D. A. Zedgenizov

Carbonatitic melts in cuboid diamonds from Udachnaya kimberlite pipe (Yakutia): evidence from vibrational spectroscopy

Abstract Micro-inclusions (1 −10 μm) in 55 diamonds of cubic habit from the Udachnaya kimberlite pipe have been studied using vibrational spectroscopy. This has revealed a multiphase assemblage in cuboid diamonds from the Udachnaya kimberlite pipe. This assemblage includes carbonates, olivine, apatite, graphite, water and silicate glasses. The micro-inclusions preserve the high internal pressure and give confidence that the original materials were trapped during growth of the host diamond. The internal pressures, extrapolated to mantle temperatures, lie within the stability field of diamond and the relatively low temperatures are typical for the formation of cuboid diamonds. In contrast to previously reported data for African diamonds, the micro-inclusions in the cuboids from Udachnaya are extremely carbonatitic in composition (H2O/(H2O+CO2) ≈5−20%) with the observed assemblage of microinclusions similar to some types of carbonatites. The low water and silica content testify that the material in the micro-inclusions of the Udachnaya diamonds was near-solidus carbonatitic melt. Vibrational spectroscopy has provided the evidence of carbonatitic melts in cuboid diamonds.

Water-related IR characteristics in natural fibrous diamonds

Abstract Water-related features were studied using infrared absorption spectroscopy in fibrous diamonds with micro-inclusions. Both OH-stretching and HOH-bending vibrations were observed. The lack of correlation between the intensities of HOH and OH bands in different samples and the complexity of the OH-stretching band indicate that a large fraction of water is present as hydroxyl groups in minerals. Heating and cooling experiments were performed to elucidate the properties of fluids in micro- inclusions in diamonds. The results of experiments at various temperatures support the presence of several water-related components in individual diamonds. These spectroscopic investigations of fibrous diamonds revealed two or more interrelated water-related components preserved in micro-inclusions. The existence of several water phases or water solutions with different salinity and solutes within one diamond crystal is possible.

The mineralogy of Ca-rich inclusions in sublithospheric diamonds

This paper discusses mineralogy of Ca-rich inclusions in ultra-deep (sublithospheric) diamonds. It was shown that most of the Ca-rich majoritic garnets are of metabasic (eclogitic) affinity. The observed variation in major and trace element composition is consistent with variations in the composition of the protolith and the degree of enrichment or depletion during interaction with melts. Major and trace element compositions of the inclusions of Ca minerals in ultra-deep diamonds indicate that they crystallized from Ca-carbonatite melts that were derived from partial melting of eclogite bodies in deeply subducted oceanic crust in the transition zone or even the lower mantle. The occurrence of merwinite or CAS inclusions in ultra-deep diamonds can serve as mineralogical indicators of the interaction of metaperidotitic and metabasic mantle lithologies with alkaline carbonatite melts. The discovery of the inclusions of carbonates in association with ultra-deep Ca minerals can not only provide additional support for their role in the diamond formation process but also help to define additional mantle reservoirs involved in global carbon cycle.

Chemical Heterogeneity in the Diamondiferous Eclogite Xenolith from the Udachnaya Kimberlite Pipe

The first studies of diamond-hosted inclusions in xenoliths have demonstrated that the compositions of inclusions and minerals in xenoliths may differ substantially [1]. It was noted that a higher K content in clinopyroxene as compared with that in the matrix is among the most important differences [2]. The Mir Pipe yielded diamonds with numerous garnet and pyroxene inclusions with highly variable compositions [3, 4]. Some authors explain these compositional variations in inclusions by fractionation from the silicate melt [3].

Micro- and nano-inclusions in a superdeep diamond from São Luiz, Brazil

We report cloudy micro- and nano-inclusions in a superdeep diamond from São-Luiz, Brazil which contains inclusions of ferropericlase (Mg, Fe)O and former bridgmanite (Mg, Fe)SiO3 and ringwoodite (Mg, Fe)2SiO4. Field emission-SEM and TEM observations showed that the cloudy inclusions were composed of euhedral micro-inclusions with grain sizes ranging from tens nanometers to submicrometers. Infrared absorption spectra of the cloudy inclusions showed that water, carbonate, and silicates were not major components of these micro- and nano-inclusions and suggested that the main constituent of the inclusions was infrared-inactive. Some inclusions were suggested to contain material with lower atomic numbers than that of carbon. Mineral phase of nano- and micro-inclusions is unclear at present. Microbeam X-ray fluorescence analysis clarified that the micro-inclusions contained transition metals (Cr, Mn, Fe, Co, Ni, Cu, Zn) possibly as metallic or sulfide phases. The cloudy inclusions provide an important information on the growth environment of superdeep diamonds in the transition zone or the lower mantle.

Distribution of OK1, N3 and NU1 defects in diamond crystals of different habits

Comprehensive studies of diamond crystals with a low nitrogen concentration from the placer deposits and kimberlite pipes of Yakutia have facilitated the detection of three titanium-nitrogen-related centers: OK1/S1, N3/440.3 nm and NU1/485 nm in the EPR and photoluminescence spectra. Additional proof of titanium presence in the structure of EPR N3 center was obtained from the hyperfine structure of titanium magnetic isotopes 47 Ti and 49 Ti. Titanium-nitrogen-related centers in the neighboring substitutional sites (N3/440.3 nm) and in the structure of the interstitial (NU1/485 nm) are not found in cubic habit crystals, which are characterized by the presence of the OK1/S1 center with a double semi-vacancy structure. All three types of nitrogen-titanium-related centers are present in cuboctahedral habit diamonds. It is assumed that these habit-specific distributions of defects in diamond are a result of the peculiarities of incorporating nitrogen and titanium impurities into the different growth sector of crystals and aggregation thereof at high pressure and temperature.

U-Pb age of rutile from the eclogite xenolith of the Udachnaya kimberlite pipe

861 The Udachnaya kimberlite pipe in the Daldyn kimberlite field (Daldyn–Alakit region) of the central part of the Yakutian diamond province is the largest diamond deposit in Russia and one of the largest in the world. The pipe consists of two conjugate bodies: Udachnaya East and Udachnaya West. As is evident from the U–Pb dating of perovskites from kimberlites, the ages of the Udachnaya pipe formation are 367 ± 3 and 367 ± 5 Ma (Udachnaya East); 361 ± 4 and 353 ± 5 Ma (Udachnaya West) [1]. Deep seated xenoliths of mantle rocks in kimber lite pipes are represented by a wide spectrum of ultra basic rocks, as well as pyroxenites and eclogites. Eclogites are coarse granular rocks mostly composed of garnet and clinopyroxene with accessory rutile. In addition to bimineral eclogites, the most abundant among xenoliths of the basic composition, there are corundum and kyanite eclogites [2]. Numerous stud ies of eclogite xenoliths from the Udachnaya kimber lite pipe have provided evidence for the influence of mantle metasomatism on the upper mantle rocks and have distinguished some signs of metasomatic origin of diamonds [3, 4]. However, the age of these processes has been not determined to date. Because of this, we have performed the dating of rutiles from the eclogite xenolith (Sample UD 208 05) entering the composi tion of the secondary mineral association. Eclogite xenolith from the Udachnaya pipe (Sam ple UD 208 05) is bimineral eclogite composed of dark green xenomorphic clinopyroxene (3–6 mm) and round garnet (2–5 mm) grains reaching ~55 and ~44 vol %, respectively. The xenolith contains the areas of partial melting including veins crossing rock forming omphacite and garnet, which consist of amor phous material (silicate glass) and products of its replacement (chlorite and quartz). These areas are surrounded by replaced omphacite with the typical “sponged textures” (symplectites) [3]. Among the accessory minerals are rutile, ilmenite, and pyrrhotite. The chemical composition of minerals was analyzed by energy dispersive spectrometry on a Tescan MYRA 3 LMU electron microscope with an EDS detector (Oxford Instruments) and using a JEOL JXA 8100 X ray microanalyzer at the Institute of Geology and Mineralogy, Siberian Branch, Russian Academy of Sciences.

Local variations in carbon isotopes and nitrogen contents in diamonds from placers of the northeastern portion of the Siberian Platform

Variations in the isotopic composition of carbon and the nitrogen contents in diamonds from placers of the northeastern portion of the Siberian Platform have been examined. The results obtained indicate that there is no correlation between local variations in the isotopic composition of carbon and the nitrogen content and the degree of nitrogen aggregation. It has been demonstrated that changes in oxygen fugacity in the course of the growth of diamonds of the V variety do not affect the isotopic composition of carbon. The nature of the variations in the isotopic composition of carbon and the nitrogen contents indicate that there were at least two sources of carbon. The sources of lightweight and weighted compositions of carbon in the diamonds could be organic carbon and carbon in marine carbonates of the subducted crust of the Earth, respectively. Mantle carbon was involved in the diamond formation process at the final stages of the growth.

Carbonate-silicate composition of diamond-forming media of fibrous diamonds from the Snap Lake area (Canada)

This study presents new data on the compositions of microinclusions in fibrous diamonds from the Snap Lake area in the eastern part of the Slave Craton (Canada). The compositional trends of diamond microinclusions are consistent with those of diamond-forming media ranging continuously between a highly carbonatitic endmember and a highly silicic endmember. The microinclusions exhibit general enrichment of most incompatible elements, which is probably indicative of their crystallization during partial melting of mantle peridotites and eclogites. Our results also suggest that the diamond analyzed in this study may have formed as a result of interaction between carbonate-silicate melts and peridotitic wall-rocks at the base of a thick lithospheric mantle at depths below 300 km. The trace element distributions in the studied diamond microinclusions show a general similarity to those previously found in the parental kimberlites and carbonatites. These data suggest that diamonds may have crystallized either directly from a kimberlitic/carbonatitic melt or from a proto-kimberlitic fluid/melt, which was derived from a source also common to kimberlites. This is supported by differences in the major element compositions of diamond-forming fluids/melts and kimberlites.

The transformation features of impurity defects in natural diamonds of various habits under high P–T conditions

The results of the investigations of the transformation of impurity defects in natural diamonds of various habits at the stage of high-temperature annealing at P = 6 GPa and T = 2200°C are presented. The studies conducted allowed us to ascertain that the transformations of Aand B-defects in diamonds of octahedral and cubic habits follow general regularities. This fact shows that most of the diamonds of cubic habit with low degree of aggregation of nitrogen centers were not really annealed over a long-term interval. Unlike octahedral diamonds, those of cubic habit are characterized by a pronounced increase in the peak of H-containing defects (3107 cm–1) after annealing.