Craig Sheridan

An annual and seasonal characterisation of winery effluent in South Africa.

Winery effluent is known to have a high chemical oxygen demand (COD) and a low pH. In this study, we extensively analysed effluent from two cellars and studied the temporal changes over the duration of a harvest and the duration of a year. We found that ethanol contributes approximately 85% to 90% of the COD of raw winery effluent, with acetic acid being the next significant contributor. The pH showed some dependence on the concentration of acetic acid. The concentration of sodium in the effluent is strongly dependent on the cleaning regime in place at the cellar, and the concentration of potassium has been shown to be linked to the spillage of juice, wine or lees. The data and correlations presented here could allow for an artificial effluent to be prepared easily for research purposes.

The availability of second generation feedstocks for the treatment of acid mine drainage and to improve South Africa's bio-based economy

South Africa has a wide range of mining activities making mineral resources important economic commodities. However, the industry is responsible for several environmental impacts; one of which is acid mine drainage (AMD). Despite several years of research, attempts to prevent AMD generation have proven to be difficult. Therefore, treatment of the resulting drainage has been common practice over the years. One of the recommended treatment methods is the use of second generation feedstocks (lignocellulosic biomass). This biomass is also acknowledged to be an important feedstock for bio-refineries as it is abundant, has a high carbon content and is available at minimal cost. It can also potentially be converted to fermentable sugars (e.g. glucose) through different treatment steps, which could further yield other valuable commodities (cellulase, poly-β-hydroxybutyric acid (PHB) and penicillin V). It is estimated by a generic flowsheet model that 7 tons of grass biomass can produce 1400 kg of glucose which can subsequently produce 205 kg, 438 kg and 270 kg of cellulase, PHB and Penicillin V, respectively. In this paper we investigate the feasibility of grass as feedstock for AMD treatment and the subsequent conversion of this acid pre-treated grass into valuable bio-products.

Hydraulic study of a non-steady horizontal sub-surface flow constructed wetland during start-up

This paper describes the hydraulic performance of a start-up, pilot-scale, horizontal sub-surface flow constructed wetland (CW), located outdoors at the Helmholtz UFZ, Leipzig. This paper aims to investigate the impact of the method of hydraulic calculation in a pilot-scale system. Impulse-response tracer tests were conducted at multiple depths and locations throughout the system and the uranine concentration was measured using a fluorometer. In addition, the volumetric flow rate was closely monitored and climatic data was gathered to support the hydraulic results. Werner and Kadlecs modified residence time distribution (RTD) theory (originally developed for systems with large flow rate and volume fluctuations) was applied and the results compared to those obtained using classic RTD theory. Progressive uranine dispersion, broadening of the RTD base, a change in peak shape and extended tailing were observed with increasing distance. All of these factors indicated deviation from plug flow and mixing effects with low-to-moderate dead volume. As this was a non-steady flow system, application of modified RTD theory ensured that the first moments of the normalized breakthrough curves and RTD functions were always unity. The Students t-test (95% confidence) showed that the outlet RTDs calculated assuming steady-flow were significantly different, but those determined using the modified theory were closely comparable. In general, a decrease in flow rate from inlet to outlet was observed and fluctuations in the outflow were linked to climatic conditions. August was characterized by the highest temperatures, high global radiation and high rates of evapotranspiration. Low or no outflow was recorded in conjunction with high evapotranspiration. The lowest temperatures, low global radiation, low evapotranspiration and high humidity were recorded in October, as well as the second highest rainfall (82 mm) after June (115 mm). Surges in outflow were observed with rain events.

Removal of dissolved chromium from synthetic mine effluent: A mesocosm experiment

Dispersion of hexavalent chromium (Cr(VI)) in streams around nickel laterite mines, which are mostly located in the tropics, may pose serious risks for the environment and human health. In an earlier study, a local natural wetland effectively removed Cr from a nickel mine environment in Indonesia. In order to understand the processes and conditions that would facilitate the establishment of operational constructed wetlands that would remove Cr from mine water discharge, we used two native macrophyte species from the same wetland, Lepironia articulata and Machaerina rubiginosa, in a series of mesocosm experiments to follow the distribution of Cr species in water, substrate and plants. A 1 m3 mesocosm was charged with a sand/compost mixture to a depth of 0.5 m, filled to within 0.1 m from the top by water with Cr concentrations of about 1.0 mg L-1, similar to mine discharge water, and plants were introduced to part of the substrate surface. Stage 1 of the experiment supplied and removed fresh water continuously by surface flow, maintaining a residence time of 12 h. In stages, the water was recirculated (Stage 2), more plants were added (Stage 3) and outflow conditions were changed from totally surface to partially from beneath the substrate (Stage 4). All stages lowered Cr concentrations at the surface water outflow, but Cr concentrations were lower again close to the sediment/water interface. Due to the reduction of Cr(VI), the Cr concentrations in substrate pore water were higher near the surface compared to those at depth, and the pore water concentrations of Cr(VI) and total Cr were higher in the vegetated area compared to the non-vegetated area. Higher plant density and mixed species composition of the macrophytes did not increase the efficiency of Cr(VI) removal from the system. The hybrid system, comprising surface and below-substrate outflow (Stage 4), removed hexavalent chromium at a much higher rate than surface outflow only.