David L. Vander Jagt

Convenient synthetic routes to the 5,6-trimethylenenorbornanones

Exo-endo relative reactivities in three representative U-shaped systems. Exo-endo rate ratio in solvolysis as a steric phenomenon

Unusually high exo-endo rate ratio in the solvolysis of the 2,2,6-trimethyl-2-norbornyl p-nitrobenzoates. Evidence for steric effects as a major factor in the exo-endo rate ratios of norbornyl derivatives

Reactions of Benzyne with Pyrroles

High exo:endo rate ratios in the solvolysis of the 2-methyl- and 2-phenyl-exo-5,6-trimethylene-2-norbornyl p-nitrobenzoates. Evidence for the unimportance of .sigma. participation in the high exo:endo rate ratios in tertiary norbornyl derivatives

Structural effects in solvolytic reactions. 31. High exo:endo rate and product ratios in the solvolyses of the 2-methyl-, 2-phenyl-, and 2-(5'-coumaranyl)-exo-5,6-trimethylene-2-norbornyl p-nitrobenzoates

Evidence for steric hindrance to ionization in the slow rates of solvolysis of the tertiary 2-,8-, and 9-phenyl-endo-5,6-trimethylene-endo-norbornanyl p-nitrobenzoates. An unusually high exo:endo rate ration not involving .sigma. participation

Rates of solvolysis of the p-nitrobenzoates of tertiary 8- and 9-methyl-endo-5,6-trimethylenenorbornanols. Evidence for steric hindrance to ionization in the endo derivatives

Reactions of 1-(Chloromethyl)naphthalenes

EINFACHE SYNTH. FUER 5,6-TRIMETHYLENNORBORNANONE