David De Vleeschouwer

Cyclostratigraphic calibration of the Frasnian (Late Devonian) time scale (western Alberta, Canada)

Until now, the duration of the Frasnian Stage has remained very poorly constrained, hampering a detailed understanding of sedimentation processes and environmental and evolutionary change. In this study, timeseries analyses of high-resolution (10–20 k.y.) magnetic susceptibility data identify sixteen 405 k.y. eccentricity cycles in the magnetic susceptibility stratigraphy of the Frasnian (Late Devonian), derived from carbonate-platform and surrounding slope and basin deposits in western Alberta, Canada. Previous studies demonstrated the generally consistent pattern of magnetic susceptibility change across the Alberta basin and thus demonstrated the utility of magnetic susceptibility stratigraphy as a refi ned regional correlation tool compared to biostratigraphy. In the present study, we show that the magnetic susceptibility stratigraphy of the Frasnian interval in western Alberta has been signifi cantly infl uenced by astro nomical forcing. Using the sixteen 405 k.y. eccentricity cycles as a geochronometer, we constructed a Frasnian astronomical time scale. This time scale indicates a duration of 6.5 ± 0.4 m.y. for the Frasnian. Calibrating this duration to the best available Devonian chronology, the absolute age of the Givetian-Frasnian boundary is recalculated to 383.6 ± 3.0 Ma, and the age of the Frasnian-Famennian boundary is recalculated to 376.7 ± 3.0 Ma. These new absolute ages take into account the astronomically derived duration of the Frasnian, but they also yield a narrowing of the error margins of the absolute ages by several hundreds of thousands of years.

Reducing time-scale uncertainty for the Devonian by integrating astrochronology and Bayesian statistics

Dealing with uncertainties is inherent to the scientific process. In the process of building geologic time scales, the reported uncertainties are at least as important as the estimates of the numerical ages. Currently all time scales for the Devonian are based on conventional age-depth models, constructed by linear or cubic interpolation between different dated positions. Unfortunately, such models tend to produce overoptimistic confidence intervals. In this study we apply Bayesian statistics to the Devonian time scale to better incorporate stratigraphic and radioisotopic uncertainty. This approach yields a Devonian time scale characterized by increasing uncertainty with growing stratigraphic distance from a radioisotopically dated sample. This feature is absent from The Geologic Time Scale 2012 ; therefore, that time scale is overoptimistic. We further constrain the obtained time scale by incorporating astrochronological duration estimates for the Givetian and Frasnian stages. The combination of radioisotopic dating and astrochronology results in a reduction of the uncertainty on the numerical age of the stage boundaries concerned by several million years. For example, we estimate the age of the Frasnian- Famennian boundary at 373.9 ± 1.4 Ma.

Alternating Southern and Northern Hemisphere climate response to astronomical forcing during the past 35 m.y.

Earth’s climate has undergone different intervals of gradual change as well as abrupt shifts between climate states. Here we aim to characterize the corresponding changes in climate response to astronomical forcing in the icehouse portion of the Cenozoic, from the latest Eocene to the present. As a tool, we use a 35-m.y.-long δ 18 O benthic record compiled from different high-resolution benthic isotope records spliced together (what we refer to as a megasplice). We analyze the climate response to astronomical forcing during four 800-k.y.-long time windows. During the mid-Miocene Climatic Optimum (ca. 15.5 Ma), global climate variability was mainly dependent on Southern Hemisphere summer insolation, amplified by a dynamic Antarctic ice sheet; 2.5 m.y. later, relatively warm global climate states occurred during maxima in both Southern Hemisphere and Northern Hemisphere summer insolation. At that point, the Antarctic ice sheet grew too big to pulse on the beat of precession, and the Southern Hemisphere lost its overwhelming influence on the global climate state. Likewise, we juxtapose response regimes of the Miocene (ca. 19 Ma) and Oligocene (ca. 25.5 Ma) warming periods. Despite the similarity in δ 18 O benthic values and variability, we find different responses to precession forcing. While Miocene warmth occurs during summer insolation maxima in both hemispheres, Oligocene global warmth is consistently triggered when Earth reaches perihelion in the Northern Hemisphere summer. This pattern is in accordance with previously published paleoclimate modeling results, and suggests an amplifying role for Northern Hemisphere sea ice.

Quantifying K, U, and Th contents of marine sediments using shipboard natural gamma radiation spectra measured on DV JOIDES Resolution

During International Ocean Discovery Program (IODP) expeditions, shipboard-generated data provide the first insights into the cored sequences. The natural gamma radiation (NGR) of the recovered material, for example, is routinely measured on the ocean drilling research vessel DV JOIDES Resolution. At present, only total NGR counts are readily available as shipboard data, although full NGR spectra (counts as a function of gamma-ray energy level) are produced and archived. These spectra contain unexploited information, as one can estimate the sedimentary contents of potassium (K), thorium (Th), and uranium (U) from the characteristic gamma-ray energies of isotopes in the ^(40)K, ^(232)Th, and ^(238)U radioactive decay series. Dunlea et al. [2013] quantified K, Th and U contents in sediment from the South Pacific Gyre by integrating counts over specific energy levels of the NGR spectrum. However, the algorithm used in their study is unavailable to the wider scientific community due to commercial proprietary reasons. Here, we present a new MATLAB algorithm for the quantification of NGR spectra that is transparent and accessible to future NGR users. We demonstrate the algorithms performance by comparing its results to shore-based inductively coupled plasma-mass spectrometry (ICP-MS), inductively coupled plasma-emission spectrometry (ICP-ES), and quantitative wavelength-dispersive X-ray fluorescence (XRF) analyses. Samples for these comparisons come from eleven sites (U1341, U1343, U1366-U1369, U1414, U1428-U1430, U1463) cored in two oceans during five expeditions. In short, our algorithm rapidly produces detailed high-quality information on sediment properties during IODP expeditions at no extra cost.

The astronomical calibration of the Givetian (Middle Devonian) timescale (Dinant Synclinorium, Belgium)

Abstract Recent advances in radiometric dating result in significant improvements in the geological timescale and provide better insight into the timing of various processes and evolutions within the Earths system. However, no radiometric ages are contained within the Givetian. Consequently, the absolute ages of the Givetian Stage boundaries, as well as the stages duration, remain poorly constrained. As an alternative, the analysis of sedimentary cycles allows for the estimation of the duration of this stage. We examined the high-resolution magnetic susceptibility signals of four Givetian outcrops in the Givet area for a possible astronomical imprint, to fully understand the rates of evolutionary and environmental change. All four sections are firmly correlated and wavelet analyses of the magnetic susceptibility signals reveal the imprint of astronomical eccentricity forcing. The highly stable 405 kyr cycles constrain the duration of the Givetian Stage at 4.35±0.45 Myr, which is in good agreement with the International Chronostratigraphic Chart (5.0 Myr). The studied sections also exhibit an imprint of obliquity, suggesting a climatic teleconnection between low and high latitudes. The corresponding microfacies curves demonstrate similar astronomical imprint, and thereby indicate that the observed 105 year-scale cyclicity is the result of climatic and environmental change.

Indonesian Throughflow drove Australian climate from humid Pliocene to arid Pleistocene

Late Miocene to mid-Pleistocene sedimentary proxy records reveal that northwest Australia underwent an abrupt transition from dry to humid climate conditions at 5.5 million years (Ma), likely receiving year-round rainfall, but after ~3.3 Ma, climate shifted toward an increasingly seasonal precipitation regime. The progressive constriction of the Indonesian Throughflow likely decreased continental humidity and transferred control of northwest Australian climate from the Pacific to the Indian Ocean, leading to drier conditions punctuated by monsoonal precipitation. The northwest dust pathway and fully established seasonal and orbitally controlled precipitation were in place by ~2.4 Ma, well after the intensification of Northern Hemisphere glaciation. The transition from humid to arid conditions was driven by changes in Pacific and Indian Ocean circulation and regional atmospheric moisture transport, influenced by the emerging Maritime Continent. We conclude that the Maritime Continent is the switchboard modulating teleconnections between tropical and high-latitude climate systems.

Australian shelf sediments reveal shifts in Miocene Southern Hemisphere westerlies

Sediments from Western Australia show how westerly winds made the southwest wetter during the Miocene (18 to 6 million years ago). Global climate underwent a major reorganization when the Antarctic ice sheet expanded ~14 million years ago (Ma) (1). This event affected global atmospheric circulation, including the strength and position of the westerlies and the Intertropical Convergence Zone (ITCZ), and, therefore, precipitation patterns (2–5). We present new shallow-marine sediment records from the continental shelf of Australia (International Ocean Discovery Program Sites U1459 and U1464) providing the first empirical evidence linking high-latitude cooling around Antarctica to climate change in the (sub)tropics during the Miocene. We show that Western Australia was arid during most of the Middle Miocene. Southwest Australia became wetter during the Late Miocene, creating a climate gradient with the arid interior, whereas northwest Australia remained arid throughout. Precipitation and river runoff in southwest Australia gradually increased from 12 to 8 Ma, which we relate to a northward migration or intensification of the westerlies possibly due to increased sea ice in the Southern Ocean (5). Abrupt aridification indicates that the westerlies shifted back to a position south of Australia after 8 Ma. Our midlatitude Southern Hemisphere data are consistent with the inference that expansion of sea ice around Antarctica resulted in a northward movement of the westerlies. In turn, this may have pushed tropical atmospheric circulation and the ITCZ northward, shifting the main precipitation belt over large parts of Southeast Asia (4).

Insight into the development of a carbonate platform through a multi-disciplinary approach: a case study from the Upper Devonian slope deposits of Mount Freikofel (Carnic Alps, Austria/Italy)

The development and behavior of million year-scaled depositional sequences recorded within Palaeozoic carbonate platform has remained poorly examined. Therefore, the understanding of palaeoenvironmental changes that occur in geological past is still limited. We herein undertake a multi-disciplinary approach (sedimentology, conodont biostratigraphy, magnetic susceptibility (MS), and geochemistry) of a long-term succession in the Carnic Alps, which offers new insights into the peculiar evolution of one of the best example of Palaeozoic carbonate platform in Europe. The Freikofel section, located in the central part of the Carnic Alps, represents an outstanding succession in a fore-reef setting, extending from the Latest Givetian (indet. falsiovalis conodont zones) to the Early Famennian (Lower crepida conodont zone). Sedimentological analysis allowed to propose a sedimentary model dominated by distal slope and fore-reef-slope deposits. The most distal setting is characterized by an autochthonous pelagic sedimentation showing local occurrence of thin-bedded turbiditic deposits. In the fore-reef slope, in a more proximal setting, there is an accumulation of various autochthonous and allochthonous fine- to coarse-grained sediments originated from the interplay of gravity-flow currents derived from the shallow-water and deepwater area. The temporal evolution of microfacies in the Freikofel section evolves in two main steps corresponding to the Freikofel (Unit 1) and the Pal (Unit 2) limestones. Distal slope to fore-reef lithologies and associate changes are from base to top of the section: (U1) thick bedded litho- and bioclastic breccia beds with local fining upward sequence and fine-grained mudstone intercalations corresponding, in the fore-reef setting, to the dismantlement of the Eifelian–Frasnian carbonate platform during the Early to Late Frasnian time (falsiovalis to rhenana superzones) with one of the causes being the Late Givetian major rift pulse; (U2) occurrence of thin-bedded red nodular and cephalopod-bearing limestones with local lithoclastic grainstone intercalations corresponding to a significant deepening of the area and the progressive withdrawal of sedimentary influxes toward the basin, in relation with Late Frasnian sea-level rise. MS and geochemical analyses were also performed along the Freikofel section and demonstrate the inherent parallel link existing between variation in MS values and proxy for terrestrial input. Interpretation of MS in terms of palaeoenvironmental processes reflects that even though distality remains the major parameter influencing MS values, carbonate production and water agitation also play an important role.

Timing and pacing of the Late Devonian mass extinction event regulated by eccentricity and obliquity

The Late Devonian envelops one of Earth’s big five mass extinction events at the Frasnian–Famennian boundary (374 Ma). Environmental change across the extinction severely affected Devonian reef-builders, besides many other forms of marine life. Yet, cause-and-effect chains leading to the extinction remain poorly constrained as Late Devonian stratigraphy is poorly resolved, compared to younger cataclysmic intervals. In this study we present a global orbitally calibrated chronology across this momentous interval, applying cyclostratigraphic techniques. Our timescale stipulates that 600 kyr separate the lower and upper Kellwasser positive δ13C excursions. The latter excursion is paced by obliquity and is therein similar to Mesozoic intervals of environmental upheaval, like the Cretaceous Ocean-Anoxic-Event-2 (OAE-2). This obliquity signature implies coincidence with a minimum of the 2.4 Myr eccentricity cycle, during which obliquity prevails over precession, and highlights the decisive role of astronomically forced “Milankovitch” climate change in timing and pacing the Late Devonian mass extinction.Understanding of Late Devonian mass extinction mechanisms is poor due to imprecise stratigraphies. Here, using cyclostratigraphic techniques, the authors present a global orbitally-calibrated chronology and reveal the key role of astronomically-forced Milankovitch climate change.

Stratigraphic record of the asteroidal Veritas breakup in the Tortonian Monte dei Corvi section (Ancona, Italy)

The discovery of elevated concentrations of the cosmogenic radionuclide ^3He in deep-sea sediments from Ocean Drilling Program (ODP) Site 926 (Atlantic Ocean) and ODP Site 757 (Indian Ocean) points toward accretion of extraterrestrial matter, probably as a result of the catastrophic disruption of a large asteroid that produced the Veritas family of asteroids at ca. 8.3 ± 0.5 Ma, and which may have had important effects on the global climatic and ecologic systems. Here, we investigated the signatures possibly related to the Veritas event by performing a high-resolution multiproxy stratigraphic analysis through the late Tortonian−early Messinian Monte dei Corvi section near Ancona, Italy. Closely spaced bulk-rock samples through a 36-m-thick section, approximately spanning from ca. 9.9 Ma to ca. 6.4 Ma, show an ∼5-fold ^3He anomaly starting at ca. 8.5 Ma and returning to background values at ca. 6.9 Ma, confirming the global nature of the event. We then analyzed, at 5 cm intervals, bulk-rock samples for sedimentary and environmental proxies such as magnetic susceptibility, calcium carbonate content, total organic carbon, and bulk carbonate δ^(18)O and δ^(13)C, through a 21-m-thick section encompassing the ^3He anomaly. Available high-resolution sea-surface temperature data (via alkenone analyses) for this site show a temperature decrease starting exactly at the inception of the ^3He anomaly. Cyclostratigraphic fast-Fourier-transform spectral analyses of the proxies indicate an age of 8.47 ± 0.05 Ma for the inception of the ^3He anomaly. A search for impact ejecta (analogous to what is present in the late Eocene, where both a ^3He anomaly and large-scale impact events are recorded) was not successful. Detailed cyclostratigraphic analyses of our data suggest that the changes in the stable isotope series and environmental proxy series through this late Tortonian time interval had a common forcing agent, and that perturbations of orbitally forced climate cycles are present exactly through the interval with the enhanced influx of extraterrestrial ^3He. Thus, the chemostratigraphic evidence for a collisional event that created the Veritas family of asteroids, coinciding with climate perturbations on Earth, suggests yet another form of interaction between Earth and the solar system.