Network


Latest external collaboration on country level. Dive into details by clicking on the dots.

Hotspot


Dive into the research topics where Daniel Bruck is active.

Publication


Featured researches published by Daniel Bruck.


Tetrahedron Letters | 1981

Protonation of acenaphthoquinone. A novel peripheral 10 π-electron aromatic system

Daniel Bruck; Abraham Minsky; Arie Dagan; Mordecai Rabinovitz

Acenaphthoquinone (1) undergoes ppotonation to afford the respective double protonation product 2. The proton and carbon NMR parameters of 2 are discussed.


Journal of The Chemical Society-perkin Transactions 1 | 1975

Observation of stable arylalkoxycarbenium ions: a nuclear magnetic resonance study

Daniel Bruck; Mordecai Rabinovitz

Stable carbenium ions are formed by treatment of acetals of aromatic aldehydes with BF3 or fluorosulphonic acid. The structure of these ions has been elucidated from their 1H chemical shifts. Additional evidence is the presence of a common counter ion in the series. Very good correlations were observed between the 1H chemical shifts and the respective Brown σ+ substituent constants emphasizing the dependence of these quantities on the charge density of the ions. The value of σ+ for the H–C+–OCH3 group is + 1.074 in the para-position and +0.916 in the meta-position, reflecting the strong electron-withdrawing properties of this group.


Journal of the American Chemical Society | 1976

Exhaustive protonation of benzenepolycarboxylic acid polymethyl esters. Polycarbenium ions surrounding a benzene ring

Daniel Bruck; Mordecai Rabinovitz


Tetrahedron Letters | 1978

Protonation of indane-1,2,3-trione: Formation of 1,2,3-trihydroxyindane trication - a new aromatic system

Daniel Bruck; Arie Dagan; Mordecai Rabinovitz


Journal of the American Chemical Society | 1977

Protonation of phthalic acid: an unusual acylium-carboxonium rearrangement

Daniel Bruck; Mordecai Rabionvitz


Magnetic Resonance in Chemistry | 1978

Additivity of proton and carbon nmr chemical shifts in protonated benzene carboxylic acids

Daniel Bruck; Mordecai Rabinovitz


Tetrahedron Letters | 1977

Conformation of the carbonyl groups in benzenepolycarboxylic acids and related compounds

Daniel Bruck; Mordecai Rabinovitz


Tetrahedron Letters | 1977

Tribenzo[a,c,f]cyclooctyl anion and tetrabenzo[a,de,h,kl]bicyclo[6,6.0]tetradecyl dianion and the question of their homoaromaticity. Benzannelated homopentadienyl and homopentalenyl anions.

Arie Dagan; Daniel Bruck; Mordecai Rabinovitz


ChemInform | 1976

EXHAUSTIVE PROTONATION OF BENZENEPOLYCARBOXYLIC ACID POLYMETHYL ESTERS. POLYCARBENIUM IONS SURROUNDING A BENZENE RING

Daniel Bruck; Mordecai Rabinovitz


Tetrahedron Letters | 1972

Arylalkoxy dicarbonium ions

Mordecai Rabinovitz; Daniel Bruck

Collaboration


Dive into the Daniel Bruck's collaboration.

Top Co-Authors

Avatar

Mordecai Rabinovitz

Hebrew University of Jerusalem

View shared research outputs
Top Co-Authors

Avatar

Arie Dagan

Hebrew University of Jerusalem

View shared research outputs
Top Co-Authors

Avatar

Abraham Minsky

Hebrew University of Jerusalem

View shared research outputs
Researchain Logo
Decentralizing Knowledge