D. C. Griffin

Excitation-autoionisation of Ti3+, Zr3+and Hf3+in the distorted-wave approximation with exchange

Full distorted-wave calculations have been carried out on np6 to np5nd2 transitions to test the formalism for complex atomic configurations, and to provide a more meaningful comparison with experiment than was possible from earlier calculations. Agreement with experiment is certainly improved, but some discrepancies remain.

Calculations of the contributions of excitation-autoionisation to the electron impact ionisation of Ca+ and Ba+ in the distorted-wave approximation

The contributions of the excitation-autoionisation transitions 3p64s to 3p53d4s in Ca+ and 5p66s to 5p55d6s in Ba+ to the total electron impact ionisation cross sections of these ions have been calculated in the distorted-wave approximation. Partial cross sections originating from transitions to three of the nine terms in the configuration 3p53d4s of Ca+ are compared with the recent R-matrix close-coupling calculations for these transitions by Burke et al. (1983) in order to determine the effect of continuum coupling between autoionising channels. Both the R-matrix and distorted-wave calculations predict a series of large peaks near threshold in Ca+ that are not observed in the measurements of Peart and Dolder (1968). Total cross sections with estimates for the contributions of direct ionisation are calculated and compared with the ionisation measurements of Peart and Dolder for Ca+ and of Peart et al. (1973) for Ba+. Both LS term dependence in the nd radial wavefunctions and unitarisation are found to have a pronounced effect on these cross sections. The implications of the discrepancies between theory and experiment are discussed.

Indirect processes in the electron impact ionisation of Ca+ using an LS-term-dependent close-coupling method

Contributions to the electron impact ionisation of Ca+ resulting from 3p to 3d inner shell excitations, followed by autoionisation, are calculated using an LS term-dependent close-coupling method. The Ca+ results are compared with previous distorted-wave calculations and the experimental measurements of Peart and Dolder (1975).