Cheng Jui Tsai

Hydrogenation induced reversible modulation of perpendicular magnetic coercivity in Pd/Co/Pd films

In perpendicularly magnetized Pd/Co/Pd trilayers, the hydrogenation not only increased Kerr signal but also significantly enhanced the magnetic coercivity (H C ) by 17%. The reversibility was demonstrated by cyclic H2 exposure. The time constants of hydrogen absorption and desorption effect on H C range from tens to hundreds seconds, depending on the H2 gas pressure. The magneto-optical Kerr signal and magnetic coercivity was simultaneously recorded during H2 absorption and desorption. These multifarious signals respond differently and provide a detailed understanding of hydrogenation effect on the functional Pd/Co/Pd trilayers.

Critical hydrogenation effect on magnetic coercivity of perpendicularly magnetized Co/Pd multilayer nanostructures

Low dimensional materials of perpendicularly magnetized [Co(0.5 nm)/Pd(3 nm)] multilayer, including continuous thin film, nanodots and nanodot-chains were prepared for the investigation of reversible hydrogenation effect on the magnetic and optical properties. For the continuous film, after hydrogenation the magnetic coercivity (Hc) was enhanced by 47% and the Kerr intensity was significantly reduced to 10% of the pristine value. In nanodots, hydrogenation led to 25% reduction of Hc and Kerr intensity as well. For nanodot-chains, the shape of magnetic hysteresis loop was modulated by hydrogenation. The hydrogenation and desorption completed within few seconds in nanodots.

Uniaxial magnetic anisotropy in Pd/Fe bilayers on Al2O3 (0001) induced by oblique deposition

This study reports the preparation of self-organized 1-dimensional magnetic structures of Fe on Al2O3 (0001) by oblique deposition. The x-ray diffraction (XRD) results in this study show the preferred (110) texture of the Fe films. XRD and extended x-ray adsorption fine structure measurements indicate larger oblique deposition angle (65°) leads to more disorder in the Fe crystalline structure. After capping with a Pd overlayer, the Pd/Fe/Al2O3 (0001) still exhibits uniaxial magnetic anisotropy induced by the underlying 1-dimensional Fe nanostructure. This uniaxial magnetic anisotropy changes with the variation in Fe thickness and oblique deposition angle. These results clearly indicate the feasibility of manipulating uniaxial magnetic anisotropy and crystalline order through the oblique deposition of magnetic materials.

Magnetism modulation of Fe/ZnO heterostructure by interface oxidation

In this study, the magnetic coercivity (Hc) of Fe/ZnO heterostructure was significantly enhanced by 2–3 times after applying a suitable current. This Hc enhancement originates from the Fe-oxidation at the Fe/ZnO interface induced by direct current heating. Depth-profiling X-ray photoemission spectroscopy analysis confirmed the formation of FeO, Fe3O4, and Fe2O3 close to the interface region, depending on the Fe thickness and annealing process. This study demonstrates that direct current heating can moderately change the local interface oxidation and modulate the magnetic properties. These results clearly reveal the correlation between magnetism and interface properties in the Fe/ZnO heterostructure and provide valuable information for future applications.

Hydrogenation-induced change of magneto optical Kerr effect in Pd/Fe bilayers

The hydrogenation induced change of magneto-optical Kerr effect (MOKE) was studied in n ML Pd/30 ML Fe bilayers on Al2O3(0001). With the increasing of Pd thickness from 3 ML to 60 ML, the MOKE extinction angle was gradually shifted by 0.6° and the enhancement of Kerr intensity reached 35%–40% after exposure to 1 atm hydrogen. The reversibility of this significant change was demonstrated by cyclic desorption and reabsorption of hydrogen. This study reveals the sensitive MO response in the combination of a magnetic Fe thin film with a highly hydrogenated Pd capping layer.

Hydrogen-mediated long-range magnetic ordering in Pd-rich alloy film

The effect of hydrogenation on a 14 nm Co14Pd86/Al2O3(0001) thin film was investigated on the basis of the magnetooptical Kerr effect. After exposure to H2 gas, the squareness of the hysteresis loop showed a large transition from approximately 10% to 100% and the saturation Kerr signal was reduced to nearly 30% of the pristine value. The reversibility of the transition was verified and the response time was within 2–3 s. These observations indicate that the hydride formation transformed the short-range coupled and disordered magnetic state of the Co14Pd86 film to a long-range-ordered ferromagnetic state and induced appreciable decrease in the magnetic moment. The enhanced long-range-ordering and the reduction of the magnetic moment were attributed to the change of electronic structure in Co14Pd86 with hydrogen uptake.

Voltage-induced reversible changes in the magnetic coercivity of Fe/ZnO heterostructures

In this study, the magnetic coercivity (Hc) of Fe/ZnO heterostructure monotonically decreased as voltage was applied. The reversibility of this effect was demonstrated by cyclically changing the bias voltage from 0 to 6–9 V; the Hc decreased 15%–20%. The Hc value exhibited the same variation whether the applied voltage was positive or negative. As thick Fe-oxide gradually formed at the interface by using direct current heating, the Hc increased and the Fe/ZnO heterostructure demonstrated a similar voltage-induced reduction of Hc.

Magnetic anisotropic properties of Pd/Co/Pd trilayer films studied by X-ray absorption spectroscopy and magnetic circular dichroism

We study the magnetic anisotropic properties of as-grown and annealed Pd/Co/Pd trilayer films based on their atomic and electronic structures using extended X-ray absorption fine structure (EXAFS), X-ray absorption near edge structure (XANES) spectroscopy and magnetic circular dichroism (XMCD) measurements. The annealed film exhibits interesting perpendicular magnetic anisotropy (PMA) whereas the as-grown film exhibits in-plane anisotropy. Cross-sectional transmission electron microscopic analysis together with the Co K-edge EXAFS results confirm the formation of an ordered-alloy CoPd phase in the annealed film, whereas the as-grown film has an hcp Co-like phase. Co L3,2-edge XMCD measurements reveal an enhanced ratio of the Co 3d orbital to spin moments of the annealed film providing evidence of the observed PMA upon annealing.

Oxygen surfactant-assisted growth and dewetting of Co films on O-3 × 3/W(111)

Following the cyclic heating in oxygen and annealing, an oxygen-induced 3 × 3 reconstruction was found on the W(111) surface. The growth, crystalline structure, thermal stability, and magnetism of Co ultrathin films deposited on the O-3 × 3/W(111) surface were investigated. The Auger signal of the oxygen was always observable and nearly invariant after either Co deposition or annealing, indicating the role of the surfactant played by oxygen. Auger electron spectroscopy and scanning tunneling microscopy measurements revealed the 2-dimensional growth of Co on O-3 × 3/W(111). Following the annealing procedures, the surfactant oxygen was always observed to float on the film surface while the Co film transformed to 3-dimensional islands with a wetting layer. In contrast to the thermodynamically stable wetting layer of 1 physical monolayer (PML) Co on clean W(111) between 700 and 1000 K, the oxygen surfactant led to a reduction of the wetting layer to ≈1/3 PML after thermal annealing. The 6 and 9.6 PML Co/O-3 × 3/W(111) revealed a stable in-plane magnetic anisotropy. A 6-fold symmetry corresponding to the crystalline structure was observed in the in-plane angle-dependent magneto-optical Kerr effect measurement.