Christopher Chase

Critical diameter for III-V nanowires grown on lattice-mismatched substrates

The authors report the experimental observation of a critical diameter (CD) of III-V compound semiconductor epitaxial nanowires (NWs) grown on lattice-mismatched substrates using Au-catalyzed vapor-liquid-solid growth. The CD is found to be inversely proportional to the lattice mismatch. NWs with well-aligned orientation are synthesized with catalysts smaller than the CD. Well-aligned InP NWs grown on a Si substrate exhibit a record low photoluminescence linewidth (5.1meV) and a large blueshift (173meV) from the InP band gap energy due to quantization. Well-aligned InAs NWs grown on a Si substrate are also demonstrated.

Planar high-numerical-aperture low-loss focusing reflectors and lenses using subwavelength high contrast gratings

We propose planar, high numerical aperture (NA), low loss, focusing reflectors and lenses using subwavelength high contrast gratings (HCGs). By designing the reflectance and the phase of non-periodic HCGs, both focusing reflectors and lenses can be constructed. Numerical aperture values as high as 0.81 and 0.96 are achieved for a reflector and lens with very low losses of 0.3 and 0.2 dB, respectively. The design algorithm is also shown to be readily extended to a 2D lens. Furthermore, HCG optics can simultaneously focus the reflected and transmitted waves, with important technological implications. HCG focusing optics are defined by one-step photolithography and thus can be readily integrated with many devices including VCSELs, saturable absorbers, telescopes, CCDs and solar cells.

Atomically sharp catalyst-free wurtzite GaAs∕AlGaAs nanoneedles grown on silicon

We report a catalyst-free, self-assembled growth mode generating single-crystal wurtzite phase ultrasharp GaAs∕AlGaAs nanoneedles on both GaAs and Si substrates via low-temperature metal-organic chemical vapor deposition. The needles exhibit record-narrow tip diameters of 2–4nm wide and sharp 6°–9° taper angles. The length is dependent on growth time and up to 3–4μm nanoneedles are attained. The structures do not exhibit twinning defects, contrary to typical GaAs nanowires grown by vapor-liquid-solid catalyzed growth. AlGaAs layered nanoneedle structures are also demonstrated.

High-Index-Contrast Grating (HCG) and Its Applications in Optoelectronic Devices

We review recent advances in subwavelength high-index-contrast gratings (HCGs) and a variety of applications in optoelectronic devices, including vertical-cavity surface-emitting lasers (VCSELs), tunable VCSELs, high-Q optical resonators, and low-loss hollow-core waveguides (HWs). HCGs can serve as broadband (Delta lambda/lambda ~ 35%), high-reflectivity (>99%) mirrors for surface-normal incident light, which is useful to replace conventional distributed Bragg reflectors in optical devices. HCGs can also be designed as high-Q resonators with output coupling in the surface-normal direction. Finally, we discuss a novel design of HCG as shallow angle reflectors and HWs.

Neurologic features of Williams and Down syndromes

Eight patients with Williams syndrome and 6 with Down syndrome, matched for age and full-scale IQ, underwent detailed neurologic testing as part of a large multidisciplinary research center study. Williams syndrome patients were small for gestational age and often had histories of failure-to-thrive and feeding problems as infants. Half of the Williams syndrome patients had epilepsy. On neurologic testing, Williams syndrome patients had greater difficulty with gross and fine motor coordination, oromotor skills, and cerebellar function than did those with Down syndrome. The neurologic distinctions between these 2 groups may reflect an underlying, as yet undefined, metabolic defect in Williams syndrome.

1550 nm high contrast grating VCSEL

We demonstrate an electrically pumped high contrast grating (HCG) VCSEL operating at 1550 nm incorporating a proton implant-defined aperture. Output powers of >1 mW are obtained at room temperature under continuous wave operation. Devices operate continuous wave at temperatures exceeding 60 degrees C. The novel device design, which is grown in a single epitaxy step, may enable lower cost long wavelength VCSELs.

Long-Wavelength VCSEL Using High-Contrast Grating

Recent advances in high-contrast grating (HCG) vertical-cavity surface-emitting lasers (VCSEL) emitting at 1550 nm is reported in this paper. The novel near-wavelength HCG has an ultrathin structure and broadband reflectivity. It enables a monolithic, simple fabrication process for realizing InP-based VCSELs emitting at ~1550 nm. We report 2.4-mW single-mode output under continuous-wave operation at 15°C. We show that, despite broadened by the Brownian motion, the HCG-VCSEL has a total linewidth of 60 MHz or a coherent length of 5 m in air, and an intrinsic linewidth <;20 MHz. Transmission of directly modulated 10 Gbps over 100-km dispersion-compensated single-mode fiber is demonstrated. Tunable HCG-VCSEL is demonstrated with the HCG integrated with a micro-electro-mechanical structure. Continuous wavelength tuning as wide as 26.3 nm is achieved. The tunable VCSEL was used as a source for external modulation for 40-Gbps differential-phase-shift-keyed signal and transmitted over 100-km dispersion-compensated link with negligible power penalty.

High-Contrast Grating VCSELs

Recent advances in a single-layer 1-D high-index-contrast subwavelength grating structure are reviewed. Its incorporation into a vertical-cavity surface-emitting laser (VCSEL) structure enabled simple fabrication, lithographically defined polarization control and large aperture, single-transverse-mode control. Extraordinarily large fabrication tolerance is demonstrated with plusmn20% variation of the high-contrast grating (HCG) critical dimension. Emission wavelength of HCG-VCSEL varied 0.2% with a 40% change in lithography linewidth. Tunable VCSELs are fabricated using HCG, which led to a 8000 times reduction in the tunable mirror size and 160 times improved tuning speed of 63 ns. This configuration will open the door for a wide spectrum of optoelectronic devices in large wavelength regimes.

Monolithically integrated multi-wavelength VCSEL arrays using high-contrast gratings.

We propose a novel design for multi-wavelength arrays of vertical cavity surface-emitting lasers (VCSELs) using high-contrast gratings (HCGs) as top mirrors. A range of VCSEL cavity wavelengths in excess of 100 nm is predicted by modifying only the period and duty-cycle of the high-contrast gratings, while leaving the epitaxial layer thickness unchanged. VCSEL arrays fabricated with this novel design can easily accommodate the entire Er-doped fiber amplifier bandwidth with emission wavelengths defined solely by lithography with no restrictions in physical layout. Further, the entire process is identical to that of solitary VCSELs, facilitating cost-effective manufacturing.

Piracetam and dyslexia: effects on reading tests

Previous research has suggested that dyslexics treated with piracetam have shown improvements in reading skills, verbal memory and verbal conceptualizing ability, feature analysis, and processing of letter-like stimuli. Two hundrend twenty-five dyslexic children between the ages of 7 years 6 months and 12 years 11 months whose reading skills were significantly below their intellecutual capacity were enrolled in a multicenter, 36-week, double-blind, placebo-contrlled study. Children of below average intelligence, with abnormal findings on audiologic, ophthalmologic, neurologic, psychiatric, and physical examinations, who were emotionally disturbed or educationally deprived and who had recently been treated with psychoactive medication were excluded from the trial. Piracetam was well tolerated, with no serious adverse clinical or laboratory effects reported. Piracetam-treated children showed significant improvements in reading ability (Gray Oral Reading Test) and reading comprehension (Gilmore Oral Reading Test). Treatment effects were evident after 12 weeks and were sustained for the total period (36 weeks)