Claire Weiss

A New Proprietary Hybrid-Solvent Process for Improved Mercaptan Removal

This paper (SPE 145501) was accepted for presentation at the International Petroleum Technology Conference, Doha, Qatar, 7–9 December 2009, and revised for publication. Original manuscript received for review 9 February 2010. Revised manuscript received for review 10 November 2010. Paper peer approved 7 January 2011. Summary Removing mercaptans from sour natural gas has always been considered a challenge. This is becoming an even more important issue with the global trend toward more-stringent specifications for commercial gases. Amines have been used extensively because of their ability to meet the most severe H2S and CO2 specifications and their very high acid-gas selectivity over hydrocarbons, but they present very limited mercaptans-removal performances. They require an additional treatment step to achieve the total sulfur-content specification in the exported gas. Hybrid solvents are more efficient in removing mercaptans but have the disadvantage of poor acid-gas selectivity over hydrocarbons, resulting in hydrocarbon losses with the separated acid gases. Total, taking advantage of its extensive knowledge and experience in acid-gas removal with amine mixtures, has developed a new proprietary hybrid-solvent formulation allowing simultaneous absorption of acid gases and of mercaptans, with limited coabsorption of hydrocarbons. (The new hybrid solvent process is Total’s proprietary process known as the HySWEET process, which is a registered trademark.) The solvent was selected at the laboratory scale, with a particular attention given to operation-related constraints (e.g., cost, corrosion, foaming, degradation). The new solvent’s acid-gasand mercaptans-removal performances were then validated on a pilot rig. The performance of the process has been assessed for several field applications and compared with the performances of conventional amine processes. This allowed evaluating the potential gain achievable by the implementation of the new hybrid solvent. The study identifies the application cases for which the new hybrid solvent will allow an economic and complete mercaptan removal without any additional treatment and identifies the perspective reduction of these additional treatments for the other cases. Besides an economical mercaptan removal, the new hybrid solvent allows a significant reduction in the energy consumption. The results of the technoeconomic evaluation of the process have been confirmed during the first successful industrial application at the Lacq sour-gas plant in 2008. Half of the gas production is now treated with the hybrid solvent, allowing the plant to achieve high global mercaptans removal. These results are fully documented in the paper, demonstrating that the newly developed process is a good contender for the development of new sour-gas fields to achieve the increasingly stringent commercial gas specifications.

Industrial Operation of HySWEET®, a New Hybrid Solvent for Improved Mercaptan Removal

Publisher Summary Solvent-based deacidification processes are very well suited to the removal of H2S and CO2 from large quantities of sour gases, but generally require an additional treatment step to achieve the specification for total sulphur content in the exported gas. Amines have been extensively used because of their ability to meet the most severe H2S and CO2 specifications and their very high acid-gas selectivity over hydrocarbons, but their performances as regards mercaptan removal are extremely limited. Hybrid solvents are more efficient in removing mercaptans, but have the disadvantage of poor acid-gas selectivity over hydrocarbons, with the result that some of the hydrocarbons are lost with the separated acid gases. On the strength of its extensive knowledge and experience in acid gas removal with amine mixtures, Total has developed a new hybrid solvent formulation that offers simultaneous absorption of acid gases and mercaptans, with limited coabsorption of hydrocarbons. The solvent was selected at the laboratory stage, focusing specially on operational constraints such as cost, corrosion, foaming, and degradation.

Down Hole Sulphur Removal and Recovery

Total and CrystaTech are developing a regenerable solvent based process to prevent the formation of sulphur deposition during production in natural gas well bores or even in the surface circuits and facilities. While producing gas from certain formations, solid sulphur has been observed to deposit on the well tubing which causes gas production to diminish and ultimately stop. Such scenarios can result in production time losses ranging from one day for batch treatment to three days for coiled tubing cleaning.