Chun-Wei Chen

Red, Green and Blue Reflections Enabled in an Optically Tunable Self‐Organized 3D Cubic Nanostructured Thin Film

A new light-driven chiral molecular switch doped in a stable blue phase (BP) liquid crystal allows wide optical tunability of three-dimensional cubic nanostructures with a selective reflection wavelength that is reversibly tuned through the visible region. Moreover, unprecedented reversible light-directed red, green, and blue reflections of the self-organized three-dimensional cubic nanostructure in a single film are demonstrated for the first time. Additionally, unusual isothermal photo-stimulated less ordered BP II to more ordered BP I phase transition was observed in the system.

Random lasing in blue phase liquid crystals

Random lasing actions have been observed in optically isotropic pure blue-phase and polymer-stabilized blue-phase liquid crystals containing laser dyes. Scattering, interferences and recurrent multiple scatterings arising from disordered platelet texture as well as index mismatch between polymer and mesogen in these materials provide the optical feedbacks for lasing action. In polymer stabilized blue-phase liquid crystals, coherent random lasing could occur in the ordered blue phase with an extended temperature interval as well as in the isotropic liquid state. The dependence of lasing wavelength range, mode characteristics, excitation threshold and other pertinent properties on temperature and detailed make-up of the crystals platelets were obtained. Specifically, lasing wavelengths and mode-stability were found to be determined by platelet size, which can be set by controlling the cooling rate; lasing thresholds and emission spectrum are highly dependent on, and therefore can be tuned by temperature.

Temperature dependence of refractive index in blue phase liquid crystals

The refractive indices of a class of Blue-Phase liquid crystals (BPLCs) and their temperature dependence have been measured and analyzed. In general, the thermal index gradients in blue phases, BPI and BPII, are both larger than in isotropic liquid state; the index gradient of BPII phase is steeper than that of BPI, and is attributed to the difference between the expansion coefficients of simple and body-centered cubic lattices. Besides their obvious importance in photonics and nonlinear optical processes and applications, the investigation of the phase dependence of the index gradient also provides a useful way for phase identification of BPLCs, namely the second-order and weakly first order phase transitions corresponding to the ISO/BPII transition and the BPII/BPI transition.

Direction switching and beam steering of cholesteric liquid crystal gratings

This work proposes two mechanisms for switching the direction of stripes in cholesteric liquid crystal (CLC) gratings. The stripe direction depends on the ratio of cell gap to the natural pitch length (d/P0) of a CLC sample. Electrical switching is based on the different pitches at the planar and the transient planar states. Optical switching, however, changes pitch by using the photo-isomerization effect of the azobenzene doped in a CLC sample. Using the two mechanisms, we can switch the stripe directions in two orthogonal directions. Furthermore, the beam-steering capability of CLC gratings also remains effective after switching directions.

Bistable cholesteric liquid crystal light shutter with multielectrode driving

An electrically activated bistable light shutter that exploits polymer-stabilized cholesteric liquid crystal film was developed. Under double-sided three-terminal electrode driving, the device can be bistable and switched between focal conic and homeotropic textures with a uniform in-plane and vertical electrical field. The transparent state with a transmittance of 80% and the opaque/scattering state with a transmittance of 13% can be realized without any optical compensation film, and each can be simply switched to the other by applying a pulse voltage. Also, gray-scale selection can be performed by varying the applied voltage. The designed energy-saving bistable light shutter can be utilized to preserve privacy and control illumination and the flow of energy.

Nonlinear Optics of Nematic and Blue Phase Liquid Crystals

We present a critical reexamination of individual electronic and collective optical nonlinearities of nematic liquid crystals (NLC) in the context of all-optical transmission switching of femtoseconds – CW lasers, and report recent observations of similar optical nonlinearities in Blue-phase liquid crystals (BPLC) and their utilization in feasibility demonstrations of polarization-free nonlinear grating diffraction and transmission switching of CW as well as pulsed lasers.

Polarization-independent bistable light valve in blue phase liquid crystal filled photonic crystal fiber

This article demonstrates a bistable optical valve in a photonic liquid crystal fiber using the thermal hysteresis effect of the phase transition between the cholesteric phase and the blue phase (BP). The attenuation is due to various scattering losses in different phases. Both cholesteric and BPs can exist stably at room temperature (RT) and can also be switched to each other using temperature-control processes. The transmission spectrum and the intensity of the guided light can be controlled with various extents of scattering loss. For optical communications, this device can be manipulated over a loss difference of 10 dB at RT and insensitive to the polarization of light.

High efficiency holographic Bragg grating with optically prolonged memory.

In this paper, we show that photosensitive azo-dye doped Blue-phase liquid crystals (BPLC) formed by natural molecular self-assembly are capable of high diffraction efficiency holographic recording with memory that can be prolonged from few seconds to several minutes by uniform illumination with the reference beam. Operating in the Bragg regime, we have observed 50 times improvement in the grating diffraction efficiency and shorter recording time compared to previous investigations. The enabling mechanism is BPLC’s lattice distortion and index modulation caused by the action of light on the azo-dopant; upon photo-excitation, the azo-molecules undergo transformation from the oblong-shaped Trans-state to the bent-shaped Cis-state, imparting disorder and also cause the surrounding BPLC molecules to undergo coupled flow & reorientation leading to lattice distortion and index modulation. We also showed that the same mechanism at work here that facilitates lattice distortion can be used to frustrate free relaxation of the lattice distortion, thereby prolonging the lifetime of the written grating, provided the reference beam is kept on after recording. Due to the ease in BPLC fabrication and the availability of azo-dopants with photosensitivity throughout the entire visible spectrum, one can optimize the controlling material and optical parameters to obtain even better performance.

Ultrafast pulse compression, stretching-and-recompression using cholesteric liquid crystals

We have experimentally demonstrated the feasibility of direct compression, or stretching and recompression of laser pulses in a very wide temporal time scale spanning 10s fs to ~1 ps time with sub-mm thick cholesteric liquid crystal (CLC) cells. The mechanisms at work here are the strong dispersion at the photonic band-edges and nonlinear phase modulation associated with the non-resonant ultrafast molecular electronic optical nonlinearity. The observed pulse compression limit, spectral characteristics and intensity dependence of the compression are in good agreement with theoretical expectations and simulations based on a coupled-mode propagation model. Owing to the large degree of freedom to engineer the wavelength locations of CLC photonic bandgap and band-edges, these self-action all-optical processes can be realized with ultrafast lasers pulses in a very wide spectral region from the visible to near infrared, with potential applications in compact ultrafast photonic modulation devices/platforms.

Study of electro-optical properties of templated blue phase liquid crystals

A templating technique is proposed for improving the electro-optical properties of polymer stabilized blue phase (PSBP). After polymerizing a monomer-doped blue phase, the remaining chiral nematic liquid crystal was removed to create a porous free-standing cast that retained the 3D structure of the blue phase. The effects of the helical twisting power of the filling mesogen on the electro-optical properties of PSBP were studied. The driving voltage effectively declined as the proportion of chiral dopant in the filling material was decreased. Because of the achiral mesogen tended to be less twisted intrinsically, the elastic restoring force helped the electric field to unwind the helical structure, which was supported by the polymer anchoring force. Replacing the chiral agent with a reverse-handed chiral further reduced the driving voltage by 40% and doubled the value of the resulting figure of merit.