Daisuke Araoka

Tsunami recurrence revealed by Porites coral boulders in the southern Ryukyu Islands, Japan

Information about past tsunami hazards, such as their recurrence interval and magnitude, is needed for future disaster prediction and mitigation. We examined radiocarbon ages of the surfaces of massive coral boulders cast ashore by past tsunamis in the southern Ryukyu Islands, Japan, where few historical and geological records of past tsunamis are available. We selected only non-eroded Porites coral boulders along the shoreline, because their characteristics make it possible to determine the probable timing of their deposition by tsunamis, and we applied a dating method that uses the cumulative probability distributions of large numbers of radiocarbon measurements of those boulders to determine the timing of past tsunamis. The results demonstrate that the southern Ryukyu Islands have repeatedly experienced tsunami events since at least 2400 yr ago, with a recurrence interval of ∼150–400 yr. The largest Porites tsunami boulder that we studied (long axis, 9 m), which is probably the largest single-colony tsunami boulder in the world, was displaced by the A.D. 1771 Meiwa tsunami. Although the 1771 Meiwa tsunami was likely the largest event in at least the past 700 yr, calculations of current velocity show that all identified tsunamis occurring before 1771 were probably large enough to cause considerable damage to human-built structures and loss of life. This study demonstrates that by reliably dating large numbers of selected coastal boulders it is possible to ascertain the timing, recurrence interval, and magnitude of past tsunamis in a location where few adequate survey sites of sandy tsunami deposits exist.

Lithium and strontium isotopic systematics in playas in Nevada, USA: constraints on the origin of lithium

Lithium-rich brine in playas is a major raw material for lithium production. Recently, lithium isotopic ratios (δ7Li) have been identified as a tool for investigating water–rock interactions. Thus, to constrain the origin of lithium in playas by the use of its isotopes, we conducted leaching experiments on various lacustrine sediment and evaporite deposit samples collected from playas in Nevada, USA. We determined lithium and strontium isotopic ratios and contents and trace element contents of the leachate, estimated the initial δ7Li values in the water flowing into the playas, and examined the origin of lithium in playas by comparison with δ7Li values of the possible sources. In samples from the playas, δ7Li values show some variation, reflecting differences both in isotopic fractionation during mineral formation and in initial δ7Li value in water flowing into each playa. However, all δ7Li values in this study are much lower than those in river water and groundwater samples from around the world, but they are close to those of volcanic rocks. Considering the temperature dependence of lithium isotopic fractionation between solid and fluid, these results indicate that the lithium concentrated in playas in Nevada was supplied mainly through high-temperature water–rock interaction associated with local hydrothermal activity and not directly by low-temperature weathering of surface materials. This study, which is the first to report lithium isotopic compositions in playas, demonstrates that δ7Li may be a useful tracer for determining the origin of lithium and evaluating its accumulation processes in playas.

Spatial and Seasonal Variation in Surface Water pCO2 in the Ganges, Brahmaputra, and Meghna Rivers on the Indian Subcontinent

Recent studies have remarked on the importance of direct CO2 release from river water into the atmosphere on the global carbon cycle over a short timescale. In this study, we investigated carbonate systems, including spatial and seasonal variations of pCO2, in three major Himalayan rivers in Bangladesh: the Ganges, Brahmaputra, and Meghna Rivers, and their potential importance. Although pCO2 is known to be low in the upper reaches of these rivers, owing to active chemical weathering, we observed pCO2 values higher than the atmospheric pCO2 level along their lower reaches, where deep soils have developed and where high air temperatures promote active soil respiration. By a simple mixing calculation, we found that seasonal variations in these river water carbonate systems are controlled by subsurface water flows. In the rainy season, most of the lowlands are inundated, and the contribution of subsurface flow to river water carbonate systems increases, resulting in higher pCO2 values. In future research, more detailed spatial and seasonal investigations are required to clarify the role of terrestrial ecosystems, including rivers and the CO2 flux to the atmosphere, in the global carbon cycle and to examine how that role will change under global warming.

Lithium isotopic systematics of submarine vent fluids from arc and back‐arc hydrothermal systems in the western Pacific

The Li concentration and isotopic composition (δ7Li) in submarine vent fluids are important for oceanic Li budget and potentially useful for investigating hydrothermal systems deep under the seafloor because hydrothermal vent fluids are highly enriched in Li relative to seawater. Although Li isotopic geochemistry has been studied at mid-ocean-ridge (MOR) hydrothermal sites, in arc and back-arc settings Li isotopic composition has not been systematically investigated. Here, we determined the δ7Li and 87Sr/86Sr values of 11 end-member fluids from 5 arc and back-arc hydrothermal systems in the western Pacific and examined Li behavior during high-temperature water–rock interactions in different geological settings. In sediment-starved hydrothermal systems (Manus Basin, Izu-Bonin Arc, Mariana Trough, and North Fiji Basin), the Li concentrations (0.23–1.30 mmol/kg) and δ7Li values (+4.3‰ to +7.2‰) of the end-member fluids are explained mainly by dissolution-precipitation model during high-temperature seawater–rock interactions at steady state. Low Li concentrations are attributable to temperature-related apportioning of Li in rock into the fluid phase and phase separation process. Small variation in Li among MOR sites is probably caused by low-temperature alteration process by diffusive hydrothermal fluids under the seafloor. In contrast, the highest Li concentrations (3.40 − 5.98 mmol/kg) and lowest δ7Li values (+1.6‰ to +2.4‰) of end-member fluids from the Okinawa Trough demonstrate that the Li is predominantly derived from marine sediments. The variation of Li in sediment-hosted sites can be explained by the differences in degree of hydrothermal fluid–sediment interactions associated with the thickness of the marine sediment overlying these hydrothermal sites. This article is protected by copyright. All rights reserved.

Rapid Alkalization in Lake Inawashiro, Fukushima, Japan: Implications for Future Changes in the Carbonate System of Terrestrial Waters

The global carbon cycle, one of the important biogeochemical cycles controlling the surface environment of the Earth, has been greatly affected by human activity. Anthropogenic nutrient loading from urban sewage and agricultural runoff has caused eutrophication of aquatic systems. The impact of this eutrophication and consequent photosynthetic activity on CO2 exchange between freshwater systems and the atmosphere is unclear. In this study, we focused on how nutrient loading to lakes affects their carbonate system. Here, we report results of surveys of lakes in Japan at different stages of eutrophication. Alkalization due to photosynthetic activity and decreases in PCO2 had occurred in eutrophic lakes (e.g., Lake Kasumigaura), whereas in an acidotrophic lake (Lake Inawashiro) that was impacted by volcanic hot springs, nutrient loading was changing the pH and carbon cycling. When the influence of volcanic activity was stronger in the past in Lake Inawashiro, precipitation of volcanic-derived iron and aluminum had removed nutrients by co-precipitation. During the last three decades, volcanic activity has weakened and the lake water has become alkalized. We inferred that this rapid alkalization did not result just from the reduction in acid inputs but was also strongly affected by increased photosynthetic activity during this period. Human activities affect many lakes in the world. These lakes may play an important part in the global carbon cycle through their influence on CO2 exchange between freshwater and the atmosphere. Biogeochemical changes and processes in these systems have important implications for future changes in aquatic carbonate systems on land.

Downstream and seasonal changes of lithium isotope ratios in the Ganges-Brahmaputra river system

The Li isotope ratio (δ7Li) is expected to be a useful tracer of silicate weathering in river and groundwater systems, which is an important contributor to the seawater compositional changes that accompany the evolution of the Earths surface environment. To obtain accurate estimates of continental Li fluxes to the ocean, we determined δ7Li values of dissolved Li in the lower Ganges-Brahmaputra river system in both the dry and rainy seasons, and in deep groundwater in the Bengal basin. Dissolved Li and δ7Li values in the lower reaches of the rivers (0.04–0.66 µmol kg−1 and +19.1‰ to +34.2‰, respectively) were predominantly derived from silicate weathering, as is the case in the upper parts of these rivers. We observed large changes in δ7Li over a distance of more than 1000 km downstream that were due mainly to Rayleigh-type removal of Li from river water. Extremely high Li concentrations (1.15–1.67 µmol kg−1) and low δ7Li values (+5.1‰ to +11.6‰) in groundwater samples indicate congruent isotope leaching and dissolution of silicate minerals in the deep aquifer, where the water residence time is long. In the rainy season, Li concentrations and δ7Li values were lower than in the dry season, owing to the shorter residence time of river water and the substantial input of local subsurface flow through lowland alluvium. These results suggest that accurate estimation of continental Li fluxes to the ocean should take account of downstream and seasonal changes, as well as aquifer depth variations, in δ7Li values.

Lithium, magnesium and sulfur purification from seawater using an ion chromatograph with a fraction collector system for stable isotope measurements

We describe the mass descrimination and validation of an offline method for purification of Li, Mg and S with an ion chromatograph coupled to an automated fraction collector for use prior to stable isotope measurements. Significant sub-fraction mass fractionation was observed for both the Li and the Mg stable isotope ratios. The lighter Li and heavier Mg isotopes were preferentially retained by the column, resulting in 7Li/6Li and 26Mg/24Mg biases up to 85.8‰ and 0.95‰, respectively. The isotopic compositions of Li, Mg, and S separated from seawater were δ7LiL-SVEC = +30.9‰, δ26MgDSM3 = -0.83 ± 0.10‰, and δ34SVCDT = +19.4 ± 0.6‰; each chromatographic peak was completely recovered, and the results were in good agreement with the published values regardless of whether or not chemical suppressor was used. The purification method enables multi-isotope analysis of a sample using various mass spectrometry techniques, such as multiple-collector inductively coupled plasma and thermal ionization mass spectrometry.