Christina Manning

Lu–Hf and Sm–Nd dating of metamorphic garnet: evidence for multiple accretion events during the Caledonian orogeny in Scotland

Caledonian orogenesis in Scotland is currently interpreted in terms of a Mid-Ordovician arc–continent collision (Grampian event) followed by the Silurian collision of Laurentia with Baltica (Scandian event). Lu–Hf and Sm–Nd garnet ages of c. 475–460 Ma obtained from prograde garnets in metasedimentary successions and metabasic intrusions within the Northern Highland and Grampian terranes confirm that the Mid-Ordovician Grampian orogenic event was approximately synchronous in the two terranes. Lu–Hf and Sm–Nd ages of c. 450 Ma obtained from prograde garnets within the Moine Nappe of the Northern Highland terrane provide evidence for a hitherto unrecognized Late Ordovician regional metamorphic event. The existing two-stage Grampian–Scandian model for Caledonian orogenesis in northern Scotland is thus an oversimplification, and the new ages imply a more complex structural evolution. The restriction of the Late Ordovician and Silurian events to the Northern Highland terrane reinforces the suggestion that it was far removed from the Grampian terrane until juxtaposition following major end-Caledonian (Devonian) sinistral displacement along the Great Glen Fault. A similar record of Mid- and Late Ordovician metamorphic events within the Laurentian-derived Uppermost Allochthons of Norway has been attributed to episodic accretion significantly prior to Silurian continent–continent collision and closure of the Iapetus Ocean. Supplementary materials: Results of trace element analysis of the garnets by laser ablation inductively coupled plasma mass spectrometry are available at www.geolsoc.org.uk/SUP18583.

Two possible source regions for central Greenland last glacial dust

Dust in Greenland ice cores is used to reconstruct the activity of dust-emitting regions and atmospheric circulation. However, the source of dust material to Greenland over the last glacial period is the subject of considerable uncertainty. Here we use new clay mineral and <10 µm Sr–Nd isotopic data from a range of Northern Hemisphere loess deposits in possible source regions alongside existing isotopic data to show that these methods cannot discriminate between two competing hypothetical origins for Greenland dust: an East Asian and/or central European source. In contrast, Hf isotopes (<10 µm fraction) of loess samples show considerable differences between the potential source regions. We attribute this to a first-order clay mineralogy dependence of Hf isotopic signatures in the finest silt/clay fractions, due to absence of zircons. As zircons would also be absent in Greenland dust, this provides a new way to discriminate between hypotheses for Greenland dust sources.

Dimensions, texture-distribution, and geochemical heterogeneities of fracture–related dolomite geobodies hosted in Ediacaran limestones, northern Oman

Predicting spatial distribution, dimension, and geometry of diagenetic geobodies, as well as heterogeneities within these bodies, is challenging in subsurface applications, and can impact the results of reservoir modeling. In this outcrop–based study, we generated a data set of the dimensions of fracture–related dolomite geobodies hosted in Ediacaran (Khufai Formation) limestones of the Oman Mountains that are up to several hundreds of meters long and a few tens of meters wide. The dolomite formed under burial conditions by fluids that interacted with siliciclastic layers, as demonstrated by the enriched Fe (up to 4.4%) and Mn (up to 0.8%) contents and () signatures. Dolomitization probably occurred during the Hercynian Orogeny (or pre-Permian) because dolomitization predates some folding and pre-Permian rocks have seen intense deformation related to the Carboniferous Hercynian Orogeny. Moreover, dolomitization occurred between the onset and termination of bedding-parallel stylolitization and thus most likely before deep burial related to the Alpine Orogeny. Hence, dolomitization most likely occurred before deep burial related to the Alpine Orogeny and during or following the intense deformation related to the Carboniferous Hercynian Orogeny had affected pre–Permian rocks. The clumped–isotope signature yields a temperature of approximately 260°C (500°F), interpreted as the apparent equilibrium temperature obtained during uplift after deepest burial during the Late Cretaceous. Lateral transects across the dolomite bodies show that zebra dolomite textures are common throughout the body and that vugs are more common at the rim than the center of the bodies. Moreover, a weak geochemical trend exists with more depleted , Fe, and Mn concentrations in the core than at the rim of the dolomite bodies. These results show that minor heterogeneities exist within the dolomite bodies investigated. These data contrast with previous studies, in which more significant variation is reported in width of the dolomitization halo and texture for larger dolomite bodies that formed in host rocks more permeable than the examples from the Oman Mountains.

Precambrian olistoliths masquerading as sills from Death Valley, California

Olistolith production and magmatism are processes commonly associated with extensional tectonic settings, such as rift basins. We present a cautionary exemplar from one such Precambrian basin, in which we reinterpret metabasite bodies, previously documented as sills, to be olistoliths. We nevertheless demonstrate that, on the basis of field observation alone, the previous but erroneous sill interpretation is parsimonious. Indeed, it is only by using isotopic age and compositional analysis that the true identities of these metabasite olistoliths are revealed. We present new data from metabasites and metasedimentary strata of the Kingston Peak Formation (Cryogenian) and Crystal Spring Formation (Mesoproterozoic) of Death Valley, USA. These include field observations, U–Pb apatite ages, U–Pb zircon ages (detrital and igneous) and whole-rock geochemistry. These data also provide a new maximum age for the base of the Pahrump Group and suggest that the Crystal Spring Diabase was more tholeiitic than previously thought. Similar sill/olistolith misinterpretations may have occurred elsewhere, potentially producing erroneous age and tectonic-setting interpretations of surrounding strata. This is particularly relevant in Precambrian rocks, where fossil age constraints are rare. This is illustrated herein using a potential example from the Neoproterozoic literature of the Lufilian belt, Africa. We caution others against Precambrian olistoliths masquerading as sills. Supplementary material: Details of a meta-igneous boulder from P12 of the Silurian Hills, LA-ICP-MS and whole-rock geochemistry methods and standards, and U–Pb apatite and zircon isotopic data, including standards and selected cathodoluminescence images, are available at https://doi.org/10.6084/m9.figshare.c.3990639