Dalva Cristina Baptista do Lago

Influence of cathodic current density and mechanical stirring on the electrodeposition of Cu-Co alloys in citrate bath

Cathodic polarization curves of Cu-Co alloys were galvanostatically obtained on a platinum net, using electrolytes containing copper and cobalt sulfates, sodium citrate and boric acid (pH values ranging from 4.88 to 6.00), with different mechanical stirring conditions. In order to evaluate quantitatively the influence of the applied current density and the mechanical stirring on the cathodic efficiency, the alloy composition for the Cu-Co alloy deposition process, and the average deposition potential, an experimental central composite design 22 was employed, and three current density intervals (0.11 to 0.60, 0.50 to 1.98 and 2.44 to 9.94 mA.cm-2) were chosen from the polarization curves for this purpose. The results indicated that the current density (mainly in the range between 0.11 and 0.60 mA.cm-2) affected significantly all the studied variables. In the intermediate range (0.50 to 1.98 mA.cm-2), only the average potential was influenced by the current density. On the other hand, the mechanical stirring had a significant effect only on the copper content, for both the lowest (0.11 to 0.60 mA.cm-2) and the highest current density range (2.44 to 9.94 mA.cm-2). Indeed, in the last range, none of the studied deposition parameters presented significant influence on the studied variables, except for the copper content. This could probably be explained by the direct incorporation of Cu-Citrate complexes in the coating, which was enhanced at high current values.

Corrosion evaluation of orthodontic wires in artificial saliva solutions by using response surface methodology

and response surface methodology. The open circuit potential (OCP) was measured over the same period of time. Polarization curves and morphological analysis of the wires before and after the corrosion experiments were also carried out. The results showed that corrosion of the studied metal alloys depended on a combination among saliva pH, the exposition time, and the concentration of F - ions in the solution. The critical condition was observed for Ni-Ti wires at pH = 3.0, and high concentration of F - ions, causing a decrease in the OCP values and an increase in Ni dissolution and corrosion current density.

Electrodeposition of Cobalt Rich Zn-Co alloy Coatings from Citrate Bath

Zn-Co alloy coatings were produced on carbon steel, at room temperature, from citrate baths (0.100 mol L-1) containing [Zn2+]= [Co2+] = 0.05 mol L-1. Coatings with %m/m Co > %m/m Zn were observed under all deposition conditions, except for I = 10 A m-2. As the current density (I) was increased, a significant decrease (p<0.05) in %m/m Zn was noted, and the highest value of % m/m Co was observed at 80 A m-2. The Co-rich coatings presented refined microstructure, with small grain sizes. The smallest Icorr of the studied substrate/coatings systems, 2.4 µA cm-2, was obtained at I = 10 A m-2. Under these conditions, the coatings contained ~ 30 % m/m Co and 70 % m/m Zn and only the γ-ZnCo phase was obtained. The Icorr found in the present work is smaller than those usually found in the literature for Zn-Co coatings with small Co content.

Statistic evaluation of cysteine and allyl alcohol as additives for Cu-Zn coatings from citrate baths

In the present work, cysteine and allyl alcohol were added to citrate baths as additives to Cu-Zn coatings on steel substrates. In order to verify the effects of the deposition parameters (current density, mechanical stirring speed, and additives) on the coating composition, electrochemical behavior, morphology, and microstructure properties of Cu-Zn coatings, the electrodeposition of the alloy was carried out using an experimental composite design 23, in which these parameters were considered the entry variables and the measured properties were the response variables. The confidence level was 95% and the results were shown as response surface diagrams. It was possible to verify that the current density affected the zinc content in the coating, while the coating produced from cysteine-contained bath presented the worse anticorrosive performance. In a general way, it was possible to observe that the studied parameters affected the morphology, grain size, and the electrochemical behavior of these coatings, although only a few response variables were statistically influenced by them.

A review of Corrosion Resistance Nanocomposite Coatings

The deterioration of materials, particularly metals, under the influence of electrochemical corrosion is a high cost problem faced by nearly all industries. The reduction of corrosion processes and the prevention of future problems require a detailed knowledge of these processes and of the strategies to avoid them. In this context, it is essential to use method‐ ologies that may prevent the electrochemical deterioration of materials as well as monitor their performance in aggressive environments. Among them, it is possible to cite the use of functional coatings, particularly nanocomposite coatings. Therefore, this chapter pro‐ poses a review concerning the production of nanocomposite coatings with anticorrosive application obtained by electrodeposition technique (electrochemical codeposition). The production of such coatings is in agreement with the current needs of innovation, which drives a requirement for scientific advancement and the need for fundamental research. In this context, nanocomposite coatings with anticorrosive properties promote changes in metal surfaces, creating new materials with improved characteristics compared to those originally observed and maintaining the integrity of these surfaces.

Influence of stress corrosion on the mechanical properties of laser-welded titanium

STATEMENT OF PROBLEM Whether laser-welded (LW) titanium can resist the stress corrosion produced by the combination of fluoride ions and stress in the oral environment is unknown. PURPOSE The purpose of this in vitro study was to investigate the influence of stress corrosion on the mechanical properties of LW titanium. MATERIAL AND METHODS Twenty-seven titanium bars (25×2 mm) with a circular cross-section were cut in half and laser-welded, while another 27 nonwelded (NW) bars were used as the control. Thirty bars were submitted to a flexural load of 480 N at 1 Hz and immersed in artificial saliva at pH 6 (S1) or in 1000 ppm fluoride-containing saliva at pH 6.0 (S2) or 2.0 (S3) at room temperature for up to 4000 cycles. After the stress corrosion simulation, the tensile strength and Vickers microhardness were determined (n=5). Twelve LW and NW bars were submitted to the corrosion immersion test media for 51 days (n=2) to determine polarization curves (n=2) in an artificial saliva media. The corroded surface was examined with scanning electron microscopy (SEM). RESULTS The combination of fluoride and low pH significantly decreased the tensile strength of LW (P<.05). Stress corrosion did not affect the hardness of LW or NW (P>.05). NW bars immersed in S3 exhibited progressive surface dissolution, while LW bars spontaneously fractured at the welded area after 25 days of immersion in the same medium. SEM images demonstrated pitting corrosion without the presence of cracks in both groups immersed in S3. CONCLUSIONS Stress corrosion caused by acidic fluoride-containing saliva and flexural load cycling decreased the tensile strength and hardness of LW titanium bars.