Daniel R. Joswiak

Climatic and atmospheric circulation pattern variability from ice-core isotope/geochemistry records (Altai, Tien Shan and Tibet)

Abstract Several firn/ice cores were recovered from the Siberian Altai (Belukha plateau), central Tien Shan (Inilchek glacier) and the Tibetan Plateau (Zuoqiupu glacier, Bomi) from 1998 to 2003. The comparison analyses of stable-isotope/geochemistry records obtained from these firn/ice cores identified the physical links controlling the climate-related signals at the seasonal-scale variability. The core data related to physical stratigraphy, meteorology and synoptic atmospheric dynamics were the basis for calibration, validation and clustering of the relationships between the firn-/ice-core isotope/ geochemistry and snow accumulation, air temperature and precipitation origin. The mean annual accumulation (in water equivalent) was 106 gcm−2 a−1 at Inilchek glacier, 69 gcm−2 a−1 at Belukha and 196 g cm−2 a−1 at Zuoqiupu. The slopes in regression lines between the δ18O ice-core records and air temperature were found to be positive for the Tien Shan and Altai glaciers and negative for southeastern Tibet, where heavy amounts of isotopically depleted precipitation occur during summer monsoons. The technique of coupling synoptic climatology and meteorological data with δ18O and d-excess in firn-core records was developed to determine climate-related signals and to identify the origin of moisture. In Altai, two-thirds of accumulation from 1984 to 2001 was formed from oceanic precipitation, and the rest of the precipitation was recycled over Aral–Caspian sources. In the Tien Shan, 87% of snow accumulation forms by precipitation originating from the Aral–Caspian closed basin, the eastern Mediterranean and Black Seas, and 13% from the North Atlantic.

Stable-Isotope and Trace Element Time Series from Fedchenko Glacier (Pamirs) Snow/Firn Cores

In summer 2005, two pilot snow/firn cores were obtained at 5365 and 5206 m a.s.l. on Fedchenko glacier, Pamirs, Tajikistan, the worlds longest and deepest alpine glacier. The well-defined seasonal layering appearing in stable-isotope and trace element distribution identified the physical links controlling the climate and aerosol concentration signals. Air temperature and humidity/precipitation were the primary determinants of stable-isotope ratios. Most precipitation over the Pamirs originated in the Atlantic. In summer, water vapor was re-evaporated from semi-arid regions in central Eurasia. The semi-arid regions contribute to non-soluble aerosol loading in snow accumulated on Fedchenko glacier. In the Pamir core, concentrations of rare earth elements, major and other elements were less than those in the Tien Shan but greater than those in Antarctica, Greenland, the Alps and the Altai. The content of heavy metals in the Fedchenko cores is 2-14 times lower than in the Altai glaciers. Loess from Afghan- Tajik deposits is the predominant lithogenic material transported to the Pamirs. Trace elements generally showed that aerosol concentration tended to increase on the windward slopes during dust storms but tended to decrease with altitude under clear conditions. The trace element profile documented one of the most severe droughts in the 20th century.

The Influence of Dust on Quantitative Measurements of Black Carbon in Ice and Snow when Using a Thermal Optical Method

Accurate measurements of black carbon concentrations in snow and ice are essential to quantify its impact on glacial melting and sequential climate forcing via snow albedo. However, snow and ice contain dust that may severely bias the precision of the elemental carbon (EC) and organic carbon (OC) measurements of filters with a thermal/optical method. To evaluate the effects of dust on black carbon analysis and to optimize filtration methods, meltwater from ice core and surface snow samples with variable dust content were filtered with different methods, including filtration of the entire material (including settling) and supernatant liquid, mechanical stirring and sonication, as well as utilization of single and double quartz filters. In this research, it is shown that dust can induce an extra decrease in optical reflectance during the 250°C heating stage in the thermal/optical method and an improper OC and EC split. To address this problem, a correction procedure was suggested and used to revise the OC and EC results. The OC, EC, and TC concentration variations from different filtration methods along the ice core depth and along surface snow elevation were illustrated. These results indicate that black carbon and dust generally mix as agglomerates. The agglomerate structure will contribute to the underestimation of EC and OC in the measurement. However, carbonaceous matter can be efficiently detached from dust particles by ultrasonic agitation of the meltwater samples, which significantly improves carbon volatilization during the thermal/optical analysis. Copyright 2012 American Association for Aerosol Research

Selected Organochlorine Pesticides and Polychlorinated Biphenyls in Urban Atmosphere of Pakistan: Concentration, Spatial Variation and Sources

Robust knowledge on the occurrence and distribution of persistent organic pollutants (POPs) in the atmosphere of low-latitude regions is inevitable to forecast their transportation to pristine ecosystem and assess toxicological impacts upon local biota. Despite the earlier revelation of organochlorine pesticides (OCPs) and polychlorinated biphenyls (PCBs) in soils/sediments and water bodies in Pakistan, knowledge about atmospheric levels and sources of these POPs remains limited. For the first time, a network of XAD resin-based passive air samplers (PAS) was established across megacities of Pakistan, i.e., Karachi, the coastal city, and Lahore, lying in an agricultural region. Typical geographical locations of the two cities allowed assessing the influence of source regions on the occurrence and distribution patterns of selected POPs. Average concentrations (ng/PAS) in both cities ranged as endosulfan 39-101, DDTs 63-92, HCHs 33-65, heptachlor 10-26, and PCBs 48-61. High concentrations of endosulfan and lindane as observed throughout Lahore were certainly due to their ongoing applications in surrounding agricultural fields. Lower proportions of parental DDTs as compared to their metabolites were observed in both cities, suggesting inputs of DDTs from older or secondary sources. Owing to ultimate discharge of countrys agricultural/industrial waste through river streams in to Arabian Sea, the coastal region of Karachi was found potential source of weathered POPs that could be dissipated at regional/global scales by maritime advections. The study contributes to the pool of information on fate and geographical distribution of POPs in subtropical developing countries.

Methods for assessing regional glacial lake variation and hazard in the southeastern Tibetan Plateau: a case study from the Boshula mountain range, China

Glaciers on the Tibetan Plateau are undergoing an accelerating retreat under climatic warming, with the immediate result of glacial lake outburst floods (GLOFs) becoming increasingly frequent. Glacial lakes in the southeast of the Tibetan Plateau are densely distributed. Due to the difficulties associated with field investigations of glacial lakes, including remote locations and harsh weather conditions, methods which combine remote sensing, geographic information systems and hydrodynamic modeling (HEC-RAS) with field investigation were developed to assess regional glacial lake variation and hazard. The methods can be divided into three levels. At the first level, multi-temporal satellite images were used to (1) study the variation of glacial lakes for the whole region during recent decades, as well as (2) qualitatively identify potentially dangerous glacial lakes (PDGLs). The second level is an in-depth evaluation of the degree of danger for selected PDGLs by ground-based surveys, and then verification of the first-level results. At the third level, the one-dimensional (1D) hydrodynamic model HEC-RAS was used to simulate the inundation characteristics of hypothetical outburst of PDGLs. The three levels downscale from the whole study area to individual PDGLs, and thus assess the hazard of glacial lakes progressively. The methods were then applied to a region of southeastern Tibet—the Boshula mountain range—to analyze the variation of glacial lakes and assess potential hazards posed by GLOFs. Since these methods employ easily accessible data and instruments, the application in other regions is promising.

Variations of water stable isotopes (delta O-18) in two lake basins, southern Tibetan Plateau

Abstract δ18O measurements based on systematic sampling and isotopic modeling have been adopted to study the controls of stable isotopes in lake water in two lake basins (lakes Yamdrok-tso and Puma Yum-tso) at two different elevations on the southern Tibetan Plateau. Temporally, δ18O values in precipitation and lake water display a seasonal fluctuation in both lakes. Spatially, δ18O values in the two lake basins increase by 10% from the termini of glaciers to the lake shores, by ∽1% from the lake shores to the lake center and by 0.4% from the water surface to depth in these lakes. The clear annual δ18O variations indicate that lake water mixes sufficiently in a short time. Model results show that glacial meltwater and surface lake-water temperature are not the dominant factors in the balance process of stable isotopes in lake water. Equilibrium δ18O values decrease by 0.8% for Yamdrok-tso lake and 0.6% for Puma Yum-tso lake when glacial meltwater contributions to these lakes shrink by 60%. δ18O ratios increase rapidly during the initial stages and take a longer time to approach the equilibrium value.

Addressing Climate Change Around the Tibetan Plateau

Most noted for the Himalayas, the Third Pole region encompasses several vast and varied mountain ranges, totaling 100,000 square kilometers of ice. For more than 4 years, Third Pole Environment (TPE) research program scientists and collaborators from around the globe have been racing to reveal, predict, and mediate the effects of global climate change on the mountainous region centered around the Tibetan Plateau, known as “Asias water tower” for its expansive ice cover whose sensitive environment regulates water flow to the biggest rivers in Asia.

Tibetan Plateau and beyond

Third Annual Third Pole Environment Workshop; Reykjavik, Iceland, 29 August to 1 September 2011 Recognizing the necessity of multinational, interdisciplinary environmental research on the Tibetan Plateau and surrounding mountain ranges—dubbed the “Third Pole” for its considerable ice mass and high elevation— the Third Pole Environment (TPE) program accepted an invitation from the president of Iceland and the University of Iceland to hold its third annual TPE workshop in Iceland. In accordance with TPEs mission to evaluate climate and environmental changes at both local and global scales, participants from 15 countries converged for 3 days of intensive discussions and presentations related to TPE research. The Third Pole glaciers are undergoing considerable retreat, which will likely affect more than 1.5 billion people living in the region