Chun Kwan Tsang

Electrochemical doping of anatase TiO2 in organic electrolytes for high-performance supercapacitors and photocatalysts

In this article, we report a facile electrochemical method to modify anatase TiO2 by cathodically biasing TiO2 in an ethylene glycol electrolyte. The resulting black TiO2 is highly stable with a significantly narrower bandgap and higher electrical conductivity. Furthermore, largely improved photoconversion efficiency (increased from 48% to 72% in the visible region, and from nearly 0% to 7% in the UV region), photocatalytic efficiency, and charge-storage capability (∼42 fold increase) are achieved for the treated TiO2.

Highly Stable Porous Silicon–Carbon Composites as Label-Free Optical Biosensors

A stable, label-free optical biosensor based on a porous silicon-carbon (pSi-C) composite is demonstrated. The material is prepared by electrochemical anodization of crystalline Si in an HF-containing electrolyte to generate a porous Si template, followed by infiltration of poly(furfuryl) alcohol (PFA) and subsequent carbonization to generate the pSi-C composite as an optically smooth thin film. The pSi-C sensor is significantly more stable toward aqueous buffer solutions (pH 7.4 or 12) compared to thermally oxidized (in air, 800 °C), hydrosilylated (with undecylenic acid), or hydrocarbonized (with acetylene, 700 °C) porous Si samples prepared and tested under similar conditions. Aqueous stability of the pSi-C sensor is comparable to related optical biosensors based on porous TiO(2) or porous Al(2)O(3). Label-free optical interferometric biosensing with the pSi-C composite is demonstrated by detection of rabbit IgG on a protein-A-modified chip and confirmed with control experiments using chicken IgG (which shows no affinity for protein A). The pSi-C sensor binds significantly more of the protein A capture probe than porous TiO(2) or porous Al(2)O(3), and the sensitivity of the protein-A-modified pSi-C sensor to rabbit IgG is found to be ~2× greater than label-free optical biosensors constructed from these other two materials.

Selective Removal of the Outer Shells of Anodic TiO2 Nanotubes

A facile electrochemical method to selectively remove the outer walls of anodic TiO(2) nanotubes by leaving the as-anodized nanotubes in the same electrolyte and applying an electric field parallel to the anodic film for several minutes is reported. The better-separated single-walled TiO(2) nanotubes thus obtained show significantly improved photocatalytic efficiency compared with their non-etched counterparts.

Rugated porous Fe3O4 thin films as stable binder-free anode materials for lithium ion batteries

Rugated porous Fe3O4 thin films were synthesized by a facile multi-pulse electrochemical anodization method. The fabricated Fe3O4 films are directly grown on Fe, featuring nano-channels with periodically rugated channel walls running throughout the film thickness direction. Electrochemical measurements show that the as-prepared Fe3O4 films readily serve as high-performance anode materials for lithium ion batteries with a specific capacity of 1100, 880 and 660 mA h g−1 at 0.1, 0.2, and 0.5 C, respectively, which compared favorably with the conventional straight-channel counterparts fabricated by DC anodization. Moreover, the cycling capability test of the novel electrode at 0.1 C for 100 cycles shows a steady charge/discharge platform, indicating a high cycling stability and structural robustness. The observed improvements of the rugated Fe3O4 films as lithium ion battery anode materials are attributed to their special periodic rugated nanostructures.

Metal-Based Photonic Coatings from Electrochemical Deposition

Plasmonic materials offer the remarkable ability to manipulate light by metal―dielectric features significantly smaller than the wavelengths of free space photons. The fabrication of such minuscule features for the desired plasmonic properties, however, remains challenging. Here, we report an economical and versatile bottom-up approach that combines electrodeposition and de-alloying techniques for fabricating elaborate metal-based structures, achieving structural resolutions comparable to the present lithography techniques. We present our studies on the metal-based counterpart of the rugate filter. These metal-based photonic films are porous, magnetic, and feature strong optical responses in visible wavelengths, while their structural periodicities are an order of magnitude smaller than the lights free space wavelength.

Porous metal-based multilayers for selective thermal emitters

We report the numerical study of a selective thermal emitter based on a metallic multilayered structure consisting of a graded antireflection top layer, a middle layer with uniform porosity (i.e., volume fraction of voids), and a nonporous substrate layer. Simulation results show that the proposed emitters feature an emission edge in near-IR where the emissivity drops from over 0.9 to below 0.1, for both the TE and TM polarizations. Moreover, these desired emission characteristics persist for a wide range of emission angles with the emission edge nearly nonshifted, making the proposed emitters promising for achieving isotropic thermal emission. The designed emitters are particularly attractive for the thermal-photovoltaic applications by suppressing emission below the photovoltaic material bandgap, which is normally in near-IR.