D. A. Shutov

Destruction of Sulfonol in Its Aqueous Solutions by Contact Glow Discharge Treatment: 1. Product Formation Kinetics

Degradation of the anionic surfactant Sulfonol (sodium alkylbenzenesulfonate) in its aqueous solutions acting as a liquid cathode of atmospheric-pressure dc discharge in air has been studied. The products of plasma-chemical decomposition of Sulfonol in the liquid phase have been identified. The kinetic characteristics of the formation of products of plasma-chemical reactions at a substrate concentration of 5 × 10−3 g/L (0.014 mmol/L) and a discharge current of 40 mA have been determined.

Destruction of sulfonol in its aqueous solutions by contact glow discharge treatment: 2. Mechanisms and kinetic simulation

A mechanism for the degradation of Sulfonol in its aqueous solutions acting as a liquid cathode of atmospheric-pressure dc discharge in air and for the formation of the products has been proposed, and the chemical kinetics of the degradation processes has been numerically simulated.

Synthesis of zinc oxide powders in plasma–solution systems

A new method is proposed for the synthesis of powdered zinc oxide with the use of a plasma–solution system. The chemical and phase compositions and the morphology of the synthesized powders have been determined. It has been found that the calcination of powders obtained in the plasma–solution system leads to the formation of ZnO.

Destruction of organic dyes in aqueous solution by low-temperature plasma jet treatment

A method for the destruction of organic compounds in their aqueous solutions using a plasma jet, generated by a pulse power source, at atmospheric pressure in air has been proposed. The acid–base dyes Phenol Red and Methyl Orange have been used as model compounds. The kinetics of degradation of these compounds and the formation kinetics of some products have been studied.

Kinetic features of chromium(VI) reduction and phenol degradation in aqueous solution by treatment in atmospheric-pressure air direct-current discharge

The kinetics of the processes of simultaneous reduction of Cr(VI) and degradation of phenol during the treatment of their aqueous solutions with different initial concentrations using an atmosphericpressure air direct-current discharge have been studied. The solution served as the discharge cathode. It has been shown that the discharge treatment leads to a decrease in the concentration of both Cr(VI) and phenol. Phenol additives accelerate the Cr(VI) reduction process and make it irreversible. The phenol degradation and Cr(VI) reduction kinetics are described well (R2 > 0.99) by the pseudo-first-order rate equation in phenol and Cr(VI) concentrations, respectively. The apparent rate constants of the processes have been determined, the energy efficiency of the processes has been evaluated, and possible mechanisms of the proceeding reactions have been discussed.

Destruction of sodium lauryl sulfate in its aqueous solutions by contact glow discharge treatment

Degradation of the anionic surfactant sodium lauryl sulfate (C12H25SO4Na, SLS) in its aqueous solutions with concentrations of 0.02–1.1 mmol/L acting as a liquid cathode of atmospheric-pressure dc discharge in air at a discharge current ranging within 20–100 mA has been studied. The products of degradation in the liquid phase have been identified, and the kinetic characteristics of their formation at an initial SLS concentration of 5 × 10−3 g/L (∼0.02 mmol/L) and a discharge current of 40 mA have been determined.