Dale P. Cruikshank

Evidence for Methane Segregation at the Surface of Pluto

Abstract In May 1995, a set of spectrophotometric curves of the system Pluto–Charon were recorded with the UKIRT telescope equipped with the spectrometer CGS4. The spectra cover the near-infrared range between 1.4 and 2.55 μm with a resolution of approximately 700. The existence of solid methane is confirmed by numerous absorption bands, and carbon monoxide and nitrogen ices are identified by their respective signatures at 2.35 and 2.15 μm. We have modeled the spectrum of May 15 that corresponds to the maximum of Plutos visible lightcurve using a radiative transfer algorithm dealing with compact and stratified media. A geographical mixture of three distinct units is required to explain all the significant structures of the analyzed spectrum. The first unit is a thin, fine-grained layer of pure CH4 covering a compact polycrystalline substratum of N2–CH4–CO, which are in a molecular mixture (concentrations of CH4 and CO of the order of 0.5 and 0.1–0.2% respectively). It covers about 70% of the observed area and corresponds to volatile deposits that are sublimating under solar illumination. The second unit is either (a) a single thick layer of pure large-grained methane or (b) a unit with large-grained CH4 forming a substratum and the N2–CH4–CO mixture a superficial layer of fine grains covering 20% of the surface. Finally, the third unit is bright and spectrally neutral and is first modeled as a layer of very fine grains of nearly pure N2. Tholin, suggested to explain the red slope in the visible, is also found to be spectrally compatible with this unit. It covers the remainder of the surface (about 10–15%). All these results allow a better understanding of the processes of deposition, metamorphism, sublimation, and transport affecting the different ices detected on Pluto during its climatic cycles.

The formation of Charon’s red poles from seasonally cold-trapped volatiles

A unique feature of Pluto’s large satellite Charon is its dark red northern polar cap. Similar colours on Pluto’s surface have been attributed to tholin-like organic macromolecules produced by energetic radiation processing of hydrocarbons. The polar location on Charon implicates the temperature extremes that result from Charon’s high obliquity and long seasons in the production of this material. The escape of Pluto’s atmosphere provides a potential feedstock for a complex chemistry. Gas from Pluto that is transiently cold-trapped and processed at Charon’s winter pole was proposed as an explanation for the dark coloration on the basis of an image of Charon’s northern hemisphere, but not modelled quantitatively. Here we report images of the southern hemisphere illuminated by Pluto-shine and also images taken during the approach phase that show the northern polar cap over a range of longitudes. We model the surface thermal environment on Charon and the supply and temporary cold-trapping of material escaping from Pluto, as well as the photolytic processing of this material into more complex and less volatile molecules while cold-trapped. The model results are consistent with the proposed mechanism for producing the observed colour pattern on Charon.

Organic matter on asteroid 130 elektra.

Infrared absorption spectra of a low-albedo water-rich asteroid appear to show a weak 3.4-micrometer carbon-hydrogen stretching mode band, which suggests the presence of hydrocarbons on asteroid 130 Elektra. The organic extract from the primitive carbonaceous chondritic Murchison meteorite shows similar spectral bands.

(90377) SEDNA: INVESTIGATION OF SURFACE COMPOSITIONAL VARIATION*

The dwarf planet (90377) Sedna is one of the most remote solar system objects accessible to investigations. To better constrain its surface composition and to investigate the possible heterogeneity of the surface of Sedna, several observations have been carried out at ESO-VLT with the powerful spectrometer SINFONI observing simultaneously the H and K bands. The analyzed spectra (obtained in 2005, 2007, and 2008) show a non-uniform spectral signature, particularly in the K band. Spectral modeling using the Shkuratov radiative transfer code for surface scattering has been performed using the various sets of data, including previous observations at visible wavelengths and photometry at 3.6 and 4.5 ?m by the Spitzer Space Telescope. The visible and near-infrared spectra can be modeled with organic materials (triton and titan tholin), serpentine, and H2O ice in fairly significant amounts, and CH4, N2, and C2H6 in varying trace amounts. One of the spectra obtained in 2005 October shows a different signature in the K band and is best modeled with CH3OH in place of CH4, with reduced amounts of serpentine and with the addition of olivine. The compositional surface heterogeneity can give input on the past history as well clues to the origin of this peculiar, distant object.

Observations and Laboratory Data of Planetary Organics

Interpretations of telescopic observations show that H2O ice is ubiquitous on surfaces throughout many regions of the outer Solar System. Additionally, carbon-bearing molecular material is emerging as a major component in the outer Solar System, where it appears entrained in H2O ice on comets and many planetary satellites, and in the more volatile N2 ice on Triton and Pluto. Complex macromolecular carbon, long known in carbonaceous meteorites, appears to be a notable component of comets, planetary satellites, and small trans-Neptunian bodies. Some of this material may be retained from the solar nebula, but some of it originates in the surface ices (and in a few cases, in the tenuous atmospheres) through energetic processing by uv radiation, cosmic rays, and magnetospheric particles. Laboratory studies of the reflectance properties and chemical reactions associated with C-, H-, and N-bearing precursor gases and ices show that the stable residues created exhibit a range of coloration at visual and near-infrared wavelengths. Modeling of the telescopic observations using these residues suggest they are capable of giving rise to the observed variable red color of many surfaces in the outer Solar System.

Organic matter in the Titan lakes, and comparison with primitive Earth

Titan is the only world in the solar system besides the Earth that has liquid on its surface. The liquid in the lakes is thought to be composed primarily of ethane with methane and nitrogen in solution. The clouds are thought to be composed of liquid methane drops. Surface liquid is present in polar lakes and in surface materials at equatorial sites. Studying the chemical processing that potentially results from organic material interacting with this liquid is one of the main goals of proposed missions to Titan. We have been engaged in producing tholin under Titan-like conditions for more than three decades, first at the Laboratory for Planetary Studies at Cornell University in collaboration with Late Dr. Carl Sagan and for over a decade at Laboratory for Planetary Studies at NASA Ames Research Center and Carl Sagan Center for the Study of Life in the Universe, SETI Institute. Our focus is to understand the capabilities for analysis of tholin solubility in liquid methane and ethane for flight instruments....