David R. Zornes

Using magnetic resonance imaging to monitor CH4 hydrate formation and spontaneous conversion of CH4 hydrate to CO2 hydrate in porous media

Magnetic resonance imaging was used to monitor and quantify methane hydrate formation and exchange in porous media. Conversion of methane hydrate to carbon dioxide hydrate, when exposed to liquid carbon dioxide at 8.27 MPa and approximately 4 degrees C, was experimentally demonstrated with MRI data and verified by mass balance calculations of consumed volumes of gases and liquids. No detectable dissociation of the hydrate was measured during the exchange process.

MRI Visualization of Spontaneous Methane Production From Hydrates in Sandstone Core Plugs When Exposed to CO2

Magnetic resonance imaging (MRI) of core samples in laboratory experiments showed that CO2 storage in gas hydrates formed in porous rock resulted in the spontaneous production of methane with no associated water production. The exposure of methane hydrate in the pores to liquid CO2 resulted in methane production from the hydrate that suggested the exchange of methane molecules with CO2 molecules within the hydrate without the addition or subtraction of significant amounts of heat. Thermodynamic simulations based on Phase Field Theory were in agreement with these results and predicted similar methane production rates that were observed in several experiments. MRI-based 3D visualizations of the formation of hydrates in the porous rock and the methane production improved the interpretation of the experiments. The sequestration of an important greenhouse gas while simultaneously producing the freed natural gas offers access to the significant amounts of energy bound in natural gas hydrates and also offers an attractive potential for CO2 storage. The potential danger associated with catastrophic dissociation of hydrate structures in nature and the corresponding collapse of geological formations is reduced because of the increased thermodynamic stability of the CO2 hydrate relative to the natural gas hydrate.

Magnetic Resonance Imaging of Methane - Carbon Dioxide Hydrate Reactions in Sandstone Pores

Formation and growth of methane hydrates in porous sandstone was monitored using Magnetic Resonance Imaging (MRI). A series of 3-D MRI images collected during these experiments illustrated patterns of hydrate growth. Calibrated MRI intensity changes that occured during the hydrate growth correlated with methane gas consumption and gave dynamic and quantitative in-situ information on hydrate formation rate and spatial distribution of the hydrate formed. Gas permeability was measured at various hydrate saturations and during hydrate growth. Experimentally it was verified that methane hydrate in porous sandstone spontaneously converted to CO2 hydrate when exposed to liquid CO2 at high pressure and low temperature. It has experimentally been determined that without heating, an exchange process between CO2 and methane occured allowing the injected CO2 to be stored as hydrate resulting in spontaneous production of methane, with no associated water production. The MRI images provided quantitative information on the methane production rates and amounts of methane released during the CH4-CO2 hydrate exchange reaction. Thermodynamic simulations based on Phase Field theory supported the measured results and predicted similar methane production rates observed in several reproduced experiments.

Application of Freshwater and Brine Polymer Flooding in the North Burbank Unit, Osage County, Oklahoma

A freshwater polymer-flood project was implemented in a 1,440-acre area of the North Burbank Unit (NBU) in 1980 with sequential injection of 4.2 million Ibm of polyacrylamide and 4.0 million Ibm of a 2.9% aluminum citrate crosslinking solution. Response to polymer flooding has been very pronounced, with ultimate incremental oil recovery projected to exceed 2.5 MMSTB of oil and total project oil expected to be 4.5 MMSTB. A crosslinked polymer-flood process for use in brine was developed that displays equally favorable performance characteristics as the freshwater polymer-flooding system.