David C. Lampe

Comparative Study of Transport Processes of Nitrogen, Phosphorus, and Herbicides to Streams in Five Agricultural Basins, USA

Agricultural chemical transport to surface water and the linkage to other hydrological compartments, principally ground water, was investigated at five watersheds in semiarid to humid climatic settings. Chemical transport was affected by storm water runoff, soil drainage, irrigation, and how streams were linked to shallow ground water systems. Irrigation practices and timing of chemical use greatly affected nutrient and pesticide transport in the semiarid basins. Irrigation with imported water tended to increase ground water and chemical transport, whereas the use of locally pumped irrigation water may eliminate connections between streams and ground water, resulting in lower annual loads. Drainage pathways in humid environments are important because the loads may be transported in tile drains, or through varying combinations of ground water discharge, and overland flow. In most cases, overland flow contributed the greatest loads, but a significant portion of the annual load of nitrate and some pesticide degradates can be transported under base-flow conditions. The highest basin yields for nitrate were measured in a semiarid irrigated system that used imported water and in a stream dominated by tile drainage in a humid environment. Pesticide loads, as a percent of actual use (LAPU), showed the effects of climate and geohydrologic conditions. The LAPU values in the semiarid study basin in Washington were generally low because most of the load was transported in ground water discharge to the stream. When herbicides are applied during the rainy season in a semiarid setting, such as simazine in the California basin, LAPU values are similar to those in the Midwest basins.

Simulated Fate and Transport of Metolachlor in the Unsaturated Zone, Maryland, USA

An unsaturated-zone transport model was used to examine the transport and fate of metolachlor applied to an agricultural site in Maryland, USA. The study site was instrumented to collect data on soil-water content, soil-water potential, ground water levels, major ions, pesticides, and nutrients from the unsaturated zone during 2002-2004. The data set was enhanced with site-specific information describing weather, soils, and agricultural practices. The Root Zone Water Quality Model was used to simulate physical, chemical, and biological processes occurring in the unsaturated zone. Model calibration to bromide tracer concentrations indicated flow occurred through the soil matrix. Simulated recharge rates were within the measured range of values. The pesticide transport model was calibrated to the intensive data collection period (2002-2004), and the calibrated model was then used to simulate the period 1984 through 2004 to examine the impact of sustained agricultural management practices on the concentrations of metolachlor and its degradates at the study site. Simulation results indicated that metolachlor degrades rapidly in the root zone but that the degradates are transported to depth in measurable quantities. Simulations indicated that degradate transport is strongly related to the duration of sustained use of metolachlor and the extent of biodegradation.

Hydrologic data and groundwater-flow simulations in the Brown Ditch Watershed, Indiana Dunes National Lakeshore, near Beverly Shores and Town of Pines, Indiana

The U.S. Geological Survey (USGS) collected data and simulated groundwater flow to increase understanding of the hydrology and the effects of drainage alterations on the water table in the vicinity of Great Marsh, near Beverly Shores and Town of Pines, Indiana. Prior land-management practices have modified drainage and caused changes in the distribution of open water, streams and ditches, and groundwater abundance and flow paths. Collected hydrologic data indicate that the majority of water entering Great Marsh flows from the southern dune ridge beneath Town of Pines, Indiana. Groundwater flow is intercepted by Brown Ditch in the eastern portion of the study area and Derby Ditch in the western portion of the study area. A smaller amount of groundwater from the northern dune ridge beneath Beverly Shores also contributed water to Great Marsh. Continuous groundwater-level data collected indicate that the predominant north-south groundwater-flow gradients vary during the course of the year due to increased levels of precipitation or during periods of drainage obstructions. Continuous surface-water discharge and surface-water elevation were measured at three USGS streamgages, one each on Brown, Kintzele and Derby Ditches. The monthly mean discharge statistics indicate that during the period of record— June 2012 to September 2013—streamflow in Kintzele Ditch was lowest during July 2012 and highest during April 2013. In Derby Ditch, streamflow also was lowest during July 2012 and highest during April 2013. Periods of relatively high and low groundwater levels during August 1982, March 2013, and April 2014 were examined and simulated by using MODFLOW and companion software. Results from the simulation of conditions during March 2013 include that nearly 100 percent of all water entering the area simulating Town of Pines is from recharge. Of all the water simulated to enter the eastern and western portions of Great Marsh, nearly 20 and 18 percent, respectively, flows from Town of Pines to the western and eastern portions of Great Marsh. The dune ridges beneath Town of Pines and to a lesser extent beneath Beverly Shores are a major source of recharge to the surficial aquifer and Great Marsh. Results from the simulation of the conditions of April 2014 include that, despite increases in the amount of water entering Great Marsh due to a beaver-dam-modified hydrologic condition, there is still virtually zero simulated groundwater flow from Great Marsh to Town of Pines. The volume of water simulated to be entering the zone representing Beverly Shores decreased by 0.43 cubic foot per second from the results of the March 2013 simulation. This simulated difference in water budgets can be attributed to increased simulated recharge in Great Marsh and Town of Pines. Effects of the inclusion of the beaver dam included the increase of the simulated water table and simulated inundated area upstream of the beaver dam due to the effects of ponding surface water. Results from the simulation scenario that includes six proposed pool-riffle control structures in Brown Ditch under the hydrologic conditions of March 2013 indicate areas inundated by water are larger, including areas just to the north of the entrance of Brown Ditch into Great Marsh, and areas north of the confluence of Brown and Kintzele Ditches. Results from the scenario simulating the increase of the Lake Michigan water level to the historical high of May 31, 1998, showed inundated areas of Great Marsh south of Beverly Shores enlarged on both sides of Lakeshore County Road with the greatest enlargement simulated to be southeast of the intersection of Lakeshore County Road and Beverly Drive. For the scenario simulating the decrease of the Lake Michigan water level to the historical low of December 23, 2007, results show little change from the original March 2013 inundated area. The results of this study can be used by water-resource managers to understand how surrounding ditches affect water levels in Great Marsh and other inland wetlands and residential areas. The groundwater model developed can be applied to answer questions about how alterations to the drainage system in the area affects water levels in the public and residential areas surrounding Great Marsh. The modeling methods developed in this study provide a template for other studies of groundwater flow and groundwater/surface-water interactions within the shallow surficial aquifer in northern Indiana, and in similar hydrologic settings that include surficial sand aquifers in coastal areas. 2 Hydrologic Data and Groundwater-Flow Simulations in the Brown Ditch Watershed, Indiana Dunes National Lakeshore