography. Imaging capabilities using a demonstration LUS system are also presented for complex bio-tissues. Ultrasonic images compare well with ground truth geometries, orientation, and depth of staged samples. 2D cross-sectional echo reflection images are generated for a phantom limb containing muscle and bone materials and use data inversion techniques to yield the elastic moduli distributions in the specimen.

Computational reconfigurable imaging spectrometer

We demonstrate a novel hyperspectral imaging spectrometer based on computational imaging that enables sensitive measurements from smaller, noisier, and less-expensive components (e.g. uncooled microbolometers), making it useful for applications such as small space and air platforms with strict size, weight, and power requirements. The computational reconfigurable imaging spectrometer (CRISP) system exploits platform motion and a spectrally coded focal-plane mask to temporally modulate the optical spectrum, enabling simultaneous measurement of multiple spectral bins. Demodulation of this coded pattern returns an optical spectrum in each pixel.

Integration of high-speed surface-channel charge coupled devices into an SOI CMOS process using strong phase shift lithography

To enable development of novel signal processing circuits, a high-speed surface-channel charge coupled device (CCD) process has been co-integrated with the Lincoln Laboratory 180-nm RF fully depleted silicon-on-insulator (FDSOI) CMOS technology. The CCDs support charge transfer clock speeds in excess of 1 GHz while maintaining high charge transfer efficiency (CTE). Both the CCD and CMOS gates are formed using a single-poly process, with CCD gates isolated by a narrow phase-shift-defined gap. CTE is strongly dependent on tight control of the gap critical dimension (CD). In this paper we review the tradeoffs encountered in the co-integration of the CCD and CMOS technologies. The effect of partial coherence on gap resolution and pattern fidelity is discussed. The impact of asymmetric bias due to phase error and phase shift mask (PSM) sidewall effects is presented, along with adopted mitigation strategies. Issues relating to CMOS pattern fidelity and CD control in the double patterning process are also discussed. Since some signal processing CCD structures involve two-dimensional transfer paths, many required geometries present phase compliance and trim engineering challenges. Approaches for implementing non-compliant geometries, such as T shapes, are described, and the impact of various techniques on electrical performance is discussed.