Clayton DeVault

Roadmap on optical metamaterials

Optical metamaterials have redefined how we understand light in notable ways: from strong response to optical magnetic fields, negative refraction, fast and slow light propagation in zero index and trapping structures, to flat, thin and perfect lenses. Many rules of thumb regarding optics, such as mu = 1, now have an exception, and basic formulas, such as the Fresnel equations, have been expanded. The field of metamaterials has developed strongly over the past two decades. Leveraging structured materials systems to generate tailored response to a stimulus, it has grown to encompass research in optics, electromagnetics, acoustics and, increasingly, novel hybrid materials responses. This roadmap is an effort to present emerging fronts in areas of optical metamaterials that could contribute and apply to other research communities. By anchoring each contribution in current work and prospectively discussing future potential and directions, the authors are translating the work of the field in selected areas to a wider community and offering an incentive for outside researchers to engage our community where solid links do not already exist.

Enhanced graphene photodetector with fractal metasurface

We designed and fabricated a broadband, polarization-independent photodetector by integrating graphene with a fractal Cayley tree metasurface. Our measurements show an almost uniform, tenfold enhancement in photocurrent generation due to the fractal metasurface structure.

Effective third-order nonlinearities in metallic refractory titanium nitride thin films

Nanophotonic devices offer an unprecedented ability to concentrate light into small volumes which can greatly increase nonlinear effects. However, traditional plasmonic materials suffer from low damage thresholds and are not compatible with standard semiconductor technology. Here we study the nonlinear optical properties in the novel refractory plasmonic material titanium nitride using the Z scan method at 1550 nm and 780 nm. We compare the extracted nonlinear parameters for TiN with previous works on noble metals and note a similarly large nonlinear optical response. However, TiN films have been shown to exhibit a damage threshold up to an order of magnitude higher than gold films of a similar thickness, while also being robust, cost-efficient, bio- and CMOS compatible. Together, these properties make TiN a promising material for metal-based nonlinear optics.

Controlling the Polarization State of Light with Plasmonic Metal Oxide Metasurface

Conventional plasmonic materials, namely, noble metals, hamper the realization of practical plasmonic devices due to their intrinsic limitations, such as lack of capabilities to tune in real-time their optical properties, failure to assimilate with CMOS standards, and severe degradation at increased temperatures. Transparent conducting oxide (TCO) is a promising alternative plasmonic material throughout the near- and mid-infrared wavelengths. In addition to compatibility with established silicon-based fabrication procedures, TCOs provide great flexibility in the design and optimization of plasmonic devices because their intrinsic optical properties can be tailored and dynamically tuned. In this work, we experimentally demonstrate metal oxide metasurfaces operating as quarter-waveplates (QWPs) over a broad near-infrared (NIR) range from 1.75 to 2.5 μm. We employ zinc oxide highly doped with gallium (Ga:ZnO) as the plasmonic constituent material of the metasurfaces and fabricate arrays of orthogonal nanorod pairs. Our Ga:ZnO metasurfaces provide a high degree of circular polarization across a broad range of two distinct optical bands in the NIR. Flexible broad-band tunability of the QWP metasurfaces is achieved by the significant shifts of their optical bands and without any degradation in their performance after a post-annealing process up to 450 °C.

Controlling hybrid nonlinearities in transparent conducting oxides via two-colour excitation

Nanophotonics and metamaterials have revolutionized the way we think about optical space (ε,μ), enabling us to engineer the refractive index almost at will, to confine light to the smallest of the volumes, and to manipulate optical signals with extremely small footprints and energy requirements. Significant efforts are now devoted to finding suitable materials and strategies for the dynamic control of the optical properties. Transparent conductive oxides exhibit large ultrafast nonlinearities under both interband and intraband excitations. Here we show that combining these two effects in aluminium-doped zinc oxide via a two-colour laser field discloses new material functionalities. Owing to the independence of the two nonlinearities, the ultrafast temporal dynamics of the material permittivity can be designed by acting on the amplitude and delay of the two fields. We demonstrate the potential applications of this novel degree of freedom by dynamically addressing the modulation bandwidth and optical spectral tuning of a probe optical pulse.

Optical absorption of hyperbolic metamaterial with stochastic surfaces

We investigate the absorption properties of planar hyperbolic metamaterials (HMMs) consisting of metal-dielectric multilayers, which support propagating plane waves with anomalously large wavevectors and high photonic-density-of-states over a broad bandwidth. An interface formed by depositing indium-tin-oxide nanoparticles on an HMM surface scatters light into the high-k propagating modes of the metamaterial and reduces reflection. We compare the reflection and absorption from an HMM with the nanoparticle cover layer versus those of a metal film with the same thickness also covered with the nanoparticles. It is predicted that the super absorption properties of HMM show up when exceedingly large amounts of high-k modes are excited by strong plasmonic resonances. In the case that the coupling interface is formed by non-resonance scatterers, there is almost the same enhancement in the absorption of stochastically perturbed HMM compared to that of metal.

Dynamic nanophotonics [Invited]

The field of integrated plasmonics is multifaceted in a way that few other disciplines in applied science are, mainly due to its intrinsic “hybrid” nature of combining materials and strategies borrowed from electronics and photonics. Because of the multitude of angles under which the plasmonic world could be analyzed, and also because of the intrinsic interest behind this branch of physics, numerous review papers have been recently published with the attempt to exhaustively describe this subject and its possible future developments. However, despite the considerable literature already available, a few important aspects deserve a deeper investigation. Among these dark spots we find the lack of a general overview of active plasmonics, specifically focused on the possibility to dynamically alter the optical properties of the constituent plasmonic materials in order to gain full active control over the overall desired functionality. The present review focuses on the possibility to tune the optical properties of said components, deliberately neglecting those strategies relying on the dynamic properties of the dielectric constituent. The present work also will attempt to outline experimental and multidisciplinary aspects of tunable plasmonic devices, giving only a marginal overview of telecom applications, for which considerable literature is already available.

Optical time reversal from time-dependent Epsilon-Near-Zero media

We provide an efficient surface time-reversal of the incident electric field in an ENZ material producing both phase-conjugated and negative refracted beams. The results obtained exploiting degenerate four-wave mixing show an efficiency conversion over 200%.

Material platforms for optical metasurfaces

Abstract Optical metasurfaces are judicously engineered electromagnetic interfaces that can control and manipulate many of light’s quintessential properties, such as amplitude, phase, and polarization. These artificial surfaces are composed of subwavelength arrays of optical antennas that experience resonant light-matter interaction with incoming electromagnetic radiation. Their ability to arbitrarily engineer optical interactions has generated considerable excitement and interest in recent years and is a promising methodology for miniaturizing optical components for applications in optical communication systems, imaging, sensing, and optical manipulation. However, development of optical metasurfaces requires progress and solutions to inherent challenges, namely large losses often associated with the resonant structures; large-scale, complementary metal-oxide-semiconductor-compatible nanofabrication techniques; and incorporation of active control elements. Furthermore, practical metasurface devices require robust operation in high-temperature environments, caustic chemicals, and intense electromagnetic fields. Although these challenges are substantial, optical metasurfaces remain in their infancy, and novel material platforms that offer resilient, low-loss, and tunable metasurface designs are driving new and promising routes for overcoming these hurdles. In this review, we discuss the different material platforms in the literature for various applications of metasurfaces, including refractory plasmonic materials, epitaxial noble metal, silicon, graphene, phase change materials, and metal oxides. We identify the key advantages of each material platform and review the breakthrough devices that were made possible with each material. Finally, we provide an outlook for emerging metasurface devices and the new material platforms that are enabling such devices.

Ultrafast all-optical switching in a continuous layer gap plasmon metasurface (Conference Presentation)

All-optical nanophotonic switches, not bound by the inherent RC delays of electronic circuits, have the potential to push data-processing speeds beyond the limits of Moore’s Law. This has lead to the investigation of light-matter interactions in nanostructured materials in several all-optical data processing applications. To have a true impact on the field of ultrafast data-transfer, it is important to demonstrate switching in the telecom frequency range. We have designed a continuous layer gap plasmon metasurface, comprising a layer of gold nanodisk resonators on a 20 nm film of ZnO deposited on an optically thick gold layer. The performance of the metasurface has been investigated through numerical studies, using the optical properties of as-grown gold and zinc oxide, characterized by ellipsometry. An on-off ratio of 10.6 dB has been observed in simulations. Experimental studies are underway. The findings of this research work will pave the pathway to the design of ultra-compact and ultrafast optical switches employing ultrafast, dynamically tunable metasurfaces.