Dana D. Swift

Long-Term Nitrate Measurements in the Ocean Using the in situ Ultraviolet Spectrophotometer: Sensor Integration into the APEX Profiling Float

AbstractReagent-free optical nitrate sensors [in situ ultraviolet spectrophotometer (ISUS)] can be used to detect nitrate throughout most of the ocean. Although the sensor is a relatively high-power device when operated continuously (7.5 W typical), the instrument can be operated in a low-power mode, where individual nitrate measurements require only a few seconds of instrument time and the system consumes only 45 J of energy per nitrate measurement. Operation in this mode has enabled the integration of ISUS sensors with Teledyne Webb Researchs Autonomous Profiling Explorer (APEX) profiling floats with a capability to operate to 2000 m. The energy consumed with each nitrate measurement is low enough to allow 60 nitrate observations on each vertical profile to 1000 m. Vertical resolution varies from 5 m near the surface to 50 m near 1000 m, and every 100 m below that. Primary lithium batteries allow more than 300 vertical profiles from a depth of 1000 m to be made, which corresponds to an endurance near f...

Biogeochemical sensor performance in the SOCCOM profiling float array

The Southern Ocean Carbon and Climate Observations and Modeling (SOCCOM) program has begun deploying a large array of biogeochemical sensors on profiling floats in the Southern Ocean. As of February 2016, 86 floats have been deployed. Here the focus is on 56 floats with quality controlled and adjusted data that have been in the water at least 6 months. The floats carry oxygen, nitrate, pH, chlorophyll fluorescence, and optical backscatter sensors. The raw data generated by these sensors can suffer from inaccurate initial calibrations and from sensor drift over time. Procedures to correct the data are defined. The initial accuracy of the adjusted concentrations is assessed by comparing the corrected data to laboratory measurements made on samples collected by a hydrographic cast with a rosette sampler at the float deployment station. The long-term accuracy of the corrected data is compared to the GLODAPv2 data set whenever a float made a profile within 20 km of a GLODAPv2 station. Based on these assessments, the fleet average oxygen data are accurate to 1±1%, nitrate to within 0.5±0.5 µmol kg−1, and pH to 0.005±0.01, where the error limit is 1 standard deviation of the fleet data. The bio-optical measurements of chlorophyll fluorescence and optical backscatter are used to estimate chlorophyll a and particulate organic carbon concentration. The particulate organic carbon concentrations inferred from optical backscatter appear accurate to with 35 mg C m−3 or 20%, whichever is larger. Factors affecting the accuracy of the estimated chlorophyll a concentrations are evaluated.

Three Years of Ocean Data From a Bio‐optical Profiling Float

Ocean color, first measured from space 30 years ago, has provided a revolutionary synoptic view of near-surface fields of phytoplankton pigments. Since 1979, a number of ocean color satellite missions have provided coverage of phytoplankton biomass and other biogeochemical variables on scales of days to years and of kilometers to ocean basin. Because of the nature of visible light and its interaction with absorbing and scattering materials in the ocean and atmosphere, these measurements are biased toward near-surface waters and are obscured by clouds. As a consequence, ocean color satellites miss significant fractions of phytoplankton biomass, marine primary productivity, and particle flux that occur at depths beyond their sensing range. They also miss phytoplankton blooms and other events that occur during periods of extended cloud cover.

Net community production at Ocean Station Papa observed with nitrate and oxygen sensors on profiling floats

Six profiling floats equipped with nitrate and oxygen sensors were deployed at Ocean Station P in the Gulf of Alaska. The resulting six calendar years and 10 float years of nitrate and oxygen data were used to determine an average annual cycle for net community production (NCP) in the top 35 m of the water column. NCP became positive in February as soon as the mixing activity in the surface layer began to weaken, but nearly 3 months before the traditionally defined mixed layer began to shoal from its winter time maximum. NCP displayed two maxima, one toward the end of May and another in August with a summertime minimum in June corresponding to the historical peak in mesozooplankton biomass. The average annual NCP was determined to be 1.5 ± 0.6 mol C m−2 yr−1 using nitrate and 1.5 ± 0.7 mol C m−2 yr−1 using oxygen. The results from oxygen data proved to be quite sensitive to the gas exchange model used as well as the accuracy of the oxygen measurement. Gas exchange models optimized for carbon dioxide flux generally ignore transport due to gas exchange through the injection of bubbles, and these models yield NCP values that are two to three time higher than the nitrate-based estimates. If nitrate and oxygen NCP rates are assumed to be related by the Redfield model, we show that the oxygen gas exchange model can be optimized by tuning the exchange terms to reproduce the nitrate NCP annual cycle.

RAFOS Floats: Defining and Targeting Surfaces of Neutral Buoyancy

Abstract For timescales much greater than the local buoyancy period, the buoyant response of a RAFOS float is virtually dictated by its compressibility. As the compressibility of a thermally inert RAFOS float increases from zero, its oceanic equilibrium surface undergoes a smooth continuous deformation starting from an in situ density surface, eventually merging with an isopycnal surface and finally with a neutral surface. Thus there is a continuum of operational modes available to RAFOS floats; each mode is associated with a critical compressibility. Hypothetically, the compressee that transforms an isobaric RAFOS float into an isopycnal float can be modified to make a neutral-surface drifter by altering the critical value of its compressibility. The ballast procedure used to target a float to a prescribed equilibrium surface can be viewed as an accurate (±3%) laboratory measurement of the floats compressibility. For current “isobaric” RAFOS floats, the mean measured compressibility was approximately 2....

Profiling Floats in SOCCOM: Technical Capabilities for Studying the Southern Ocean

We report on profiling float technology used in the Southern Ocean Carbon and Climate Observations and Models (SOCCOM) program, a 6 year study of the interaction of ocean physics and the carbon cycle in the Southern Ocean. A central part of this program is to produce and deploy 200 profiling floats equipped with CTD units and chemical sensors capable of measuring dissolved oxygen, nitrate, pH, chlorophyll fluorescence, and particulate backscatter. The performance of the first 63 floats deployed in SOCCOM is examined, and examples of the design criteria used in producing these floats are shown. Some of the sensors require surface measurements to be made in the dark at regular intervals, and the probability of ascending to the sea surface in the dark is estimated as a function of year-day and latitude. An energy budget derived from laboratory measurements shows that only about 25% of the total energy stored in the batteries is used by the biogeochemical sensors, which bodes well for the long-term survivability of the floats. The ice-avoidance algorithm is discussed in detail, and it is shown that it is working as designed and allowing unprecedented numbers of profiles to be collected beneath the wintertime ice cover. The overall reliability of the first group of SOCCOM floats is compared with a much larger ensemble of Argo floats; the results show that the SOCCOM floats are surviving at a rate similar to the Argo floats, which have been shown to have lifetimes in excess of 5 years.