Cristiano Nisoli

Artificial ‘spin ice’ in a geometrically frustrated lattice of nanoscale ferromagnetic islands

Frustration, defined as a competition between interactions such that not all of them can be satisfied, is important in systems ranging from neural networks to structural glasses. Geometrical frustration, which arises from the topology of a well-ordered structure rather than from disorder, has recently become a topic of considerable interest. In particular, geometrical frustration among spins in magnetic materials can lead to exotic low-temperature states, including ‘spin ice’, in which the local moments mimic the frustration of hydrogen ion positions in frozen water. Here we report an artificial geometrically frustrated magnet based on an array of lithographically fabricated single-domain ferromagnetic islands. The islands are arranged such that the dipole interactions create a two-dimensional analogue to spin ice. Images of the magnetic moments of individual elements in this correlated system allow us to study the local accommodation of frustration. We see both ice-like short-range correlations and an absence of long-range correlations, behaviour which is strikingly similar to the low-temperature state of spin ice. These results demonstrate that artificial frustrated magnets can provide an uncharted arena in which the physics of frustration can be directly visualized.

Colloquium: Artificial spin ice : Designing and imaging magnetic frustration

Frustration, the presence of competing interactions, is ubiquitous in the physical sciences and is a source of degeneracy and disorder, which in turn gives rise to new and interesting physical phenomena. Perhaps nowhere does it occur more simply than in correlated spin systems, where it has been studied in the most detail. In disordered magnetic materials, frustration leads to spin-glass phenomena, with analogies to the behavior of structural glasses and neural networks. In structurally ordered magnetic materials, it has also been the topic of extensive theoretical and experimental studies over the past two decades. Such geometrical frustration has opened a window to a wide range of fundamentally new exotic behavior. This includes spin liquids in which the spins continue to fluctuate down to the lowest temperatures, and spin ice, which appears to retain macroscopic entropy even in the low-temperature limit where it enters a topological Coulomb phase. In the past seven years a new perspective has opened in the study of frustration through the creation of artificial frustrated magnetic systems. These materials consist of arrays of lithographically fabricated single-domain ferromagnetic nanostructures that behave like giant Ising spins. The nanostructures’ interactions can be controlled through appropriate choices of their geometric properties and arrangement on a (frustrated) lattice. The degrees of freedom of the material can not only be directly tuned, but also individually observed. Experimental studies have unearthed intriguing connections to the out-of-equilibrium physics of disordered systems and nonthermal “granular” materials, while revealing strong analogies to spin ice materials and their fractionalized magnetic monopole excitations, lending the enterprise a distinctly interdisciplinary flavor. The experimental results have also been closely coupled to theoretical and computational analyses, facilitated by connections to classic models of frustrated magnetism, whose hitherto unobserved aspects have here found an experimental realization. Considerable experimental and theoretical progress in this field is reviewed here, including connections to other frustrated phenomena, and future vistas for progress in this rapidly expanding field are outlined.

Crystallites of magnetic charges in artificial spin ice

Artificial spin ice is a class of lithographically created arrays of interacting ferromagnetic nanometre-scale islands. It was introduced to investigate many-body phenomena related to frustration and disorder in a material that could be tailored to precise specifications and imaged directly. Because of the large magnetic energy scales of these nanoscale islands, it has so far been impossible to thermally anneal artificial spin ice into desired thermodynamic ensembles; nearly all studies of artificial spin ice have either treated it as a granular material activated by alternating fields or focused on the as-grown state of the arrays. This limitation has prevented experimental investigation of novel phases that can emerge from the nominal ground states of frustrated lattices. For example, artificial kagome spin ice, in which the islands are arranged on the edges of a hexagonal net, is predicted to support states with monopolar charge order at entropies below that of the previously observed pseudo-ice manifold. Here we demonstrate a method for thermalizing artificial spin ices with square and kagome lattices by heating above the Curie temperature of the constituent material. In this manner, artificial square spin ice achieves unprecedented thermal ordering of the moments. In artificial kagome spin ice, we observe incipient crystallization of the magnetic charges embedded in pseudo-ice, with crystallites of magnetic charges whose size can be controlled by tuning the lattice constant. We find excellent agreement between experimental data and Monte Carlo simulations of emergent charge–charge interactions.

Effective Temperature in an Interacting Vertex System: Theory and Experiment on Artificial Spin Ice

Frustrated arrays of interacting single-domain nanomagnets provide important model systems for statistical mechanics, as they map closely onto well-studied vertex models and are amenable to direct imaging and custom engineering. Although these systems are manifestly athermal, we demonstrate that an effective temperature, controlled by an external magnetic drive, describes their microstates and therefore their full statistical properties.

Energy minimization and ac demagnetization in a nanomagnet array.

We study ac demagnetization in frustrated arrays of single-domain ferromagnetic islands, exhaustively resolving every (Ising-like) magnetic degree of freedom in the systems. Although the net moment of the arrays is brought near zero by a protocol with sufficiently small step size, the final magnetostatic energy of the demagnetized array continues to decrease for finer-stepped protocols and does not extrapolate to the ground-state energy. The resulting complex disordered magnetic state can be described by a maximum-entropy ensemble constrained to satisfy just nearest-neighbor correlations.

Ground state lost but degeneracy found: The effective thermodynamics of artificial spin ice

We analyze the rotational demagnetization of artificial spin ice, a recently realized array of nanoscale single-domain ferromagnetic islands. Demagnetization does not anneal this model system into its antiferromagnetic ground state: the moments have a static disordered configuration similar to the frozen state of the spin ice materials. We demonstrate that this athermal system has an effective extensive degeneracy and we introduce a formalism that can predict the populations of local states in this icelike system with no adjustable parameters.

Unhappy vertices in artificial spin ice: new degeneracies from vertex frustration

In 1935, Pauling estimated the residual entropy of water ice with remarkable accuracy by considering the degeneracy of the ice rule solely at the vertex level. Indeed, his estimate works well for both the three-dimensional pyrochlore lattice and the two-dimensional six-vertex model, solved by Lieb in 1967. A similar estimate can be done for the honeycomb artificial spin. Indeed, its pseudo-ice rule, like the ice rule in Pauling and Liebs systems, simply extends to the global ground state a degeneracy which is already present in the vertices. Unfortunately, the anisotropy of the magnetic interaction limits the design of inherently degenerate vertices in artificial spin ice, and the honeycomb is the only degenerate array produced so far. In this paper we show how to engineer artificial spin ice in a virtually infinite variety of degenerate geometries built out of non-degenerate vertices. In this new class of vertex models, the residual entropy follows not from a freedom of choice at the vertex level, but from the nontrivial relative arrangement of the vertices themselves. In such arrays not all of the vertices can be chosen in their lowest energy configuration. They are therefore vertex-frustrated and contain unhappy vertices. This can lead to residual entropy and to a variety of exotic states, such as sliding phases, smectic phases and emerging chirality. These new geometries will finally allow for the fabrication of many novel, extensively degenerate versions of artificial spin ice.

Comparing artificial frustrated magnets by tuning the symmetry of nanoscale permalloy arrays

We study the impact of geometry on magnetostatically frustrated single-domain nanomagnet arrays. We examine square and hexagonal lattice arrays, as well as a brickwork geometry that combines the anisotropy of the square lattice and the topology of the hexagonal lattice. We find that the more highly frustrated hexagonal lattice allows for the most thorough minimization of the magnetostatic energy, and that the pairwise correlations between moments differ qualitatively between hexagonal and brickwork lattices, although they share the same lattice topology. The results indicate that the symmetry of local interaction is more important than overall lattice topology in the accommodation of frustrated interactions.

Demagnetization protocols for frustrated interacting nanomagnet arrays

We report a study of demagnetization protocols for frustrated arrays of interacting single-domain permalloy nanomagnets by rotating the arrays in a changing magnetic field. The most effective demagnetization is achieved by not only stepping the field strength down while the sample is rotating, but also by combining each field step with alternation in the field direction. By contrast, linearly decreasing the field strength or stepping the field down without alternating the field direction leaves the arrays with a larger remanent magnetic moment. These results suggest that nonmonotonic variations in field magnitude around and below the coercive field are important for the demagnetization process.

Degeneracy and Criticality from Emergent Frustration in Artificial Spin Ice

Although initially introduced to mimic the spin-ice pyrochlores, no artificial spin ice has yet exhibited the expected degenerate ice phase with critical correlations similar to the celebrated Coulomb phase in the pyrochlore lattice. Here we study a novel artificial spin ice based on a vertex-frustrated rather than pairwise frustrated geometry and show that it exhibits a quasicritical ice phase of extensive residual entropy and, significantly, algebraic correlations. Interesting in its own regard as a novel realization of frustration in a vertex system, our lattice opens new pathways to study defects in a critical manifold and to design degeneracy in artificial magnetic nanoarrays, a task so far elusive.