David Mannes

Characterizing saline uptake and salt distributions in porous limestone with neutron radiography and X-ray micro-tomography

Samples of Savonnières limestone subjected to repeated wetting–drying cycles were investigated by both neutron radiography and X-ray micro-tomography to collect information on saline uptake and salt precipitation. Capillary uptake of water, 1.4 molal sodium sulphate and 5.8 molal sodium chloride solution was visualized with neutron radiography. The liquid penetration coefficients and diffusivities were determined and are markedly lower for the salt solutions than for water, due to the higher surface tension and viscosity of salt solutions. Halite distributions were derived from neutron radiographs. Porosity analysis of X-ray tomographic datasets allowed quantifying thenardite distributions and porosity decrease due to salt crystallization.

Non-destructive determination and quantification of diffusion processes in wood by means of neutron imaging.

Abstract Diffusion processes in samples of European beech (Fagus sylvatica L.) and Norway spruce (Picea abies [L.] Karst.) were determined and quantified by means of neutron imaging (NI). The experiments were carried out at the neutron imaging facility NEUTRA at the Paul Scherrer Institute in Villigen (Switzerland) using a thermal neutron spectrum. NI is a non-destructive and non-invasive testing method with a very high sensitivity for hydrogen and thus water. Within the scope of this study, diffusion processes in the longitudinal direction were ascertained for solid wood samples exposed to a differentiating climate (dry side/wet side). With NI it was possible to determine the local distribution and consequently the total amount of water absorbed by the samples. The calculated values scarcely differ from those ascertained by weighing (≤3%). The method yields profiles of the water content over the whole sample, thus allowing the local and temporal resolution of diffusion processes within the sample in the main transport direction (longitudinal). On the basis of these profiles, it was possible to calculate the diffusion coefficients along the fibre direction according to Ficks second law.

Gas Evolution in Operating Lithium-Ion Batteries Studied In Situ by Neutron Imaging.

Gas generation as a result of electrolyte decomposition is one of the major issues of high-performance rechargeable batteries. Here, we report the direct observation of gassing in operating lithium-ion batteries using neutron imaging. This technique can be used to obtain qualitative as well as quantitative information by applying a new analysis approach. Special emphasis is placed on high voltage LiNi0.5Mn1.5O4/graphite pouch cells. Continuous gassing due to oxidation and reduction of electrolyte solvents is observed. To separate gas evolution reactions occurring on the anode from those associated with the cathode interface and to gain more insight into the gassing behavior of LiNi0.5Mn1.5O4/graphite cells, neutron experiments were also conducted systematically on other cathode/anode combinations, including LiFePO4/graphite, LiNi0.5Mn1.5O4/Li4Ti5O12 and LiFePO4/Li4Ti5O12. In addition, the data were supported by gas pressure measurements. The results suggest that metal dissolution in the electrolyte and decomposition products resulting from the high potentials adversely affect the gas generation, particularly in the first charge cycle (i.e., during graphite solid-electrolyte interface layer formation).

Olive Tree-Ring Problematic Dating: A Comparative Analysis on Santorini (Greece)

Olive trees are a classic component of Mediterranean environments and some of them are known historically to be very old. In order to evaluate the possibility to use olive tree-rings for dendrochronology, we examined by various methods the reliability of olive tree-rings identification. Dendrochronological analyses of olive trees growing on the Aegean island Santorini (Greece) show that the determination of the number of tree-rings is impossible because of intra-annual wood density fluctuations, variability in tree-ring boundary structure, and restriction of its cambial activity to shifting sectors of the circumference, causing the tree-ring sequences along radii of the same cross section to differ.

High-resolution proxies for wood density variations in Terminalia superba.

BACKGROUND AND AIMS Density is a crucial variable in forest and wood science and is evaluated by a multitude of methods. Direct gravimetric methods are mostly destructive and time-consuming. Therefore, faster and semi- to non-destructive indirect methods have been developed. METHODS Profiles of wood density variations with a resolution of approx. 50 µm were derived from one-dimensional resistance drillings, two-dimensional neutron scans, and three-dimensional neutron and X-ray scans. All methods were applied on Terminalia superba Engl. & Diels, an African pioneer species which sometimes exhibits a brown heart (limba noir). KEY RESULTS The use of X-ray tomography combined with a reference material permitted direct estimates of wood density. These X-ray-derived densities overestimated gravimetrically determined densities non-significantly and showed high correlation (linear regression, R(2) = 0·995). When comparing X-ray densities with the attenuation coefficients of neutron scans and the amplitude of drilling resistance, a significant linear relation was found with the neutron attenuation coefficient (R(2) = 0·986) yet a weak relation with drilling resistance (R(2) = 0·243). When density patterns are compared, all three methods are capable of revealing the same trends. Differences are mainly due to the orientation of tree rings and the different characteristics of the indirect methods. CONCLUSIONS High-resolution X-ray computed tomography is a promising technique for research on wood cores and will be explored further on other temperate and tropical species. Further study on limba noir is necessary to reveal the causes of density variations and to determine how resistance drillings can be further refined.

Quantitative determination of bound water diffusion in multilayer boards by means of neutron imaging.

Diffusion processes into multilayered samples of Norway spruce (Picea abies [L.] Karst.) exposed to a differentiating climate (dry side/wet side) were determined and quantified by means of neutron imaging (NI). The experiments were carried out at the neutron imaging facility NEUTRA at the Paul Scherrer Institute (PSI) in Villigen (Switzerland).With NI the influence of different adhesives (polyvinyl acetate (PVAc), urea formaldehyde resin (UF), epoxy resin (EP), one-component polyurethane (1C PUR)) on the diffusion process could be determined by varying the layer number and the thickness of adhesive joints of the samples. Thereby, neutron transmission images were used to measure time dependent water profiles in the diffusion direction. Using Fick’s second law, diffusion coefficients for radial and tangential water transport in spruce wood and in the adhesive joints were calculated depending on moisture content (MC). It was found that the diffusion coefficients of the adhesives (1C PUR, EP at high MC) were up to three orders of magnitude lower than those of spruce wood. PVAc and UF had a smaller barrier effect compared to wood, which in contrast to 1C PUR and EP, clearly depends on the MC.ZusammenfassungEs wurden Diffusionsprozesse an mehrlagigen Proben von Fichte (Picea abies [L.] Karst.), welche einem Differenzklima (trocken/feucht) ausgesetzt waren, mittels Neutronenradiographie untersucht und quantifiziert. Die Experimente wurden an der Radiographiestrahllinie NEUTRA am Paul Scherrer Institut (PSI) in Villigen (Schweiz) durchgeführt.Mittels Neutronenradiographie konnte der Einfluss verschiedener Klebstoffe (Polyvinylacetat (PVAc), Harnstoffharz (UF), Epoxidharz (EP) und Einkomponenten-Polyurethan (1K-PUR)) auf den Diffusionsprozess bestimmt werden, indem die Anzahl und die Dicke der Klebfugen variiert wurden. Dabei wurden Neutronen-Transmissionsbilder verwendet, womit zeitabhängige Profile in Diffusionsrichtung gemessen werden konnten. Anhand des zweiten Fick’schen Gesetzes konnten die Diffusionskoeffizienten für die Klebstoffe sowie für Fichte in radialer und tangentialer Richtung in Abhängigkeit der Feuchte berechnet werden. Dabei wiesen die Klebstoffe (1K-PUR, EP bei hohen Feuchten) bis zu drei Zehnerpotenzen niedrigere Diffusionskoeffizienten als Fichtenholz auf. Bei PVAc und UF war die Sperrwirkung gegenüber dem Holz geringer und es zeigte sich im Gegensatz zu 1K-PUR und EP eine deutliche Abhängigkeit von der Holzfeuchte.

On-line monitoring of hygroscopicity and dimensional changes of wood during thermal modification by means of neutron imaging methods

Abstract European beech (Fagus sylvatica L.) and Norway spruce [Picea abies (L.) Karst.] have been thermally modified in a combined air-steam atmosphere between 70°C and 150°C and pressures up to 4 bar, and the changes of dimensions and moisture contents (MC) of the samples were studied in-situ by means of neutron imaging (NI). This non-invasive testing method offers unique opportunities. NI is highly sensitive for hydrogen and thus well suited for monitoring the MC changes, although some metals (e.g., Al), indispensable for sample environments under high temperature and pressure, are practically transparent to neutrons. The results show that the modification induced changes of MC and dimensions both in radial and tangential direction can well be determined by NI. Dimensional changes from water saturation to oven-dry state, the sorption isotherms, and the differential swelling were observed. Additionally, the sorption behaviour at 20°C was investigated after thermal modification and colour measurements were carried out before and after the thermal treatment.

Neutron attenuation coefficients for non-invasive quantification of wood properties.

Abstract Attenuation coefficients and mass attenuation coefficients of wood were determined theoretically and experimentally for thermal and cold neutrons. Experiments were carried out at the neutron imaging facilities at the Paul Scherrer Institute, Villigen (CH). For the calculation of theoretical attenuation coefficients, only the three main elemental components (carbon, oxygen and hydrogen) were taken into consideration. While hydrogen accounts only for 6% (by wt) of wood, over 90% of the attenuation can be attributed to this element. Nitrogen and other trace elements were estimated to have a negligible impact on the theoretical attenuation coefficient. For the experimental determination of the attenuation coefficients, samples from different European and tropical wood species were tested in order to examine the influence of density and extractives content. Experimental results show a very strong linear correlation between attenuation coefficient and wood density irrespective of the tested species and extractives content that play only a minor role. As neutrons are very susceptible to scattering, it is necessary to apply a scattering correction if a quantitative evaluation is intended.

Combination of X-ray and digital image correlation for the analysis of moisture-induced strain in wood: opportunities and challenges

In this present study, the moisture-induced deformation behaviour of a spruce sample was analysed one- and two-dimensionally with high resolution on the radial-tangential surface. For this purpose, an artificial speckle pattern was applied to the surface which was then recorded by a CCD camera during the deformation. The generated TIF images were analysed with a strain mapping software (VIC 2D) that computed the two-dimensional strain field from the surface deformation.Selected options to evaluate two-dimensional data generated with X-ray imaging and digital image correlation are presented. Combining and correlating these techniques enables detailed analysis of structure-function relationships during swelling (and shrinkage) processes in wood. However, several issues still have to be solved to enhance effectiveness and user-friendliness of such investigations, as elucidated in detail in this paper.ZusammenfassungIn dieser Arbeit wurde das feuchte-induzierte Deformationsverhalten einer Fichtenholzprobe ein- und zweidimensional mit hoher Auflösung auf der radial-tangentialen Probenoberfläche analysiert. Dazu wurde ein künstliches Specklemuster auf die Probenoberfläche aufgebracht, welches dann mit einer CCD-Kamera während der Deformation gefilmt wurde. Die generierten TIF-Dateien wurden mit einer Bildkorrelationssoftware (VIC 2D) ausgewertet, welche die zweidimensionalen Dehnungen auf der Probenoberfläche berechnete.Es werden ausgewählte Möglichkeiten zur Auswertung zweidimensionaler Daten vorgestellt, die durch Röntgendurchstrahlung und digitale Bildkorrelation generiert wurden. Einerseits ermöglicht die Kombination und Korrelation dieser Techniken eine detaillierte Analyse von Struktur- Eigenschafts-Beziehungen während der Quell- (und Schwind-) Prozesse in Holz. Andererseits müssen noch einige Probleme gelöst werden, um die Effektivität und die Benutzerfreundlichkeit derartiger Untersuchungsmethoden zu verbessern, was in diesem Artikel im Detail beleuchtet wird.

The olive-branch dating of the Santorini eruption

The date of the volcanic eruption of Santorini that caused extensive damage toMinoan Crete has been controversial since the 1980s. Some have placed the event in the late seventeenth century BC. Others have made the case for a younger date of around 1500 BC. A recent contribution to that controversy has been the dating of an olive tree branch preserved within the volcanic ash fall on Santorini. In this debate feature Paolo Cherubini and colleagues argue that the olive tree dating (which supports the older chronology) is unreliable on a number of grounds. There follows a response from the authors of that dating, and comments from other specialists, with a closing reply from Cherubini and his team.