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Acta Crystallographica Section C-crystal Structure Communications | 1985

Structure of the red macrocyclic ligand complex diaqua[(1SR,2SR,4RS,7RS,8RS,9RS,11SR,14SR)-2,5,5,7,9,12,12,14-octamethyl-1,4,8,11-tetraazacyclotetradecane]copper(II) perchlorate

Tsong-Jen Lee; Tseng-Yuh Lee; Wen-Bii Juang; Chung-Sun Chung

Cu(C 18H40N4)(H20)2) (C104) 2, M,, = 611.03, monoclinic, P2t/c, a=8.201 (1), b= 16.082(3), c = 10.432(1)A, fl= 103.30(1) °, U= 1338.9A 3, Z =2, Dx= 1.515, Din: 1.50(3)Mgm -3 (by flotation in CC14/hexane mixture), Mo Kcq 2 = 0.71069 A, u = 1-105 mm -~, F(000) = 647, T = 296 (4) K, R(F) = 0.069 for 2828 observed reflections II > 3a(/)l. The coordination about Cu u is a tetragonally distorted octahedron with the macrocycle equatorial and the two water O atoms axial. This complex is centrosymmetric and has the (ISR,4RS,8RS,1 1SR) configuration for the chiral N centers. The six-membered chelate rings exhibit a chair form and the five-membered rings take gauche forms.


Acta Crystallographica Section C-crystal Structure Communications | 1986

Structure of aqua[(1SR,4RS,8SR,11RS)-1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane]copper(II) perchlorate monohydrate

Tsong-Jen Lee; Tseng-Yuh Lee; Ching-You Hong; Der-Thing Wu; Chung-Sun Chung


Acta Crystallographica Section C-crystal Structure Communications | 1984

Structures of copper(II) complexes with N,N'-bis(β-carbamoylethyl)ethylenediamine and its deprotonated form, [Cu(NO3)(C8H18N4O2)(H2O)].NO3.H2Oand [Cu(C8H16N4O2)(H2O)].H2O

Tsong-Jen Lee; T.-H. Lu; S.-H. Liu; Chung-Sun Chung; Tseng-Yuh Lee


Acta Crystallographica Section C-crystal Structure Communications | 1985

Structure of a Red Macrocyclic Ligand Complex

Tsong-Jen Lee; Tseng-Yuh Lee; Wen-Bii Juang; Chung-Sun Chung


Acta Crystallographica Section C-crystal Structure Communications | 1987

{Aqua[N,N'-bis(β-carbamoylethyl)trimethylenediamine]perchlorato}copper(II) perchlorate monohydrate

Ching-You Hong; Tseng-Yuh Lee; Tsong-Jen Lee; Min-Shiun Chao; Chung-Sun Chung


Acta Crystallographica Section C-crystal Structure Communications | 1986

Structure of [N,N'-bis(3-aminopropyl)-1,2-ethanediamine]perchloroatocopper(II) perchlorate hemihydrate

Tseng-Yuh Lee; Tsong-Jen Lee; Ching-You Hong; Ming-Yei Hsieh; Der-Thing Wu; Chung-Sun Chung


Acta Crystallographica Section C-crystal Structure Communications | 1991

Structure of (isothiocyanato)[3,3,9,9-tetramethyl-4,8-diazaundecane-2,10-dione dioximato(1−)]copper(II) monohydrate

Tsong-Jen Lee; Tseng-Yuh Lee; Chung-Sun Chung; Yun-Ming Wang


Acta Crystallographica Section C-crystal Structure Communications | 1986

Structure of [(1RS,4RS,7RS,8SR,11SR,14SR)-1,4,5,5,7,8,11,12,12,14-decamethyl-1,4,8,11-tetraazacyclotetradecane]nickel(II) perchlorate

Tseng-Yuh Lee; Ming-Yei Hsieh; Tsong-Jen Lee; Jy-Wann Chen; Chung-Sun Chung


Acta Crystallographica Section C-crystal Structure Communications | 1985

Structure of {diaqua[N,N'-bis(β-carbamoylethyl)-2-hydroxytrimethylenediamine]}nickel(II) dichloride, [Ni(C9H20N4O3)(H2O)2]Cl2

Tseng-Yuh Lee; Ching-You Hong; Tsong-Jen Lee; S.-H. Liu; Chung-Sun Chung


Acta Crystallographica Section C-crystal Structure Communications | 1984

Structure of [N,N'-bis(β-carbamoylethyl)-2-hydroxytrimethylenediamine]copper(II) perchlorate, [Cu(C9H20N4O3)](ClO4)2

Tsong-Jen Lee; Ching-You Hong; S.-H. Liu; Chung-Sun Chung; Tseng-Yuh Lee

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