Daniel Schaub

First comparison between ground‐based and satellite‐borne measurements of tropospheric nitrogen dioxide in the Po basin

in the Mount Cimone area is good (R 2 = 0.9) with the mixing properties of the atmosphere being the most important parameter for a valid comparison of the measurements. However, even when the atmospheric mixing properties are optimal for comparison, the ratio between GOME and ground-based tropospheric column data may not be unity. It is demonstrated that the values obtained (less than 1) are related to the fraction of the satellite ground pixel occupied by the NO2 hot spot. INDEX TERMS: 0345 Atmospheric Composition and Structure: Pollution—urban and regional (0305); 0365 Atmospheric Composition and Structure: Troposphere—composition and chemistry; 0368 Atmospheric Composition and Structure: Troposphere—constituent transport and chemistry; 0360 Atmospheric Composition and Structure: Transmission and scattering of radiation; KEYWORDS: tropospheric NO2, satellite validation, Po basin

SCIAMACHY tropospheric NO 2 over Switzerland: estimates of NO x lifetimes and impact of the complex Alpine topography on the retrieval

This study evaluates NO 2 vertical tropospheric column densities (VTCs) retrieved from measurements of the Scanning Imaging Absorption Spectrometer for Atmospheric Chartography (SCIAMACHY) above Switzerland and the Alpine region. The close correlation between pixel averaged NO x emission rates from a spatially and temporally highly resolved inventory and the NO 2 VTCs under anticyclonic meteorological conditions demonstrates the general ability of SCIAMACHY to detect sources of NO x pollution in Switzerland. This correlation is further used to infer seasonal mean NO x lifetimes carefully taking into account the influence of the strong diurnal cycle in NO x emissions on these estimates. Lifetimes are estimated to 3.6 (±0.8) hours in summer and 13.1 (±3.8) hours in winter, the winter value being somewhat lower than previous estimates. A comparison between the 2003-2005 mean NO 2 VTC distribution over Switzerland and the corresponding 1996–2003 mean from the Global Ozone Monitoring Experiment (GOME) illustrates the much better capability of SCIAMACHY to resolve regional scale pollution features. However, the comparison of seasonal averages over the Swiss Plateau with GOME and ground based in situ observations indicates that SCIAMACHY exhibits a too weak seasonal cycle with comparatively high values in summer and low values in winter. A problem likely contributing to the reduced values in winter (not reported in earlier literature) is the use of inaccurate satellite pixel surface pressures derived from a coarse resolution global model in the retrieval. The marked topography in the Alpine region can lead to deviations of several hundred meters between the model assumed and the real pixel-averaged surface height. A sensitivity study based on selected clear sky SCIAMACHY NO 2 VTCs over the Swiss Plateau and two fixed a priori NO 2 profile shapes indicates that inaccurate pixel surface pressures affect retrieved NO 2 columns over complex terrain by up to 40%. For retrievals in the UV-visible spectral range with a decreasing sensitivity towards the earths surface, this effect is of major importance when the NO 2 resides close to the ground, a situation most frequently observed during winter.