Conor A. Nixon

TITAN'S SURFACE BRIGHTNESS TEMPERATURES

Radiance from the surface of Titan can be detected from space through a spectral window of low opacity in the thermal infrared at 19 μm (530 cm–1). By combining Composite Infrared Spectrometer observations from Cassinis first four years, we have mapped the latitude distribution of zonally averaged surface brightness temperatures. The measurements are corrected for atmospheric opacity as derived from the dependence of radiance on the emission angle. At equatorial latitudes near the Huygens landing site, the surface brightness temperature is found to be 93.7 ± 0.6 K, in excellent agreement with the in situ measurement. Temperature decreases toward the poles, reaching 90.5 ± 0.8 K at 87°N and 91.7 ± 0.7 K at 88°S. The meridional distribution of temperature has a maximum near 10°S, consistent with Titans late northern winter.

Isotopic Ratios in Titan's Methane: Measurements and Modeling

The existence of methane in Titan’s atmosphere (∼ 6% level at the surface) presents a unique enigma, as photochemical models predict that the current inventory will be entirely depleted by photochemistry in a timescale of ∼20 Myr. In this paper, we examine the clues available from isotopic ratios ( 12 C/ 13 C and D/H) in Titan’s methane as to the past atmosphere history of this species. We first analyze recent infrared spectra of CH4 collected by the Cassini Composite Infrared Spectrometer, measuring simultaneously for the first time the abundances of all three detected minor isotopologues: 13 CH4, 12 CH3D, and 13 CH3D. From these we compute estimates of 12 C/ 13 C = 86.5 ± 8.2 and D/H = (1.59 ± 0.33) × 10 −4 , in agreement with recent results from the Huygens GCMS and Cassini INMS instruments. We also use the transition state theory to estimate the fractionation that occurs in carbon and hydrogen during a critical reaction that plays a key role in the chemical depletion of Titan’s methane: CH4 +C 2H → CH3 +C 2H2. Using these new measurements and predictions we proceed to model the time evolution of 12 C/ 13 C and D/H in Titan’s methane under several prototypical replenishment scenarios. In our Model 1 (no resupply of CH4), we find that the present-day 12 C/ 13 C implies that the CH4 entered the atmosphere 60–1600 Myr ago if methane is depleted by chemistry and photolysis alone, but much more recently—most likely less than 10 Myr ago—if hydrodynamic escape is also occurring. On the other hand, if methane has been continuously supplied at the replenishment rate then the isotopic ratios provide no constraints, and likewise for the case where atmospheric methane is increasing. We conclude by discussing how these findings may be combined with other evidence to constrain the overall history of the atmospheric methane.

Active upper-atmosphere chemistry and dynamics from polar circulation reversal on Titan

Saturn’s moon Titan has a nitrogen atmosphere comparable to Earth’s, with a surface pressure of 1.4 bar. Numerical models reproduce the tropospheric conditions very well but have trouble explaining the observed middle-atmosphere temperatures, composition and winds. The top of the middle-atmosphere circulation has been thought to lie at an altitude of 450 to 500 kilometres, where there is a layer of haze that appears to be separated from the main haze deck. This ‘detached’ haze was previously explained as being due to the co-location of peak haze production and the limit of dynamical transport by the circulation’s upper branch. Here we report a build-up of trace gases over the south pole approximately two years after observing the 2009 post-equinox circulation reversal, from which we conclude that middle-atmosphere circulation must extend to an altitude of at least 600 kilometres. The primary drivers of this circulation are summer-hemisphere heating of haze by absorption of solar radiation and winter-hemisphere cooling due to infrared emission by haze and trace gases; our results therefore imply that these effects are important well into the thermosphere (altitudes higher than 500 kilometres). This requires both active upper-atmosphere chemistry, consistent with the detection of high-complexity molecules and ions at altitudes greater than 950 kilometres, and an alternative explanation for the detached haze, such as a transition in haze particle growth from monomers to fractal structures.

THE 12C/13C RATIO ON TITAN FROM CASSINI INMS MEASUREMENTS AND IMPLICATIONS FOR THE EVOLUTION OF METHANE

We have re-evaluated the Cassini Ion Neutral Mass Spectrometer (INMS) 12 C/ 13 C ratios in the upper atmosphere of Titan based on new calibration sensitivities and an improved model for the NH3 background in the 13 CH4 mass channel. The INMS measurements extrapolated to the surface give a 12 C/ 13 Ci n CH4 of 88.5 ± 1.4. We compare the results to a revised ratio of 91.1 ± 1.4 provided by the Huygens Gas Chromatograph Mass Spectrometer and 86.5 ± 7.9 provided by the Cassini Infrared Spectrometer and determine implications of the revised ratios for the evolution of methane in Titan’s atmosphere. Because the measured 12 C/ 13 C is within the probable range of primordial values, we can only determine an upper boundary for the length of time since methane began outgassing from the interior, assuming that outgassing of methane (e.g., cryovolcanic activity) has been continuous ever since. We find that three factors play a crucial role in this timescale: (1) the escape rate of methane, (2) the difference between the current and initial ratios and the rate of methane, and (3) production or resupply due to cryovolcanic activity. We estimate an upper limit for the outgassing timescale of 470 Myr. This duration can be extended to 940 Myr if production rates are large enough to counteract the fractionation due to escape and photochemistry. There is no lower limit to the timescale because the current ratios are within the range of possible primordial values.

Dynamical implications of seasonal and spatial variations in Titan's stratospheric composition

Titans diverse inventory of photochemically produced gases can be used as tracers to probe atmospheric circulation. Since the arrival of the Cassini–Huygens mission in July 2004 it has been possible to map the seasonal and spatial variations of these compounds in great detail. Here, we use 3.5 years of data measured by the Cassini Composite InfraRed Spectrometer instrument to determine spatial and seasonal composition trends, thus providing clues to underlying atmospheric motions. Titans North Pole (currently in winter) displays enrichment of trace species, implying subsidence is occurring there. This is consistent with the descending branch of a single south-to-north stratospheric circulation cell and a polar vortex. Lack of enrichment in the south over most of the observed time period argues against the presence of any secondary circulation cell in the Southern Polar stratosphere. However, a residual cap of enriched gas was observed over the South Pole early in the mission, which has since completely dissipated. This cap was most probably due to residual build-up from southern winter. These observations provide new and important constraints for models of atmospheric photochemistry and circulation.

THE NITROGEN ISOTOPIC RATIO IN JUPITER'S ATMOSPHERE FROM OBSERVATIONS BY THE COMPOSITE INFRARED SPECTROMETER ON THE CASSINI SPACECRAFT

The Composite Infrared Spectrometer (CIRS) on the Cassini spacecraft made infrared observations of Jupiters atmosphere during the flyby of 2000 December to 2001 January. The unique database in the 600-1400 cm-1 region with 0.53 and 2.8 cm-1 spectral resolutions obtained from the observations permits retrieval of global maps of the thermal structure and composition of Jupiters atmosphere, including the distributions of 14NH3 and 15NH3. Analysis of Jupiters ammonia distributions from three isolated 15NH3 spectral lines in eight latitudes is presented for evaluation of the nitrogen isotopic ratio. The nitrogen isotopic ratio 14N/15N (or 15N/14N) in Jupiters atmosphere in this analysis is calculated to be 448 ± 62 [or (2.23 ± 0.31) × 10-3]. This value of the ratio determined from CIRS data is found to be in very close agreement with the value previously obtained from the measurements by the Galileo Probe Mass Spectrometer. Some possible mechanisms to account for the variation of Jupiters observed isotopic ratio relative to those of various astrophysical environments are discussed.

SEASONAL CHANGES IN TITAN'S POLAR TRACE GAS ABUNDANCE OBSERVED BY CASSINI

We use a six-year data set (2004-2010) of mid-infrared spectra measured by Cassinis Composite InfraRed Spectrometer to search for seasonal variations in Titans atmospheric temperature and composition. During most of Cassinis mission Titans northern hemisphere has been in winter, with an intense stratospheric polar vortex highly enriched in trace gases, and a single south-to-north circulation cell. Following northern spring equinox in mid-2009, dramatic changes in atmospheric temperature and composition were expected, but until now the temporal coverage of polar latitudes has been too sparse to discern trends. Here, we show that during equinox and post-equinox periods, abundances of trace gases at both poles have begun to increase. We propose that increases in north polar trace gases are due to a seasonal reduction in gas depletion by horizontal mixing across the vortex boundary. A simultaneous south polar abundance increase suggests that Titan is now entering, or is about to enter, a transitional circulation regime with two branches, rather than the single branch circulation pattern previously observed.

Seasonal Changes in Titan's Surface Temperatures

Seasonal changes in Titan’s surface brightness temperatures have been observed by Cassini in the thermal infrared. The Composite Infrared Spectrometer measured surface radiances at 19 μm in two time periods: one in late northern winter (LNW; Ls = 335 ◦ ) and another centered on northern spring equinox (NSE; Ls = 0 ◦ ). In both periods we constructed pole-to-pole maps of zonally averaged brightness temperatures corrected for effects of the atmosphere. Between LNW and NSE a shift occurred in the temperature distribution, characterized by a warming of ∼0.5 K in the north and a cooling by about the same amount in the south. At equinox the polar surface temperatures were both near 91 K and the equator was at 93.4 K. We measured a seasonal lag of ΔLS ∼ 9 ◦ in the meridional surface temperature distribution, consistent with the post-equinox results of Voyager 1 as well as with predictions from general circulation modeling. A slightly elevated temperature is observed at 65 ◦ S in the relatively cloud-free zone

Saturn's emitted power

Long-term (2004–2009) on-orbit observations by Cassini Composite Infrared Spectrometer are analyzed to precisely measure Saturns emitted power and its meridional distribution. Our evaluations suggest that the average global emitted power is 4.952 ± 0.035 W m^(−2) during the period of 2004–2009. The corresponding effective temperature is 96.67 ± 0.17 K. The emitted power is 16.6% higher in the Southern Hemisphere than in the Northern Hemisphere. From 2005 to 2009, the global mean emitted power and effective temperature decreased by ~2% and ~0.5%, respectively. Our study further reveals the interannual variability of emitted power and effective temperature between the epoch of Voyager (~1 Saturn year ago) and the current epoch of Cassini, suggesting changes in the cloud opacity from year to year on Saturn. The seasonal and interannual variability of emitted power implies that the energy balance and internal heat are also varying.

ETHYL CYANIDE ON TITAN: SPECTROSCOPIC DETECTION AND MAPPING USING ALMA

We report the first spectroscopic detection of ethyl cyanide (C2H5CN) in Titan’s atmosphere, obtained using spectrally and spatially resolved observations of multiple emission lines with the Atacama Large Millimeter/ submillimeter Array (ALMA). The presence of C2H5CN in Titan’s ionosphere was previously inferred from Cassini ion mass spectrometry measurements of C2H5CNH + . Here we report the detection of 27 rotational lines from C2H5CN (in 19 separate emission features detected at s >3 confidence) in the frequency range 222–241 GHz. Simultaneous detections of multiple emission lines from HC3N, CH3CN, and CH3CCH were also obtained. In contrast to HC3N, CH3CN, and CH3CCH, which peak in Titan’s northern (spring) hemisphere, the emission from C2H5CN is found to be concentrated in the southern (autumn) hemisphere, suggesting a distinctly different chemistry for this species, consistent with a relatively short chemical lifetime for C2H5CN. Radiative transfer models show that C2H5CN is most concentrated at altitudes200 km, suggesting production predominantly in the stratosphere and above. Vertical column densities are found to be in the range (1–5) ×1 0 14 cm �2 .