Craig P. Jacobson

Joining of dissimilar materials

Abstract Emerging trends in manufacturing such as light weighting, increased performance and functionality increases the use of multi-material, hybrid structures and thus the need for joining of dissimilar materials. The properties of the different materials are jointly utilised to achieve product performance. The joining processes can, on the other hand be challenging due to the same different properties. This paper reviews and summarizes state of the art research in joining dissimilar materials. Current and emerging joining technologies are reviewed according to the mechanisms of joint formation, i.e.; mechanical, chemical, thermal, or hybrid processes. Methods for process selection are described and future challenges for research on joining dissimilar materials are summarized.

LSM-YSZ Cathodes with Reaction-Infiltrated Nanoparticles

To improve the LSM-YSZ cathode performance of intermediate temperature solid oxide fuel cells (SOFCs), Sm0.6Sr0.4CoO3-sigma (SSC) perovskite nanoparticles are incorporated into the cathodes by a reaction-infiltration process. The SSC particles are {approx}20 to 80nm in diameter, and intimately adhere to the pore walls of the preformed LSM-YSZ cathodes. The SSC particles dramatically enhance single-cell performance with a 97 percent H2+3 percent H2O fuel, between 600 C and 800 C. Consideration of a simplified TPB (triple phase boundary) reaction geometry indicates that the enhancement may be attributed to the high electrocatalytic activity of SSC for electrochemical reduction of oxygen in a region that can be located a small distance away from the strict triple phase boundaries. The implication of this work for developing high-performance electrodes is also discussed.

Deposition and Evaluation of Protective PVD Coatings on Ferritic Stainless Steel SOFC Interconnects

eNASA-Glenn Research Center, Cleveland, Ohio 44135, USA Reduced operating temperatures 600–800°C of solid oxide fuel cells SOFCs may enable the use of inexpensive ferritic steels as interconnects. Due to the demanding SOFC interconnect operating environment, protective coatings are gaining attention to increase long-term stability. In this study, large area filtered arc deposition and hybrid filtered arc deposition-assisted electron beam physical vapor deposition technologies were used to deposit two-segment coatings with Cr-Co-Al-O-N-based bottom segment and Mn-Co-O top segment. The bottom segment serves as a diffusion barrier and bond segment, while the top segment is meant to increase electrical conductivity and inhibit Cr volatility. Coatings were deposited on ferritic steel and subsequently annealed in air for various time intervals. Surface oxidation was investigated using Rutherford backscattering spectrometry, scanning electron microscopy, and energy-dispersive spectrometry analyses. Cr volatilization was evaluated using a transpiration apparatus and inductively coupled plasma-mass spectrometry analysis of the resultant condensate. Electrical conductivity area specific resistance, ASR, was studied as a function of time using the four-point technique. Significant improvement in oxidation resistance, Cr volatility, and ASR were observed in the coated versus uncoated samples. Transport mechanisms for various oxidizing species and coating diffusion barrier properties are discussed.