David Jassby

Impact of Aggregate Size and Structure on the Photocatalytic Properties of TiO2 and ZnO Nanoparticles

Aggregation of photocatalytic semiconductors was determined to reduce the generation of free hydroxyl radicals in aqueous suspensions in a fashion dependent on aggregate size and structure. Static light scattering measurements were used to follow temporal changes in the fractal dimension of aggregating TiO(2) and ZnO nanoparticles. At length scales comparable to nanoparticle size, the structure of aggregated TiO(2) nanoparticles was independent of particle stability and the associated aggregation rate, consistent with the fused nature of TiO(2) primary particles in the initial suspension. In contrast, ZnO aggregates were characterized by smaller fractal dimensions when ionic strength, and the resulting aggregation rate, were increased. The photocatalytic activity of ZnO and TiO(2) in generating free hydroxyl radicals varied with aggregate structure and size, consistent with theory that predicts reduced reactivity as aggregates become larger and more dense.

Coupling Underwater Superoleophobic Membranes with Magnetic Pickering Emulsions for Fouling-Free Separation of Crude Oil/Water Mixtures: An Experimental and Theoretical Study

Oil/water separations have become an area of great interest, as growing oil extraction activities are increasing the generation of oily wastewaters as well as increasing the risk of oil spills. Here, we demonstrate a membrane-based and fouling-free oil/water separation method that couples carbon nanotube-poly(vinyl alcohol) underwater superoleophobic ultrafiltration membranes with magnetic Pickering emulsions. We demonstrate that this process is insensitive to low water temperatures, high ionic strength, or crude oil loading, while allowing operation at high permeate fluxes and producing high quality permeate. Furthermore, we develop a theoretical framework that analyzes the stability of Pickering emulsions under filtration mechanics, relating membrane surface properties and hydrodynamic conditions in the Pickering emulsion cake layer to membrane performance. Finally, we demonstrate the recovery and recyclability of the nanomagnetite used to form the Pickering emulsions through a magnetic separation step, resulting in an environmentally friendly, continuous process for oil/water separation.

Frequency-dependent stability of CNT Joule heaters in ionizable media and desalination processes

Water shortages and brine waste management are increasing challenges for coastal and inland regions, with high-salinity brines presenting a particularly challenging problem. These high-salinity waters require the use of thermally driven treatment processes, such as membrane distillation, which suffer from high complexity and cost. Here, we demonstrate how controlling the frequency of an applied alternating current at high potentials (20 Vpp) to a porous thin-film carbon nanotube (CNT)/polymer composite Joule heating element can prevent CNT degradation in ionizable environments such as high-salinity brines. By operating at sufficiently high frequencies, these porous thin-films can be directly immersed in highly ionizable environments and used as flow-through heating elements. We demonstrate that porous CNT/polymer composites can be used as self-heating membranes to directly heat high-salinity brines at the water/vapour interface of the membrane distillation element, achieving high single-pass recoveries that approach 100%, far exceeding standard membrane distillation recovery limits.

Microbial Attachment Inhibition through Low-Voltage Electrochemical Reactions on Electrically Conducting Membranes

Bacterial biofilm formation on membrane surfaces remains a serious challenge in water treatment systems. The impact of low voltages on microbial attachment to electrically conducting ultrafiltration membranes was investigated using a direct observation cross-flow membrane system mounted on a fluorescence microscope. Escherichia coli and microparticle deposition and detachment rates were measured as a function of the applied electrical potential to the membrane surface. Selecting bacteria and particles with low surface charge minimized electrostatic interactions between the bacteria and charged membrane surface. Application of an electrical potential had a significant impact on the detachment of live bacteria in comparison to dead bacteria and particles. Image analysis indicated that when a potential of 1.5 V was applied to the membrane/counter electrode pair, the percent of dead bacteria was 32±2.1 and 67±3.6% when the membrane was used as a cathode or anode, respectively, while at a potential of 1 V, 92±2.4% were alive. The application of low electrical potentials resulted in the production of low (μM) concentrations of hydrogen peroxide (HP) through the electroreduction of oxygen. The electrochemically produced HP reduced microbial cell viability and increased cellular permeability. Exposure to low concentrations of electrochemically produced HP on the membrane surface prevents bacterial attachment, thus ensuring biofilm-free conditions during membrane filtration operations.

Membrane filtration of fullerene nanoparticle suspensions: effects of derivatization, pressure, electrolyte species and concentration.

Particle aggregation is induced in derivatized fullerene (fullerol) suspensions by introducing different counter-ion species (Na(+) Ca(2+) and Mg(2+)) and concentrations. The suspensions are filtered through 20 nm ceramic membranes under different transmembrane pressures, and the removal efficiency is compared. In all cases, the average hydrodynamic radius far exceeded the average pore diameter of the membrane. In the case of mono-valent counter-ions, removal efficiency is influenced by transmembrane pressure, with higher removal efficiencies achieved at lower pressures. In contrast, removal efficiencies of fullerol suspensions destabilized with di-valent ions are insensitive to transmembrane pressure, similar to what was found in the case of non-derivatized fullerene. Scanning Electron Microscope (SEM) images of post-filtration membranes indicate that fullerol aggregates destabilized with Mg(2+) ions deform and partially penetrate the membrane, but are ultimately trapped. The proposed mechanism suggests that di-valent ions act as bridges between fullerol aggregates, forming strong bonds that were not broken under the experimental conditions. These strong bonds may allow aggregated fullerol particles to deform under high pressure, and partially penetrate the membrane. Mono-valent ions are incapable of functioning as bridges, and subsequently, when sufficient pressure is applied, fullerol aggregates will break apart and pass through the membrane.

Polyaniline-Coated Carbon Nanotube Ultrafiltration Membranes: Enhanced Anodic Stability for In Situ Cleaning and Electro-Oxidation Processes

Electrically conducting membranes (ECMs) have been reported to be efficient in fouling prevention and destruction of aqueous chemical compounds. In the current study, highly conductive and anodically stable composite polyaniline-carbon nanotube (PANI-CNT) ultrafiltration (UF) ECMs were fabricated through a process of electropolymerization of aniline on a CNT substrate under acidic conditions. The resulting PANI-CNT UF ECMs were characterized by scanning electron microscopy, atomic force microscopy, a four-point conductivity probe, cyclic voltammetry, and contact angle goniometry. The utilization of the PANI-CNT material led to significant advantages, including: (1) increased electrical conductivity by nearly an order of magnitude; (2) increased surface hydrophilicity while not impacting membrane selectivity or permeability; and (3) greatly improved stability under anodic conditions. The membranes anodic stability was evaluated in a pH-controlled aqueous environment under a wide range of anodic potentials using a three-electrode cell. Results indicate a significantly reduced degradation rate in comparison to a CNT-poly(vinyl alcohol) ECM under high anodic potentials. Fouling experiments conducted with bovine serum albumin demonstrated the capacity of the PANI-CNT ECMs for in situ oxidative cleaning, with membrane flux restored to its initial value under an applied potential of 3 V. Additionally, a model organic compound (methylene blue) was electrochemically transformed at high efficiency (90%) in a single pass through the anodically charged ECM.

Biomass density and filament length synergistically affect activated sludge settling: systematic quantification and modeling.

Settling of the biomass produced during biological treatment of wastewater is a critical and often problematic process. Filamentous bacteria content is the best-known factor affecting biomass settleability in activated sludge wastewater treatment systems, and varying biomass density has recently been shown to play an important role as well. The objective of this study was to systematically determine how filament content and biomass density combine to affect microbial biomass settling, with a focus on density variations over the range found in full-scale systems. A laboratory-scale bioreactor system was operated to produce biomass with a range of filamentous bacterium contents. Biomass density was systematically varied in samples from this system by addition of synthetic microspheres to allow separation of filament content and density effects on settleability. Fluorescent in-situ hybridization indicated that the culture was dominated by Sphaerotilus natans, a common contributor to poor settling in full-scale systems. A simple, image-based metric of filament content (filament length per floc area) was linearly correlated with the more commonly used filament length per dry biomass measurement. A non-linear, semi-empirical model of settleability as a function of filament content and density was developed and evaluated, providing a better understanding of how these two parameters combine to affect settleability. Filament content (length per dry biomass weight) was nearly linearly related to sludge volume index (SVI) values, with a slightly decreasing differential, and biomass density exhibited an asymptotic relationship with SVI. The filament content associated with bulking was shown to be a function of biomass density. The marginal effect of filament content on settleability increased with decreasing biomass density (low density biomass was more sensitive to changes in filament content than was high density biomass), indicating a synergistic relationship between these factors. Consideration of both biomass density and filament content, as by the methods and model described herein, should improve operation and troubleshooting of settling processes for biological solids.

Characterization of ZnS Nanoparticle Aggregation using Photoluminescence

Aggregation of uncoated ZnS nanoparticles was determined to have an unexpected impact on the particles photoluminescent properties. Aggregation had significant consequences to both band-edge and trap-site photoluminescence, increasing the former and decreasing the latter. The onset of changes to photoluminescence was influenced by aggregation rate. Results suggest that aggregate structure plays an important role in determining the extent to which changes to photoluminescence occur. Strong evidence is presented in support of the hypothesis that aggregation-induced changes to surface tension are responsible for the observed photoluminescence behavior. We show that changes in photoluminescence can be used to predict the attachment coefficient, in lieu of dynamic light scattering. Additionally, our data indicate that the particle size distribution of aggregating ZnS nanoparticles is invariant across electrolyte concentrations, at a given standard deviation away from the maximum rate of photoluminescence change.

Electroconductive and electroresponsive membranes for water treatment

Abstract In populated, water-scarce regions, seawater and wastewater are considered as potable water resources that require extensive treatment before being suitable for consumption. The separation of water from salt, organic, and inorganic matter is most commonly done through membrane separation processes. Because of permeate flux and concentration polarization, membranes are prone to fouling, resulting in a decline in membrane performance and increased energy demands. As the physical and chemical properties of commercially available membranes (polymeric and ceramic) are relatively static and insensitive to changes in the environment, there is a need for stimuli-reactive membranes with controlled, tunable surface and transport properties to decrease fouling and control membrane properties such as hydrophilicity and permselectivity. In this review, we first describe the application of electricity-conducting and electricity-responsive membranes (ERMs) for fouling mitigation. We discuss their ability to reduce organic, inorganic, and biological fouling by several mechanisms, including control over the membrane’s surface morphology, electrostatic rejection, piezoelectric vibrations, electrochemical reactions, and local pH changes. Next, we examine the use of ERMs for permselectivity modification, which allows for the optimization of rejection and control over ion transport through the application of electrical potentials and the use of electrostatically charged membrane surfaces. In addition, electrochemical reactions coupled with membrane filtration are examined, including electro-oxidation and electro-Fenton reactions, demonstrating the capability of ERMs to electro-oxidize organic contaminates with high efficiency due to high surface area and reduced mass diffusion limitations. When applicable, ERM applications are compared with commercial membranes in terms of energy consumptions. We conclude with a brief discussion regarding the future directions of ERMs and provide examples of several applications such as pore size and selectivity control, electrowettability, and capacitive deionization. To provide the reader with the current state of knowledge, the review focuses on research published in the last 5 years.

Wastewater Reuse for Agriculture: Development of a Regional Water Reuse Decision-Support Model (RWRM) for Cost-Effective Irrigation Sources

Water scarcity has become a critical problem in many semiarid and arid regions. The single largest water use in such regions is for crop irrigation, which typically relies on groundwater and surface water sources. With increasing stress on these traditional water sources, it is important to consider alternative irrigation sources for areas with limited freshwater resources. One potential irrigation water resource is treated wastewater for agricultural fields located near urban centers. In addition, treated wastewater can contribute an appreciable amount of necessary nutrients for plants. The suitability of reclaimed water for specific applications depends on water quality and usage requirements. The main factors that determine the suitability of recycled water for agricultural irrigation are salinity, heavy metals, and pathogens, which cause adverse effects on human, plants, and soils. In this paper, we develop a regional water reuse decision-support model (RWRM) using the general algebraic modeling system to analyze the cost-effectiveness of alternative treatment trains to generate irrigation water from reclaimed wastewater, with the irrigation water designed to meet crop requirements as well as Californias wastewater reuse regulations (Title 22). Using a cost-minimization framework, least-cost solutions consisting of treatment processes and their intensities (blending ratios) are identified to produce alternative irrigation sources for citrus and turfgrass. Our analysis illustrates the benefits of employing an optimization framework and flexible treatment design to identify cost-effective blending opportunities that may produce high-quality irrigation water for a wide range of end uses.