Daniel Bucur

Low cost adsorbents obtained from ash for copper removal

We investigated the utilization of ash and modified ash as a low-cost adsorbent to remove copper ions from aqueous solutions such as wastewater. Batch experiments were conducted to determine the factors affecting adsorption of copper. The influence of pH, adsorbent dose, initial Cu2+ concentration, type of adsorbent and contact time on the adsorption capacity of Cu2+ from aqueous solution by the batch adsorption technique using ash and modified ash as a low-cost adsorbent were investigated. The optimum pH required for maximum adsorption was found to be 5. The results from the sorption process showed that the maximum adsorption rate was obtained at 300 mg/L when a different dosage of fly ash was added into the solution, and it can be concluded that decreasing the initial concentration of copper ion is beneficial to the adsorption capacity of the adsorbent. With the increase of pH value, the removal rate increased. When the pH was 5, the removal rate reached the maximum of over 99%. When initial copper content was 300 mg/L and the pH value was 5, the adsorption capacity of the zeolite Z 4 sample reached 27.904 mg/g. The main removal mechanisms were assumed to be the adsorption at the surface of the fly ash together with the precipitation from the solution. The adsorption equilibrium was achieved at pH 5 between 1 and 4 hours in function of type of adsorbent. A dose of 1: 25 g/mL of adsorbent was sufficient for the optimum removal of copper ions. For all synthesized adsorbents the predominant mechanism can be described by pseudo-second order kinetics.

Technical Efficiency of the Subsurface Drainage on Agricultural Lands in the Moldova River Meadow

This study aims to investigate the technical efficiency of different subsurface drainage variants, in terms of the depth of the tile drains, spacing between the drain lines, type and thickness of the drain + filter complex, and the improvement procedures. Within the four variants, the discharge rate of the soil moisture excess was studied. In variants A and D, the spacing between drains is 20 m, and in the variants B and E, the spacing is 15 m. The depth of the tile drains is 0.8 m in variants D and E and 1.0 m in variants A and B. In variant A, tile drainage was combined with land shaping in the bedding system with top of ridges and furrows. Soil moisture was determined on checkpoints placed on drain cross section, at 2 m from drain lines, and of the middle of the drain spacing. In the version with land shaping, the drain lines located under the furrows favor the excess moisture removal. A similar technical efficiency was recorded in unimproved variant but with spacing between drains of 15 m. Best efficiency at removing excess water was registered in variant of the filtering material from ballast associated with flax strains.

Synthesis of Zeolite from Fly Ash and their Use as Soil Amendment

The amendments may be natural or synthetic and by their origin organic or inorganic. Among amendments, the inorganic ones are recommended, such as gypsum, lime, zeolites and altered rocks, including sand, ceramic, perlite, ash, slag, zeolite, pyrites, dolomite, calcined clay, etc. Fly ash-based zeolites can be used as amendments to improve the use of the soil for agricultural purposes. Generally, there are different methods for the synthesis of new materials using solid waste – fly ashes. Methods are known to be composed of a single stage or two stages. The first method – the conven‐ tional – is direct hydrothermal conversion of the mixture of ash and alkaline solution (NaOH or KOH), but only 50% of ashes can be converted into zeolite. The second method consists in mixing the ash with KOH and fusion at elevated temperature. The method leads to an advanced conversion – the type of zeolite depending on treatment conditions. Other studies recommend the conversion of ash using microwave ovens or ultrasound bath; in this case, the conversion time is reduced to 1–2 hours. From these methods, the direct method was proposed to be used in synthesizing zeolites for agriculture, with a part in controlling release of fertilizers and as a soil amendment. The synthesized materials were characterized with respect to microstructure (electronic microscopy SEM) and chemical and mineralogical composition (EDAX, X-ray diffraction). By analyzing the obtained data, one may observe the destruction of the ash network and crystallization of the zeolitic phase, especially in the case of treatment by diffusion. The XRD analysis confirms the presence of zeolite in materials obtained. Good results were also obtained in the case of using ultrasound treatment for zeolite synthesis; also, the time of treatment significantly decreased in this case.

Obtaining and Utilizing Cellulose Fibers with in-Situ Loading as an Additive for Printing Paper

The goal of this study was to analyze the effects of cellulose fibers loading by precipitation in-situ of calcium carbonate over the properties of printing paper obtained from mixtures of the softwood and hardwood fibers. The effects of fibers with in-situ loading were analyzed comparatively with conventional paper loading respectively, by adding precipitated calcium carbonate into fiber stock. The effectiveness of the methods was evaluated by various analyses and investigations: calcium carbonate content, Scanning electron microscope (SEM) images, X-ray diffraction, optical and mechanical properties of the paper sheets. The evaluation of the effects on paper properties led to the conclusion that, at the same filler content, the in-situ loading method gives higher opacity and brightness than conventional methods. The utilization of cellulose fibers with in-situ loading as additive, shown as a modification of the ratio between fibers with in-situ loading and fibers without loading, regardless of whether they are softwood or hardwood fibers, allowed us to optimize printing paper properties, especially regarding the relationship between optical and strength properties.

Tile Drainage on Agricultural Lands from North- East Romania - Experimental Variants and Technical Efficiency

Romania is situated in geographical center of Europe (south-east of Central Europe) at north of Balkan Peninsula at the half of distance between Atlantic Coast and The Urals, inside and outside the Carpathians Arch, on the Danube lower course and has exit to the Black Sea. Otherwise, parallel 45°N with the meridian 25°E intersects near the geometrical center of the country, 100 km N-V of the country capital, Bucharest. Romania is the twelfth country of Europe, having an area of 238,391 km2.