Christopher R.M. McFarlane

Detrital zircon evidence for non-Laurentian provenance, Mesoproterozoic (ca. 1490–1450 Ma) deposition and orogenesis in a reconstructed orogenic belt, northern New Mexico, USA: Defining the Picuris orogeny

Detrital zircon and igneous zircon U-Pb ages are reported from Proterozoic metamorphic rocks in northern New Mexico. These data give new insight into the provenance and depositional age of a >3-km-thick metasedimentary succession and help resolve the timing of orogenesis within an area of overlapping accretionary orogens and thermal events related to the Proterozoic tectonic evolution of southwest Laurentia. Three samples from the Paleoproterozoic Vadito Group yield narrow, unimodal detrital zircon age spectra with peak ages near 1710 Ma. Igneous rocks that intrude the Vadito Group include the Cerro Alto metadacite, the Picuris Pueblo granite, and the Penasco quartz monzonite and yield crystallization ages of 1710 ± 10 Ma, 1699 ± 3 Ma, and 1450 ± 10 Ma, respectively. Within the overlying Hondo Group, a metamorphosed tuff layer from the Pilar Formation yields an age of 1488 ± 6 Ma and represents the first direct depositional age constraint on any part of the Proterozoic metasedimentary succession in northern New Mexico. Detrital zircon from the overlying Piedra Lumbre Formation yield a minimum age peak of 1475 Ma, and ~60 grains (~25%) yield ages between 1500 Ma and 1600 Ma, possibly representing non-Laurentian detritus originating from Australia and/or Antarctica. Detrital zircons from the basal metaconglomerate and the middle quartzite member of the Marquenas Formation yield minimum age peaks of 1472 Ma and 1471 Ma, consistent with earlier results. We interpret the onset of ca. 1490–1450 Ma deposition followed by tectonic burial, regional Al 2 SiO 5 triple-point metamorphism, and ductile deformation at depths of 12–18 km to reflect a Mesoproterozoic contractional orogenic event, possibly related to the final suturing of the Mazatzal crustal province to the southern margin of Laurentia. We propose to call this event the Picuris orogeny.

Interactions between axial and transverse drainage systems in the Late Cretaceous Cordilleran foreland basin: Evidence from detrital zircons in the Straight Cliffs Formation, southern Utah, USA

New detrital zircon geochronologic data from the Straight Cliffs Formation of southern Utah provide insight into the controls on stratigraphic architecture of the Western Interior Basin during Turonian–early Campanian time. Detrital zircon ages ( N = 40, n = 3650) derived from linked fluvial and shallow-marine depositional systems of the Kaiparowits Plateau indicate the majority of zircons in fluvial strata were derived from the Mogollon Highlands (1.25–1.90 Ga, 67% of fluvial zircons), with subordinate contributions delivered from the Sevier fold-and-thrust belt (265–1250 Ma, 17%) and Cordilleran magmatic sources (81–265 Ma, 16%). Integration of these data with fluvial facies distributions, petrography, clast counts, and evidence of magmatic arc sources from the Mohave region of California implies the presence of a northeast-flowing, axial fluvial system. This system was fed by rivers draining the Mogollon Highlands to the south and by transverse drainages from the Sevier fold-and-thrust belt to the west. Compared to the fluvial deposits, shallow-marine sandstones have a greater proportion of Sevier fold-and-thrust belt–derived zircons (42%), which were delivered via longshore currents from the north. Shallow-marine samples also contain less Mogollon input (44%) compared to contemporaneous fluvial systems, and similar input from the magmatic arc (14%). Although Proterozoic zircons associated with the Mogollon Highlands are also present in the Sevier fold-and-thrust belt, several lines of evidence argue for a distinct southerly source for the Straight Cliffs Formation. These include (1) moderate proportions of feldspar and angular quartz grains in fluvial sandstones, which favor a felsic intrusive source, and (2) prominent 1.4 and 1.7 Ga zircon populations. The 1.4 and 1.7 Ga peaks are the only dominant Proterozoic peaks in samples from the Straight Cliffs Formation, whereas samples derived more directly from the Sevier fold-and-thrust belt tend to have a broader distribution of Proterozoic age peaks. Up-section architectural trends in the Straight Cliffs Formation are linked to trends in detrital zircon geochronologic data, underscoring the likelihood of common drivers and controls. The axial system depositing Straight Cliffs fluvial strata was primarily fed by drainages originating in the Mogollon Highlands during a pulse of tectonic activity in the Maria fold-and-thrust belt and generally high subsidence rates in the foreland basin (Turonian–Santonian). Over time, activation of the Paxton duplex in the Sevier fold-and-thrust belt (early Campanian) exhumed proximal foreland basin strata and enabled drainage systems from the Sevier fold-and-thrust belt to feed into the basin more prominently. The results presented here underscore the potential significance of axial fluvial systems and their complex interplay with transverse drainage networks in foreland basins.

Geochemistry of the Peramora Mélange and Pulo do Lobo schist: geochemical investigation and tectonic interpretation of mafic mélange in the Pangean suture zone, Southern Iberia

The Peramora Mélange is part of an accretionary complex between the South Portuguese Zone (a fragment of Laurussia) and the Ossa Morena Zone (para-autochthonous Gondwana) and is an expression of the Pangean suture zone in southwestern Iberia. The suture zone is characterized by fault-bounded units of metasedimentary rocks, mélanges, and mafic complexes. Detailed geologic mapping of the Peramora Mélange reveals a complex pattern of imbricated schists and mafic block-in-matrix mélanges. Geochemical signatures of the Pulo do Lobo schist (PDL) are consistent with derivation from both mafic and continental sources. The mafic block-in-matrix mélange displays normal mid-ocean ridge basalt (NMORB) geochemical signature, juvenile Sm–Nd isotopic compositions, and a range of zircon ages similar to those observed in the PDL, suggesting a sedimentary component. Taken together, these data suggest a complex tectonic history characterized by erosion of a NMORB source, mélange formation, and imbrication during underplating occurring during the final stages of continent–continent collision.

Petrogenesis of the Kulyk Lake monazite-apatite-Fe(Ti)-oxide occurrence revealed using in-situ LA-(MC)-ICP-MS trace element mapping, U-Pb dating, and Sm-Nd isotope systematics on monazite

Abstract The high-grade metamorphic metasedimentary rocks that comprise the Wollaston Domain, northern Saskatchewan, are host to numerous REE-mineralized pegmatite bodies, including the Kulyk Lake monazite-apatite-Fe(Ti)-oxide occurrence. This occurrence, which is defined by a 3-5 cm wide sinouous zone of granoblastic monazite, apatite, and titanomagnetite, is enclosed within aplitic monzonite and granitic pegmatite dikes. Monazite in this dike was studied in detail using in situ laser ablationinductively coupled plasma-mass spectrometry (LA-ICP-MS) and LA-multi-collector (MC)-ICP-MS. A combination of in situ LA-ICP-MS trace element mapping, trace-element quantification, and U-Pb dating were used to identify a significant volume of partial resorbed xenocyrstic monazite and zircon cores within the monazite-apatite-Fe(Ti)-oxide zone. This xenocrystic monazite is locally characterized by anomalously high As, V, Mo, and Eu concentrations and high (La/Yb)CN (i.e., >1000) consistent with their derivation from metalliferous black shales. The U-Pb age distribution of the inherited monazite and zircon populations matches that of the middle- to upper-Wollaston Group sedimentary succession. The latter was confirmed by in situ Sm-Nd isotope systematics measured by LA-MCICP- MS that yielded εNd(1830Ma) between -5.0 and -5.7 consistent with derivation from Wollaston Group metasediment. The crystallization of ~1830 Ma anatectic overgrowths on xenocrystic cores is indistinguishable from monazite crystallization in the aplitic monzonite dike hosting the monaziteapatite- Fe(Ti)-oxide bodies. This study reveals the potential importance of metalliferous monazite-rich lithologies in the anatectic zone to these pegmatite-hosted REE occurrences and suggests that entrainment and magmatic segregation mechanisms may have helped to concentrate monazite, apatite, and Fe(Ti)-oxide prior to final emplacement of the aplite-pegmatite dikes. Similar processes may have occurred regionally and in other high-grade metamorphic terrains worldwide that are endowed with metalliferous metasedimentary protoliths.

In situ elemental and isotopic analysis of fluorapatite from the Taocun magnetite-apatite deposit, Eastern China: Constraints on fluid metasomatism

Abstract Metasomatic alteration of fluorapatite has been reported in several iron-oxide apatite (IOA) deposits, but its effect on elemental and isotopic variations has not been well understood. In this study, we present integrated elemental, U-Pb, Sr, and O isotopic microanalytical data on fresh and altered domains in fluorapatite from the Taocun IOA deposit, Eastern China, to evaluate the timing and nature of the metasomatism and its effects on the ore-forming event. Orebodies of the Taocun deposit are spatially associated with a subvolcanic, intermediate intrusion, which displays zonal alteration patterns with albite in the center and increasing actinolite, chlorite, epidote, and carbonate toward the margin. Both disseminated and vein-type ores are present in the Taocun deposit, and fluorapatite commonly occurs with magnetite and actinolite in most ores. Fluorapatite grains from the both types of ores have been variably metasomatized through a coupled dissolution-reprecipitation mechanism. Many trace elements, including Na, Cl, S, Si, Mg, Sr, U, Th, and (REEs+Y), were variably leached from the fluorapatite grains during this process and the Sr and O isotopic signatures of the grains were also modified. The altered fluorapatite grains/domains have in situ 87Sr/86Sr ratios (0.70829–0.70971) slightly higher than those of the fresh fluorapatite (0.70777–0.70868), and δ18O values (–3.0 to +3.4‰) variably lower than the primary domains (+5.3 to +7.5‰). The Sr and O isotopes of the primary fluorapatite are consistent with or slightly higher than those of the ore-hosting intrusion, implying that the early-stage, ore-forming fluids were magmatic in origin but underwent weak interaction with the country rocks. U-Pb dating of the fresh and altered domains of the fluorapatite yielded indistinguishable ages of ~131 Ma, which are the same as the age of the ore-hosting intrusion. In combination with fluid inclusion data, we propose that the metasomatism of fluorapatite was induced by hydrothermal fluids at a late stage of the ore-forming event. The shifts to higher87Sr/86Sr ratios and lower δ18O values in the altered fluor-apatite indicate that the alteration was induced by fluids with more radioactive Sr and lighter O isotope signatures. The metasomatic fluids were likely dominated by meteoric waters that were mixed with the earlier magmatic fluids and interacted with sedimentary rocks. Our study highlights that elemental and isotopic compositions of fluorapatite can be significantly modified by hydrothermal fluids during ore-forming events. Thus, instead of traditional bulk-rock analysis, in situ microanalysis is important to provide accurate constraints on the magmatic and/or hydrothermal evolution of complex ore-forming systems.

Erratum to: Coupling thermodynamic modeling and high-resolution in situ LA-ICP-MS monazite geochronology: evidence for Barrovian metamorphism late in the Grenvillian history of southeastern Ontario

The Flinton Group is a greenschist to upper amphibolite facies package of metasediments in southeastern Ontario that was metamorphosed during the Ottawan Orogeny. Thermodynamic modeling of metapelitic mineral assemblages suggests an increase in peak conditions of metamorphism across the 40 km wide study area from 3.5 to 7.9 kbar and 540 to 715 °C. Garnet isopleth thermobarometry applied to the cores of compositionally zoned porphyroblasts reveals remarkably similar P-T conditions of initial crystallization at approximately 3.7–4.0 kbar and 512–520 °C, corresponding to a relatively high geothermal gradient of ca. 34–45 °C km−1. It is inferred from modeling and reaction textures that metamorphism was along Barrovian P-T paths. Major and trace element zoning in garnet from one sample records a complex growth history as evidenced by major and trace element zoning and the distribution of xenotime, allanite and monazite inclusions. High-resolution (6 μm) LA-ICP-MS U-Pb geochronology performed on monazite in the rock matrix and included in the outer 150 μm of garnet rim-ward of a Y annulus revealed an age of 976 ± 4 Ma. The age is interpreted to reflect monazite growth at the expense of allanite and apatite late in garnet’s growth history over the P-T interval 4.5–6.8 kbar and 540–640 °C. This new age estimate for near peak metamorphism fits well into the regional framework but is significantly younger than previously reported ages for Ottawan metamorphism. Based on microstructures this new age suggests that compressional tectonics were operating much later in the history of the Grenville of southeastern Ontario than previously thought.