Daisy Nestler

Nonaqueous Atomic Layer Deposition of Aluminum Phosphate

Aluminum phosphate was deposited onto bundles of carbon fibers and flat glassy carbon substrates using atomic layer deposition by exposing them to alternating pulses of trimethylaluminum and triethylphosphate vapors. Energy dispersive X-ray spectroscopy (EDXS) and solid state nuclear magnetic resonance (SS-NMR) spectra confirmed that the coating comprises aluminum phosphate (orthophosphate as well as other stoichiometries). Scanning electron microscopic (SEM) images revealed that the coatings are uniform and conformal. After coating, the fibers are still separated from each other like the uncoated fibers. Thermogravimetric analysis (TGA) indicates an improvement of oxidation resistance of the coated fibers compared to uncoated fibers.

CAPAAL and CAPET – New Materials of High-Strength, High-Stiff Hybrid Laminates

The natural resources available for national and international economic development are limited. A gentler and more efficient use of available energy and materials in all sectors is essential. In mobile applications in particular, in which large masses are moved and accelerated (e.g. automotive, railway, aircraft and in machinery and equipment), a consequent lightweight construction is necessary for a significant saving of energy.

New Sandwich Structures Consisting of Aluminium Foam and Thermoplastic Hybrid Laminate Top Layers

Sandwich structures consist of one light core layer and two top layers, which form the load-bearing structure. These layers have to be stiff and strong and have to protect the structure against indentations. The main task of the core layer is to keep the top layers in place and to generate a high shear stiffness. In order to obtain the required space between the top layers, the core layer has to have a high specific volume. Different sandwich materials with aluminium or steel top layers and cores of aluminium combs, corrugated aluminium sheets or aluminium foams are already known. In order to obtain better properties in terms of strength fibre-reinforced plastics (FRP) are utilised as top layers; this is the focus of numerous of the current research studies. The sole use of these materials leads to negative effects regarding the damage and impact behaviour. New top layers with high strength and high stiffness characteristics as well as good damage tolerances are to be expected by utilising metal layers in combination with endless fibre-reinforced plastics, so called hybrid laminates. These hybrid laminates combine the positive properties of metals (e.g. ductility) and fibre-reinforced plastics (e.g. tensile strength). The focus of this investigation lies on the production and characterisation of sandwich structures with aluminium foam core layers and hybrid laminate top layers. The foam cores consist of closed pore aluminium foams produced by utilising ingot and powder metallurgical techniques. The top layers consist of glass fibre-reinforced thermoplastics and aluminium layers. The production of the sandwich materials is realised by means of thermal pressing.

Material Selection and Process Configuration for Free-Form, Voluminous and Textile-Based Multi-Material-Design by the Example of a Bucket Seat

Hybrid textile-based composites possess an enormous potential for energy and resource efficient large-scale production, with freedom in and high specific mechanical properties. This paper covers the connection of available and established production processes for textiles in a differential process chain for the manufacturing of complex shaped and elastic sandwich components. The technology enables both stiffness and comfort through elasticity.OLU-Preg®-organic sheets, polyurethane foam cores and 3D-spacer fabrics form the targeted properties of demonstrator models. This article refers to the demonstrator part “bucket seat”. To show the benefit of complex composite material, the lightweight and mechanical properties of the sandwich structures are tested in several variations of core and comfort shapes. Absolute and specific improvements of performance are shown in static and dynamic examinations. An Analysis of coupling effects, deformation and failure behavior of the multi-material design (MMD) complete the scientific approach of the structure-property relationships of hybrid composites.

Development and Characterisation of Phenolic Resin Moulding Materials for the Production of New Short Fibre-Reinforced C/C-SiC Composites

This article focuses on the development of phenolic resin moulding materials for the production of new carbon fibre-reinforced ceramic composite materials based on C/C-SiC by utilising the LSI (liquid silicon infiltration) production method. The production of these moulding materials is being accomplished by combining phenolic resin and carbon fibres with the addition of a few selected parts of processing aids, during which the influence of the used lubricants on the processability of the moulding materials is examined. The starting materials, microstructures and mechanical properties of the materials were characterised at every step of the entire process (CFRP and C/C composites) as well as the end of the whole production (C/C-SiC composites). During this investigation a link between the portions of the lubricant used, the forming of the porosity and the impact on the mechanical properties was discovered. In regards to the optimisation of the process the involved parties were able to determine an optimal lubricant ratio.

Powder Metallurgy of Particle-Reinforced Aluminium Matrix Composites (AMC) by Means of High-Energy Ball Milling

This paper deals with the production of aluminium matrix composites through high-energy milling, hot isostatic pressing and extrusion. Spherical powder of the aluminium alloy AA2017 (grain fraction > 100 μm) was used as matrix material. SiC and Al2O3 powders of submicron and micron grain size (< 2 μm) where chosen as reinforcement particles with contents between 5 and 15 vol.% respectively. The high-energy milling process was realised in a Simoloyer mill (Zoz). The milling time was about 4 hours. Hot isostatic pressing (HIP) was used to convert the compound powder into compact material. The extrusion process realises semi-finished products with different geometrical shapes.

An innovative production method for a C/C-SiC brake disc, suitable for a large-scale production

The industrial progress and the market-oriented management concepts result in increasing demands of the industry for improved performances while simultaneously improving on the energy efficiency. This results in the necessity for a progressive implementation of high-performance materials in areas such as the automotive industry, engineering, as well as applications in aerospace industry. Especially construction elements taking on large stresses call for excellent mechanical properties even at extremely high temperatures. In these high-temperature ranges only engineering ceramics, which unfortunately are very limited regarding the application due to the very brittle characteristics, showcase sufficient strength values.

Investigation of Different Phenolic Resins and their Behavior during Pyrolysis to Form SiC/C-Composites

Specific phenolic resin samples have been developed as the carbon precursor for SiC/C composites. Liquid phenolic resins suitable for fiber-infiltration in the resin transfer moulding (RTM) process are synthesized by using versatile combination of the aromatic component (phenol, naphthalen-2-ol) with various formaldehyde equivalents such as methanal, 1,3,5,7tetraazatricyclo [3.3.1.13,7] decane (urotropine), and 1,3,5-trioxane, under different reaction conditions. Room temperature liquid resoles (RTLR) are obtained by using an excess of the formaldehyde component over phenol (≥2) under basic conditions. Upon heating RTLR can form a crosslinked network even without addition of a hardening reagent. In addition, novolacs are synthesized under acidic conditions using a phenol/formaldehyde ratio ≥1. Nitrogen-containing resins contain nitrogen due to reaction of phenol with urotropine. Novolacs and nitrogen-containing resins are solids at room temperature and not self-curing. To infiltrate these both resins into SiC fibers in the RTM process, they are dissolved in 2furanmethanol (furfuryl alcohol FA) and urotropine which is added as curing-agent. Both, the molecular weight and the amount of the dissolved phenolic resin have an influence on the viscosity and the carbon yield after pyrolysis which is important for this application. The aim was to create different phenolic resins for the fabrication in the RTM process and to characterize the carbon after pyrolysis with respect to the structure and porosity as these are key parameters to generate a stoichiometric SiC matrix by LSI.

Investigation of the specific adhesion between polyurethane foams and thermoplastics to suited material selection in lightweight structures

Lightweight construction combines various materials to create resource efficient components. Thermoplastics (TPs) combined with polyurethane (PUR) foams are increasingly used to create hybrid composites. Optimizing the energy efficiency is one of the main issues in the development of production processes of components. Reducing the number of process steps offers great potential in this respect. PUR foam develops a strong adhesive bond with most materials. This is used for the manufacturing of hybrid composite components by filling complex cavities with PUR foam simultaneously bonded with other TP polymer components. This way, one process step for joining is saved. The interfaces in this composite structures are critical points of the failure. A huge variety of TP is used for the production of hybrid composite components and PUR foam develops varying bonding strengths with all of them. Selecting the suitable TPs for a durable bonding with PUR foam in the desired production process necessarily requires information about the respective specific adhesion. In this investigation, different TPs were processed with PUR foams in order to manufacture sandwich composites. The TP facings are produced in the injection moulding process. Subsequently, the facings are combined with the foam core during reaction injection moulding. The wetting behaviour was examined using the contact angle measurement and the mechanical strength of the interface in the sandwich composite was determined using a tensile test. A precise order of the selected TPs concerning their specific adhesion to PUR foams was achieved with these investigative methods.

New approach to design of ceramic/polymer material compounds

The damage tolerance of carbon fibre-reinforced ceramic-matrix composite materials depends on their porosity and can be rather significant. Complex structures are difficult to produce. The integration of simple geometric structures of ceramic-matrix composite materials in complex polymer-based hybrid structures is a possible approach of realising those structures. These hybrid material compounds, produced in a cost-efficient way, combine the different advantages of the individual components in one hybrid material compound. In addition the individual parts can be designed to fit a specific application and the resulting forces. All these different advantages result in a significant reduction of not only the production costs and the production time, but also opens up new areas of application, such as the large-scale production of wear-resistant and chemically inert, energy dampening components for reactors or in areas of medicine. The low wettability of the ceramic component however is a disadvantage of this approach. During the course of this contribution, different C/C composite materials with a specific porosity were produced, while adjusting the resin/hardening agent-ratio, as well as the processing parameters. After the production, different penetration tests were conducted with a polymer component. The final part of the article is comprised of the microstructural analysis and the explanation of the mechanical relationships.