Dante S. Lauretta

Orbit and Bulk Density of the OSIRIS-REx Target Asteroid (101955) Bennu

The target asteroid of the OSIRIS-REx asteroid sample return mission, (101955) Bennu (formerly 1999 RQ 36), is a half-kilometer near-Earth asteroid with an extraordinarily well constrained orbit. An extensive data set of optical astrometry from 1999 to 2013 and high-quality radar delay measurements to Bennu in 1999, 2005, and 2011 reveal the action of the Yarkovsky effect, with a mean semimajor axis drift rate da=dt ¼ð � 19:0 � 0:1 Þ� 10

Mercury abundances and isotopic compositions in the murchison (CM) and Allende (CV) carbonaceous chondrites

Abstract The abundance and isotopic composition of Hg was determined in bulk samples of both the Murchison (CM) and Allende (CV) carbonaceous chondrites using single- and multi-collector inductively coupled plasma mass spectrometry (ICP-MS). The bulk abundances of Hg are 294 ± 15 ng/g in Murchison and 30.0 ± 1.5 ng/g in Allende. These values are within the range of previous measurements of bulk Hg abundances by neutron activation analysis (NAA). Prior studies suggested that both meteorites contain isotopically anomalous Hg, with δ196/202Hg values for the anomalous, thermal-release components from bulk samples ranging from −260 ‰ to +440 ‰ in Murchison and from −620 ‰ to +540 ‰ in Allende Jovanovic and Reed 1976a , Jovanovic and Reed 1976b , Kumar and Goel 1992 . Our multi-collector ICP-MS measurements suggest that the relative abundances of all seven stable Hg isotopes in both meteorites are identical to terrestrial values within 0.2 to 0.5 ‰. On-line thermal-release experiments were performed by coupling a programmable oven with the single-collector ICP-MS. Powdered aliquots of each meteorite were linearly heated from room temperature to 900°C over twenty-five minutes under an Ar atmosphere to measure the isotopic composition of Hg released from the meteorites as a function of temperature. In separate experiments, the release profiles of S and Se were determined simultaneously with Hg to constrain the Hg distribution within the meteorites and to evaluate the possibility of Se interferences in previous NAA studies. The Hg-release patterns differ between Allende and Murchison. The Hg-release profile for Allende contains two distinct peaks, at 225° and 343°C, whereas the profile for Murchison has only one peak, at 344°C. No isotopically anomalous Hg was detected in the thermal-release experiments at a precision level of 5 to 30 ‰, depending on the isotope ratio. In both meteorites the Hg peak at ∼340°C correlates with a peak in the S-release profile. This correlation suggests that Hg is associated with S-bearing phases and, thus, that HgS is a major Hg-bearing phase in both meteorites. The Hg peak at 225°C for Allende is similar to release patterns of physically adsorbed Hg on silicate and metal grains. Prior studies suggested that the isotopic anomalies reported from NAA resulted from interference between 203Hg and 75Se. However, the amount of Se released from both meteorites, relative to Hg, is insufficient to produce all of the observed anomalies.

Mineralogy of Fine-Grained Rims in the ALH 81002 CM Chondrite

Abstract The mineralogy of fine-grained rims in ALH 81002, a relatively primitive CM carbonaceous chondrite, has been determined by using transmission electron microscopy. The most abundant phase is Mg-rich serpentine, which occurs in small (≤20 nm) crystals with cylindrical or fibrous morphologies. Cronstedtite, an Fe-rich phyllosilicate, occurs as relatively large (100 to 2500 nm), platy crystals. Some cronstedtite is coherently intergrown with tochilinite. In many cases, cronstedtite has been partially altered to serpentine. The compositions and textures of these two phases provide a mineralogical and morphologic alteration sequence that parallels the known compositional trend for CM chondrite matrix. Accessory minerals embedded within the phyllosilicates include chlorite, pentlandite, gypsum, olivine, kamacite, taenite, and chromite. Regions containing only anhydrous minerals also occur. The hydrated and anhydrous regions are in direct contact with each other, suggesting that the rims accreted material from multiple reservoirs.

Large enantiomeric excesses in primitive meteorites and the diverse effects of water in cosmochemical evolution.

Carbonaceous chondrites are meteoritic fragments of asteroids that avoided the geological reprocessing of larger planets and allow laboratory probing of early solar-nebula materials. Among these, Renazzo-type (CR) chondrites found in Antarctica appear remarkably pristine and are distinguished by abundant organic materials and water-soluble molecules such as amino acids and ammonia. We present a comprehensive analysis of the organic composition of selected CR meteorites of different petrographic classification and compare compounds’ abundance and distribution as they may relate to asteroidal aqueous processing and concomitant evolution of the mineral phases. We found that several CR compounds such as amino acids and sugar alcohols are fully represented in stones with no or minimal water exposure indicating a formation that, if solar, preceded parent body processes. The most pristine CRs also revealed natal enantiomeric excesses (ee) of up to 60%, much larger than ever recorded. However, aqueous alteration appears to affect CR soluble organic composition and abundances, in particular some diastereomeric amino acids may gauge its extent by the consequent racemization of their ee.

Making the Earth: Combining Dynamics and Chemistry in the Solar System

Abstract No terrestrial planet formation simulation completed to date has considered the detailed chemical composition of the planets produced. While many have considered possible water contents and late veneer compositions, none have examined the bulk elemental abundances of the planets produced as an important check of formation models. Here we report on the first study of this type. Bulk elemental abundances based on disk equilibrium studies have been determined for the simulated terrestrial planets of O’Brien et al. [O’Brien, D.P., Morbidelli, A., Levison, H.F., 2006. Icarus 184, 39–58]. These abundances are in excellent agreement with observed planetary values, indicating that the models of O’Brien et al. [O’Brien, D.P., Morbidelli, A., Levison, H.F., 2006. Icarus 184, 39–58] are successfully producing planets comparable to those of the Solar System in terms of both their dynamical and chemical properties. Significant amounts of water are accreted in the present simulations, implying that the terrestrial planets form “wet” and do not need significant water delivery from other sources. Under the assumption of equilibrium controlled chemistry, the biogenic species N and C still need to be delivered to the Earth as they are not accreted in significant proportions during the formation process. Negligible solar photospheric pollution is produced by the planetary formation process. Assuming similar levels of pollution in other planetary systems, this in turn implies that the high metallicity trend observed in extrasolar planetary systems is in fact primordial.

Extraterrestrial Flux of Potentially Prebiotic C, N, and P to the Early Earth

With growing evidence for a heavy bombardment period ending 4–3.8 billion years ago, meteorites and comets may have been an important source of prebiotic carbon, nitrogen, and phosphorus on the early Earth. Life may have originated shortly after the late-heavy bombardment, when concentrations of organic compounds and reactive phosphorus were enough to “kick life into gear”. This work quantifies the sources of potentially prebiotic, extraterrestrial C, N, and P and correlates these fluxes with a comparison to total Ir fluxes, and estimates the effect of atmosphere on the survival of material. We find (1) that carbonaceous chondrites were not a good source of organic compounds, but interplanetary dust particles provided a constant, steady flux of organic compounds to the surface of the Earth, (2) extraterrestrial metallic material was much more abundant on the early Earth, and delivered reactive P in the form of phosphide minerals to the Earth’s surface, and (3) large impacts provided substantial local enrichments of potentially prebiotic reagents. These results help elucidate the potential role of extraterrestrial matter in the origin of life.

The Origin of Asteroid 101955 (1999 RQ36)

Near-Earth asteroid (NEA) 101955 (1999 RQ36; henceforth RQ36) is especially accessible to spacecraft and is the primary target of NASAs OSIRIS-REx sample return mission; it is also a potentially hazardous asteroid. We combine dynamical and spectral information to identify the most likely main-belt origin of RQ36 and we conclude that it is the Polana family, located at a semimajor axis of about 2.42 AU. We also conclude that the Polana family may be the most important inner-belt source of low-albedo NEAs. These conclusions are based on the following results. (1) Dynamical evidence strongly favors an inner-belt, low-inclination (2.15 AU < a < 2.5 AU and i < 10°) origin, suggesting the ν6 resonance as the preferred (95% probability) delivery route. (2) This region is dominated by the Nysa and Polana families. (3) The Polana family is characterized by low albedos and B-class spectra or colors, the same albedo and spectral class as RQ36. (4) The Sloan Digital Sky Survey colors show that the Polana family is the branch of the Nysa-Polana complex that extends toward the ν6 resonance; furthermore, the Polana family has delivered objects of the size of RQ36 and larger into the ν6 resonance. (5) A quantitative comparison of visible and near-infrared spectra does not yield a unique match for RQ36; however, it is consistent with a compositional link between RQ36 and the Polana family.

The Murray Springs Clovis site, Pleistocene extinction, and the question of extraterrestrial impact

Some of the evidence for the recent hypothesis of an extraterrestrial impact that caused late Pleistocene megafaunal extinctions [Firestone et al. (2007) Proc Natl Acad Sci USA 104:16016–16021] was based upon samples collected at Murray Springs, a Clovis archaeological site in southeastern Arizona. Here we describe sampling and analyses of magnetic separates from within, above, and below the lower Younger Dryas boundary (LYDB) black mat at Murray Springs, as well as radiation measurements from the LYDB at Murray Springs and two other well-stratified Clovis sites. The main magnetic fraction at Murray Springs is maghemite. Magnetic microspherules have terrestrial origins but also occur as cosmic dust particles. We failed to find iridium or radiation anomalies. The evidence for massive biomass burning at Murray Springs is addressed and found to be lacking. We could not substantiate some of the claims by Firestone and others, but our findings do not preclude a terminal Pleistocene cosmic event.

Opaque minerals in the matrix of the Bishunpur (LL3.1) chondrite: constraints on the chondrule formation environment

Abstract The chemistry and mineralogy of a group of opaque mineral assemblages in the matrix of the Bishunpur LL3.1 ordinary chondrite provide insight into the nebular environment in which they formed. The assemblages consist of a kamacite (Fe,Ni) core that is rimmed by troilite (FeS) and fayalite (Fe2SiO4). Accessory phases in the rims include silica (SiO2), chromite (FeCr2O4), whitlockite (Ca3(PO4)2), maricite (FeNaPO4), magnetite (Fe3O4), and tetrataenite (FeNi). We suggest that the metal melted in and equilibrated with an igneous chondrule under high-temperature, reducing conditions. In this environment the molten alloys incorporated varied amounts of Si, Ni, P, Cr, and Co, depending on the oxygen fugacity and temperature of the melt. Some of the metal was subsequently expelled from the chondrule interiors into the surrounding nebular gas. As the temperature dropped, the alloy solidified and volatile elements corroded the metal. The main reaction products were troilite and fayalite. Thermodynamic equilibrium calculations are used to constrain the conditions under which these two phases can form simultaneously in the solar nebula. Kinetic factors are used to place a lower limit on the formation temperature. We determine that the metal corroded between 1173 and 1261 K at a total pressure in the range of 10−5.0 to 10−4.1 bars and a dust/gas ratio of 302 to 355 x relative to solar composition. These conditions are consistent with our model that the metal corroded in a dust-rich region of the solar nebula that was cooling after a chondrule formation event.

Beyond the Iron Peak: r- and s-process Elemental Abundances in Stars with Planets

We present elemental abundances of 118 stars (28 of which are known extrasolar planetary host stars) observed as part of the Anglo-Australian Planet Search. Abundances of O, Mg, Cr, Y, Zr, Ba, Nd, and Eu (along with previously published abundances for C and Si) are presented. This study is one of the first to specifically examine planetary host stars for the heavy elements produced by neutron capture reactions. We find that the abundances in host stars are chemically different from both the standard solar abundances and the abundances in non-host stars in all elements studied, with enrichments over non-host stars ranging from 0.06 dex (for O) to 0.11 dex (for Cr and Y). Such abundance trends are in agreement with other previous studies of field stars and lead us to conclude that the chemical anomalies observed in planetary host stars are the result of normal galactic chemical evolution processes. Based on this observation, we conclude that the observed chemical traits of planetary host stars are primordial in origin, coming from the original nebula and not from a pollution process occurring during or after formation, and that planet formation occurs naturally with the evolution of stellar material.