David G. Wareham

Sludge digestion using ORP-regulated aerobic-anoxic cycles

Abstract This work documents the results from two lab-scale reactors digesting waste sludge in an aerobic-anoxic fashion. The control reactor “fixed” the length of the aerobic-anoxic cycle at 6 h, with each segment of the cycle set at 3 h each. The experimental reactor used ORP to control the total length of the cycle based upon the distinctive “nitrate breakpoint” occurring in the ORP-time profile. The reactors were evaluated on the basis of removals for TSS, VSS, nitrogen and phosphorus. In addition, the control stability achieved when the reactors were subjected to spikes of specific chemicals was monitored. The ORP-regulated reactor better accommodated the disturbances, as well as appeared to show an increase in the removal of nitrogen and solids.

Effects of hydraulic and solids retention times on productivity and settleability of microbial (microalgal-bacterial) biomass grown on primary treated wastewater as a biofuel feedstock.

High biomass productivity and efficient harvesting are currently recognized challenges in microbial biofuel applications. To produce naturally settleable biomass, combined growth of native microalgae and bacteria was facilitated in laboratory sequencing batch reactors (SBRs) using primary treated wastewater from the Christchurch Wastewater Treatment Plant (CWTP) in New Zealand. SBRs were operated under a simulated, local, summer climate (i.e., 925 μmol/m(2)/s of photosynthetically active radiation for 14.7 h per day at 21 °C mean water temperature) using 1.4- to 8-day hydraulic retention times (HRTs) to optimize growth. Solids retention times (SRTs) were varied from 4 to 40 days by discharging different ratios of supernatant and completely mixed culture. Biomass productivity up to 31 g/m(2)/day of solids was obtained, and it generally increased as retention times decreased. Biomass settleability was typically 70-95%, and the microbes aggregated into compact flocs as cultures aged up to four months. Due to a low lipid content of 10.5%, anaerobic digestion appeared to be the most appropriate biofuel conversion process with potential to generate 19,200 m(3)/ha/yr of methane based on settleable mixture productivity.

Effect of mixture ratio, solids concentration and hydraulic retention time on the anaerobic digestion of the organic fraction of municipal solid waste.

This paper describes how the degradation of the organic fraction of municipal solid waste (OFMSW) is affected through codigestion with varying amounts of return activated sludge (RAS). Solid waste that had its inorganic fraction selectively removed was mixed with RAS in ratios of 100% OFMSW, 50% OFMSW/50% RAS, and 25% OFMSW/75% RAS. The total solids (TS) concentration was held at 8% and three anaerobic digester systems treating the mixtures were held (for the first run) at a total hydraulic retention time (HRT) of 28 days. Increasing amounts of RAS did not however improve the mixture’s digestability, as indicated by little change and/or a drop in the main performance indices [including percentage volatile solids (VS) removal and specific gas production]. The optimum ratio in this research therefore appeared to be 100% OFMSW with an associated 85.1 ± 0.6% VS removal and 0.72 ± 0.01 L total gas g- 1 VS. In the second run, the effect of increasing percentage of TS (8, 12% and 15%) at a system HRT of 28 days was observed to yield no improvement in the main performance indices (i.e. percentage VS removal and specific gas production). Finally, during the third run, variations in the total system HRT were investigated at an 8% TS, again using 100% OFMSW. Of the HRTs explored (23, 28 and 33 days), the longest HRT yielded the best performance overall, particularly in terms of specific gas production (0.77 ± 0.01 L total gas g-1 VS).

Introducing ethics using structured controversies

This paper describes a method of introducing ethics to a second-year class of civil engineering students. The method, known as a ‘structured controversy’, takes the form of a workshop where the students assume the identity of stakeholders having an interest in a proposed development in an environmentally sensitive region. The instructor enhances the workshop by deliberately feeding incorrect information into a catalogue of facts that each stakeholder has at their disposal. After the workshop, the instructor draws out three ethical frameworks from which the stakeholders operate. A key component of the exercise is that the students do not know beforehand that the environmental workshop is being used to introduce ethics. When the connection is revealed, the students appreciate that much of their behaviour during the role-play was because they inadvertently adhered to an unknown ethical platform. Since it is an environmental simulation, an explicit connection can be made to the debate over ‘who’ to include in the moral community. In addition, a link can be drawn to the notion of sustainable development which, in this paper, is advocated as an ethical rather than a technical concept.

Two-phase anaerobic digestion of the organic fraction of municipal solid waste: estimation of methane production

Energy generation from methane (CH4) is one of the primary targets of the anaerobic digestion process. Consequently, the focus of this study was to investigate the effect on CH4 production of total solids (TS) loading (measured as % TS) and hydraulic residence time (HRT) during the treatment of the organic fraction of municipal solid waste (OFMSW). Laboratory-scale, two-phase anaerobic digestion systems were employed with each system consisting of an acidogenic reactor and a methanogenic reactor linked in series. The group A runs in the experiment explored the effect on digester performance of four variations in methanogenic HRT (15, 20, 25 and 30 days) at three different feed TS concentrations (8, 12 and 15%). The group B runs compared the actual methane yield (0.14 to 0.45 L g VS feed − 1 ) to that predicted by the Chen–Hashimoto model. Results from the group A runs indicated that acidogenesis improved with an increase in % TS and a decrease in HRT; while, methanogenesis behaved inversely, achieving higher yields at the lower % TS and longer HRT values. In comparison with the group B runs, the Chen–Hashimoto model under-predicted (by an average of 16.5 ± 6.6%) the CH4 yield obtained from the digestion of OFMSW.

TREATMENT OF FOUR INDUSTRIAL WASTEWATERS BY SEQUENCING BATCH REACTORS : EVALUATION OF COD, TKN AND TP REMOVAL

Abstract This study investigated the ability of a sequencing batch reactor (SBR) system to treat four industrial wastewaters, namely, textile, landfill leachate, seafood and slaughterhouse effluents. The system employed three identical SBRs (10 l volume each) operating in parallel and each waste was treated one at a time. The operational variables examined included the length of the non‐aerated period and the solids retention time (SRT). All four wastewaters experienced chemical oxyfen demand (COD) and total kjeldhal nitrogen (TKN) removals greater than 81%, while the TP removals were lower, ranging from 57 to 94%. The length of the non‐aerated period appeared to have minimal effect on the SBR performance; however, increases in SRT reduced the percent TP removal for the textile and leachate wastes only. In addition, to investigate organic loading limits to the seafood SBR system, the COD was increased by three increments of 250 mg l−1 starting from a baseline concentration of 1100 mg l−1. This resulted in a reduction in both the TKN and TP removal at the higher concentrations. Finally, for the slaughterhouse wastewater, the COD:TKN ratio was tested at levels of 6:1, 8:1 and 9:1 with the result that only the TP removal was affected at the lowest ratio.

Effect of shortened anaerobic HRT on phosphate release and uptake in the UCT Bio-P process

This work examines the effect of operating a biological phosphorus removal (Bio-P) system at a reduced anaerobic hydraulic retention time (HRT). The research specifically focuses on the impact a reduced HRT has on the phosphate release and uptake patterns which characterize Bio-P processes. Within the anaerobic conditions of this study, leakage of volatile fatty acids from the anaerobic to anoxic zones affected phosphate removal and effluent phosphate concentrations.

Removal of arsenic from water using the adsorbent: New Zealand iron-sand.

Adsorption is a technology used to remove arsenic from water contaminated at levels above drinking water standards. In this study, New Zealand Iron-Sand (NZIS), a naturally-available adsorbent was investigated for its efficiency in removing both As (III) and As (V). Several batch tests were conducted with different concentrations of arsenic at different pH conditions. During the batch tests, the maximum adsorption of As (III) occurred at a pH of 7.5, while As (V) adsorption reached its maximum value at a pH of 3. Both Langmuir and Freundlich adsorption models were found to fit with R2 values greater than 0.92. From the Langmuir adsorption model, the maximum adsorption capacity of NZIS for As (III) and As (V) were estimated to be 1,250 and 500 μg/g, respectively. These values were substantial enough to consider NZIS a promising new adsorbent for arsenic removal.

Treatment of a slaughterhouse wastewater: effect of internal recycle rate on chemical oxygen demand, total Kjeldahl nitrogen and total phosphorus removal

This study investigated the ability of an anaerobic/anoxic/oxic (A2/O) system to treat a slaughterhouse wastewater. The system employed two identical continuous-flow reactors (10 l total liquid volume each) running in parallel with the main operational variable, being the internal recycle (IR) rate. The chemical oxygen demand (COD), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) performance was evaluated as the IR flowrate was increased from a Q of 15 l d−1 to 4Q at a system hydraulic retention time of 16 h and a solids retention time of 10 d. The COD:TKN and COD:TP ratios were 8.2:1 and 54:1, which supported both nitrogen and phosphorus removal. For all IR multiples of Q, the COD removal was in excess of 90%. The TKN removal showed a modest improvement (a 4–5% increase, depending on the dissolved oxygen (DO)) as the IR doubled from Q to 2Q, but no further increase was observed at the 4Q IR rate. The TP removal reached its optimum (around 85%–89% (again depending on the DO)) at the 2Q rate.

The influence of organic loading and anoxic/oxic times on the removal of carbon, nitrogen and phosphorus from a wastewater treated in a sequencing batch reactor

In this study, 10 L sequencing batch reactors (SBRs) were operated at a 12-h cycle length (four alternating anoxic/oxic conditions) to assess the biological nutrient removal potential of a domestic wastewater treated at the Huay Kwang plant, Bangkok, Thailand. The wastewater was found to be carbon-limited (chemical oxygen demand (COD) to total Kjeldahl nitrogen (TKN) (i.e., COD:TKN) ratio of 6.4:1). This ratio was insufficient to support good phosphorus removal. Glucose was therefore added to increase the COD:TKN ratio ultimately to 10:1 and the COD, TKN and total phosphorus (TP) removals at this ratio were all in excess of 95%. An alternative carbon source from a local fruit canning industry was then added at the same COD:TKN ratio; and, in order to increase the throughput of the waste treated, the cycle length was simultaneously shortened to 8 h keeping approximately the same anoxic/oxic fractions. The COD removal remained high (> 95%), however the TKN and TP removals were substantially reduced (79% and 66%, respectively), indicating that the shortened cycle length was sub-optimum. The last phase of the research involved changing the anoxic/oxic fractions of the cycle time to maximize performance. It was found that for the conditions studied in this research, the performance improved in proportion to the increase in the first anoxic fraction, being most stable at the highest anoxic fraction of the cycle length (0.33).