Cláudio Pereira Jordão

ASSESSMENT OF WATER SYSTEMS FOR CONTAMINANTS FROM DOMESTIC AND INDUSTRIAL SEWAGES

The State of Minas Gerais represents one of Brazils most outstanding mining resources. The contamination of river waterfrom kaolin processing activities may be harmful to people inthe way of slow but chronic poisoning. On the other hand, the discharge of untreated or inadequately treated domestic sewage into aquatic environments can also cause deleterious effects to the health. However, no reliable figures are available for pollutant occurrences in river water. This draws attention to thevery precarious situation that exists with respect to pollutionby organic and inorganic toxic wastes, especially with respect to humans and fauna in all its expressions. Thus, with the purpose of establishing a preliminary report to trace out industrialisation outcomes, samples of river water, vegetation and fish were collected and analysed to detect pollutant inputs.The concentration of metals was determined in suspended particle,vegetation and fish, while those of nitrite, nitrate, phosphateand chloride were determined in river water samples. The concentration of dissolved oxygen (DO) was measured in river water at the time of collection. Chemical oxygen demand (COD) and biochemical oxygen demand (BOD) were also determined. Metalinputs in the samples analysed appeared to be related to effluentdischarges into the rivers. The suspended particles showed highconcentrations (in mg kg-1) of zinc (62 600) and aluminium(559 000), while vegetation samples collected near rivers wereheavily contaminated with iron (7680). The fishes examined werecontaminated with chromium (1.5 mg kg-1). In general, the concentrations of nitrite, nitrate, chloride, phosphate and BOD in river water were lower than the maximum values established bythe Brazilian Environmental Standards.

Concentrações de selênio em alimentos consumidos no Brasil

OBJECTIVE To determine the selenium content of foods consumed in Brazil. METHODS The project was carried out between 1993 and 1999. The food samples were collected in stores in several Brazilian states. The levels of selenium were determined by hydride generation atomic absorption spectrophotometry and by wet oxidation. RESULTS The highest levels of selenium were found in animal products, especially fish, and in wheat products. We found that plant products generally had selenium levels of less than 5.0 micrograms/100 g. CONCLUSIONS In Brazil a diet rich in animal products, especially fish, is important in ensuring consumption of the recommended levels of selenium.Objetivo. Determinar os teores de selenio em alimentos consumidos no Brasil. Metodos. O trabalho foi desenvolvido de 1993 a 1999. As amostras de alimentos foram coletadas no comercio varejista em varios estados do Brasil. Os teores de selenio foram determinados por meio de espectrofotometria de absorcao atomica, utilizando-se a tecnica de geracao de hidretos, e oxidacao da materia orgânica por via umida. Resultados. Os teores mais elevados de selenio foram encontrados nos produtos de origem animal, sobretudo nos pescados, e nos produtos derivados do trigo. Observou-se que os teores de selenio nos alimentos de origem vegetal foram, de modo geral, inferiores a 5,0 µg/100g. Conclusoes. No Brasil, a presenca de pescados, principalmente, e de outros produtos de origem animal e importante na dieta para garantir o consumo dos teores recomendados de selenio.

REMOVAL OF Cu, Cr, Ni, Zn, AND Cd FROM ELECTROPLATING WASTES AND SYNTHETIC SOLUTIONS BY VERMICOMPOST OF CATTLE MANURE

ABSTRACT This study was undertaken to evaluate the retention of Cu, Cr, Ni, Zn, and Cd under laboratory conditions from synthetic solution and electroplating wastes by vermicompost. A glass column was loaded with vermicompost, and metal solutions were passed through it. Metal concentrations were then measured in the eluate in order to evaluate the amounts retained by the vermicompost. Measurements of pH, metal concentrations, moistness, organic matter and ash contents, and infrared and XRD spectroscopy were used for vermicompost characterisation. Vermicompost residues obtained from this process were used for plant nutrition in eroded soil collected from a talus near a highway. Metal retention (in g of metal/kg of vermicompost) from effluents ranged from 2 for Cr and Zn to 4 in the case of Ni. In synthetic solutions, the values for metal retention were 4 for Cd and Zn, 6 for Cu and Ni, and 9 for Cr. The results also showed that metal concentrations in the purified effluents were below the maximum values established for waste discharges into rivers by the Brazilian Environmental Standards. The relatively high available Cd concentration of the vermicompost residue resulted in plant damage. This effect was attributed to the presence of Cd in the synthetic solution passed through the vermicompost. The data obtained do not give a complete picture of using vermicompost in cultivated lands, but such values as are determined do show that it can be suitable to remove heavy metals from industrial effluents.

Zn(II) adsorption from synthetic solution and kaolin wastewater onto vermicompost

The adsorption of Zn(II) from both synthetic solution and kaolin industry wastewater by cattle manure vermicompost was studied. The adsorption process was dependent on the various operating variables, viz., solution pH, particle size of the vermicompost, mass of vermicompost/volume of the Zn(II) solution ratio, contact time and temperature. The optimum conditions for Zn adsorption were pH 6.0, particle size of < or = 250 microm, 1 g per 10 mL adsorbent dose, contact time of 4h and temperature of 25 degrees C. Langmuir and Freundlich adsorption isotherms fit well in the experimental data and their constants were evaluated, with R(2) values from 0.95 to 0.99. In synthetic solution, the maximum adsorption capacity of the vermicompost for Zn(2+) ions was 20.48 mg g(-1) at 25 degrees C when the vermicompost dose was 1 g 10 mL(-1) and the initial adjusted pH was 2. The batch adsorption studies of Zn(II) on vermicompost using kaolin wastewater have shown the maximum adsorption capacity was 2.49 mg g(-1) at pH 2 (natural pH of the wastewater). The small values of the constant related to the energy of adsorption (from 0.07 to 0.163 L mg(-1)) indicated that Zn(2+) ions were binded strongly to vermicompost. The values of the separation factor, R(L), which has been used to predict affinity between adsorbate and adsorbent were between 0 and 1, indicating that sorption was very favorable for Zn(II) in synthetic solution and kaolin wastewater. The thermodynamic parameter, the Gibbs free energy, was calculated for each system and the negative values obtained confirm that the adsorption processes are spontaneous. The DeltaG degrees values were -19.656 kJ mol(-1) and -16.849 kJ mol(-1) for Zn(II) adsorption on vermicompost in synthetic solution at pH 6 and 2, respectively, and -13.275 kJ mol(-1) in kaolin wastewater at pH 2.

Contaminação por crômio de águas de rios proveniente de curtumes em Minas Gerais

In order to evaluate the chromium contamination from tannery discharges into rivers in the State of Minas Gerais, samples of water and suspended material were collected and submitted to chemical analysis. The total content of chromium in the samples was measured by flame atomic absorption spectrophotometry. Water samples were analysed by standard addition method, while chromium concentration in suspended materials was determined by calibration curves. Localities investigated were Ipatinga, Matias Barbosa, Dores de Campo, Ressaquinha, Uba and Juiz de Fora. Samples from a not-industrialized area were also analysed to obtain regional background values. Metal inputs were related to effluent discharges into the rivers. Suspended material transported Cr downriver. Chromium concentration in river water exceeded 656 times the value of the Brazilian Environmental Standards, while its concentration in suspended material ranged from 15 to 11066 µg g-1.

Caracterização química e física de vermicomposto e avaliação de sua capacidade em adsorver cobre e zinco

The physical and chemical characterization of vermicompost from bovine manure has been studied. It was examined the pH and cation exchangeable capacity (CEC), organic matter content, electric conductivity and elementary and XRD analyses, among other characteristics. The vermicompost was then applied to the retention and competition of metal micronutrients and pollutants (Cu and Zn) from metal nitrate solutions. The retention was affected by both the pH and adsorption time, while the competitive character of these metals for the substrate was relevant to each pH examined.

Evaluation of metal concentrations in edible vegetables grown in compost amended soil

Agricultural uses of compost usually have a positive effect on the yield of vegetable crops for human consumption. However, compost that contains heavy metals can transfer these components to soils and plants. To evaluate the contamination levels of metals in soil, compost, and edible vegetables, the Mn, Zn, Pb, Cd, Cu, and Ni total contents were measured. Metal availability in soils, as well as other variables – the pH, CEC (cation exchange capacity), total nitrogen, organic carbon, particle size distribution and mineralogy of the clay fraction – were examined in the soil samples. The analysed compost samples were produced from urban solid waste, cattle manure, and edible vegetable and tree pruning residues. The values of pH, CEC, total nitrogen, organic matter, exchangeable hydrogen and carboxylic groups were measured in the compost samples. Of the six metals examined in the soils, in general, Mn and Zn attained the highest concentrations, followed by Cu. Relatively high Mn, Zn, Cu, Cd and Pb concentrations were found in the soils. Metal concentrations extracted with DTPA were below the critical levels in soils, i.e. the levels above which toxicity is likely. In general, Zn, Pb, Cd, Cu and Ni concentrations in compost were lower than those reported by other workers, while Mn levels were within the range for this metal in compost. The results showed that there was an effect of the vegetable type (p < 0.01) for all the parameters examined. High Pb concentrations were found in lettuce and chive as compared with the tolerance limit for this metal in fresh vegetables in Brazil. Cadmium concentrations were also enhanced in the fresh vegetables compared with the typical concentrations of metals in plants. Zinc, Cu, Cd, and Ni concentrations were lower than the tolerance limits established for foods by the Brazilian legislation.

Distribution of Heavy Metals in Environmental Samples Near Smelters and Mining Areas in Brazil

The State of Minas Gerais possesses one of Brazils important smelting resources. Aquatic contamination produced from mining activities and smelting of ores in the region may be harmful to the human population. However, no studies on levels of heavy metal have been carried out in the area. Thus, to assess the extent of pollution resulting from the metalliferous industry, river water, sediment, plant and fish samples were collected up- and down-river from the smelters and mining areas in Conselheiro Lafaiete and Ouro Branco and analysed to detect metal inputs. Samples of mineralized, contaminated and non-contaminated regions were also collected in the State of Minas Gerais to obtain control values. The metals examined included Fe, Al, Mn, Pb, Cu, Zn, Co, Cd, Ni, and Cr and were selected due to their toxicity and occurence in ores. Metal inputs in the samples analysed appeared to be related to effluent discharges into the rivers. High concentrations (in µg l−1) of Mn (697), Pb (153) and Cd (12.7) were found...

Metal contamination of river waters and sediments from effluents of kaolin processing in Brazil

In order to evaluate the metal contamination from kaolin industry discharges into rivers in the State of Minas Gerais, Brazil, samples of river water and fluvial sediment were collected up- and down-river from the industries and analysed todetect metal inputs. The metal examined included zinc, iron, andaluminium among others, being selected due to their toxicity andoccurence in waste waters. Metal inputs in the samples analysed appeared to be related to effluent discharges into the rivers. The river water showed high concentrations (in μg mL-1) of Zn (355), Fe (354) and Al (303). Sediment investigations indicated heavy enrichment (SEF = 9.4) for Zn. The Geoaccumulation Index for this element accounted for 3 (moderately to heavy polluted). River water pH of the sample collected near the effluent discharge site reached 3.7, suggesting inadequate treatment.

Influence of domestic and industrial waste discharges on water quality at Minas Gerais State, Brazil

The aquatic contamination from kaolin processing plants, as well as from untreated or inadequately treated municipal sewage, was evaluated in the Uba Stream and Vermelho Stream, at the Minas Gerais State, Brazil. With this purpose, samples of water, suspended material and vegetation were collected and analysed. The analyses involved the determination of the concentration of metals, nitrite, nitrate, chloride, phosphate, chemical oxygen demand and biochemical oxygen demand. The suspended material showed high concentrations (in mg kg-1) of Zn (2,400) and Fe (14,900), while the vegetation collected closed to the streams was heavily contaminated with Al (7,120). The concentrations of nitrite, nitrate and chloride in stream water were lower than the maximum values established by the Brazilian Environmental Standards. The phosphate and biochemical oxygen demand values exceeded 7 and 3 times respectively, the maximum concentrations for superficial water of satisfactory quality.