David Sebag

Soil organic matter (SOM) characterization by Rock-Eval pyrolysis : scope and limitations

Application of Rock-Eval pyrolysis to soil organic matter (SOM) quantitation and characterization has been explored by the study of about 100 soil samples taken from a variety of soil profiles from different ecosystems at different latitudes. A straightforward illustration of these possibilities can be obtained from a Hydrogen Index (HI in mg hydrocarbons g−1 TOC) vs. Total Organic Carbon (TOC) diagram that effectively allows one to follow simultaneously the main qualitative (SOM hydrogen richness given by HI values) and quantitative (TOC) changes that affect SOM with increasing depth and humification, in the soil profiles. In addition, abnormally high Oxygen Index (OI in mg CO, CO2 or O2 g−1 TOC) values are fully diagnostic of extensive SOM alteration, as frequently observed in podzol B horizons. More detailed information on the heterogeneity of SOM and on its degree of evolution, can be gained from the shape of the pyrolysis S2 peak recorded in the course of programmed pyrolysis in an inert atmosphere (N2) and/or from its maximum temperature “Tpeak”. All these parameters and others, all determined rapidly and automatically, are particularly useful to screen major SOM variations within large sets of samples.

The natural hydrous sodium silicates from the northern bank of Lake Chad: occurrence, petrology and genesis

Abstract Hydrous sodium silicates sometimes associated with zeolites, form in an alkaline environment, in which there is a high concentration of dissolved silica. Such an environment existed during the Holocene in NGuigmi interdunal depressions (Lake Chad), which led to the precipitation of various types of hydrous sodium silicates, including magadiite, kenyaite, and zeolites. Scanning electron and optical microscope observations allow several microstructures to be distinguished. These microstructures result from either precipitation sequences or a transformation along a diagenetic gradient. New petrological, microstructural and geochemical data confirm the transformation of magadiite into kenyaite during its diagenetic evolution, of which the final stage is probably Magadi-type chert. The study of various deposits of these minerals (hardened beds, scattered isolated crystals, mineralized plant debris, irregular concretions) have been used for paleo-environmental reconstruction. The decrease in the abundance of magadiite concretions in the sedimentary sequence can probably be explained by the climatic evolution of the region.

Quasi‐decadal signals of Sahel rainfall and West African monsoon since the mid‐twentieth century

[1]xa0Sahel rainfall shows pronounced decadal variability and a negative trend between wet conditions in the 1950s–1960s and dry ones in the 1970s–1980s. Using continuous wavelet transform, the quasi-decadal variability (QDV) of rainfall reveals zonal contrasts. The highest QDV is identified in the 1950s–1960s over western Sahel and in the 1970s–1980s over eastern Sahel. The quasi-decadal atmospheric anomalies have been reconstructed using Fourier transform for the 1950s–1960s and the 1970s–1980s, respectively, and assessed by the composite analysis of the QDV phases for the periods before and after 1968. Over western Sahel, the rainfall QDV in the 1950s–1960s is related to the North Atlantic sea surface temperature (SST) variability, as highlighted by the wavelet coherence. A southward shift trend of the Intertropical Convergence Zone (ITCZ) is identified through an enhancement of northeasterly fluxes and moisture convergence over the western part of West Africa. A decrease (increase) of southern (northern) subtropical sinking motions seems to be involved. In the 1970s–1980s, a strengthening of cross-equatorial Atlantic SST and pressure gradients is related to an increase of monsoon flow from lower troposphere up to the midtroposphere and to the northward shift of the ITCZ, mainly over eastern Sahel. The Pacific SST influence is also identified, which involves changes in the global zonal circulation.

Coupled Rock-Eval pyrolysis and spectrophotometry for lacustrine sedimentary dynamics: Application for West Central African rainforests (Kamalété and Nguène lakes, Gabon)

In recent years, Nguène Lake and Kamalété Lake (Gabon, West Central Africa) have been studied repeatedly, providing comprehensive reconstructions of environmental changes over the last millennia. Both lakes are in different geomorphological and environmental settings. They are therefore excellent sites to test new methodological approaches. Indeed, the sedimentary cores provide various facies, and the previous studies provide references for calibrating the results of new methods. In this methodological issue, the present study aims to evaluate the potential of spectrophotometric and Rock-Eval coupled analysis to describe the Holocene lake and marsh deposits from tropical moist forests. This assessment is carried out on samples taken from two well-documented reference cores. The spectrophotometric analysis provides reproducible colour measurements, which inform about the nature of the main colour-bearing constituents. Coupled with Rock-Eval pyrolysis, this technique can be used to describe lithological changes and identify the probable source of sedimentary organic matter. In the studied cases, this approach identified the facies dominated by detrital terrigenous inputs (‘iron bearing’ signature and high OI values) and those associated with a more abundant primary production (‘chlorophyll’ signature, low OI and high HI), providing a distinction between palustrine and lacustrine dynamics. However, although the facies are comparable, sedimentary dynamics and sediment sources may vary depending on geomorphological and climatic contexts.

Early anthropogenic impact on Western Central African rainforests 2,600 y ago

Significance Modern human societies live in strongly altered ecosystems. However, anthropogenic environmental disturbances occurred long before the industrial revolution. About 2,600 y ago, a forest–savannah mosaic replaced dense rainforests in Western Central Africa. This rainforest crisis was previously attributed either to the impact of climate change or, to a lesser extent, to the expansion of Bantu peoples through Central Africa. A 10,500-y sedimentary record from Lake Barombi, Southwest Cameroon, demonstrates that the rainforest crisis was not associated with any significant hydrological change. Based on a detailed investigation of a regional archaeological database, we present evidence that humans altered the rainforest ecosystem and left detectable traces in the sediments deposited in Lake Barombi. A potential human footprint on Western Central African rainforests before the Common Era has become the focus of an ongoing controversy. Between 3,000 y ago and 2,000 y ago, regional pollen sequences indicate a replacement of mature rainforests by a forest–savannah mosaic including pioneer trees. Although some studies suggested an anthropogenic influence on this forest fragmentation, current interpretations based on pollen data attribute the ‘‘rainforest crisis’’ to climate change toward a drier, more seasonal climate. A rigorous test of this hypothesis, however, requires climate proxies independent of vegetation changes. Here we resolve this controversy through a continuous 10,500-y record of both vegetation and hydrological changes from Lake Barombi in Southwest Cameroon based on changes in carbon and hydrogen isotope compositions of plant waxes. δ13C-inferred vegetation changes confirm a prominent and abrupt appearance of C4 plants in the Lake Barombi catchment, at 2,600 calendar years before AD 1950 (cal y BP), followed by an equally sudden return to rainforest vegetation at 2,020 cal y BP. δD values from the same plant wax compounds, however, show no simultaneous hydrological change. Based on the combination of these data with a comprehensive regional archaeological database we provide evidence that humans triggered the rainforest fragmentation 2,600 y ago. Our findings suggest that technological developments, including agricultural practices and iron metallurgy, possibly related to the large-scale Bantu expansion, significantly impacted the ecosystems before the Common Era.

Low-frequency variability and zonal contrast in Sahel rainfall and Atlantic sea surface temperature teleconnections during the last century

This study systematically examines teleconnections between Atlantic sea surface temperature (SST) and the west–east distribution of Sahel rainfall throughout the twentieth century, taking nonstationarity into account. Sahel rainfall variability of six selected rain gauges displays three dominant time scales: multi-decadal (>20xa0years), quasi-decadal (8–18 years) and interannual (2–8 years). Regarding their patterns of low-frequency scales, three coherent Sahelian subregions can be identified: the Atlantic Coast (Dakar), western–central Sahel (Nioro and Mopti) and eastern Sahel (Niamey, Maradi, Maine-Soroa). Cross-analyses combining spectral and multivariate analyses of 20 station-based data and West-African gridded rainfall data statistically confirm dissimilarities between the western and eastern Sahel. Western and eastern Sahel rainfall data are correlated with SSTs from different regions of the Atlantic Ocean, especially in the North and tropical South Atlantic. As determined by wavelet coherence and phase, in-phase relationship with North Atlantic SSTs only occurs in wet periods and at the multi- and quasi-decadal scales. This teleconnection depends on the time period and the time scale, displaying a NW–SE pattern, which suggests nonuniform modulations of meridional displacements of the Intertropical Convergence Zone (ITCZ). Tropical South Atlantic SST variability is often related to opposite patterns between the Gulf of Guinean Coast (in phase) and Sahel region (out of phase).

Biodiversity and conservation genetics research in Central Africa: new approaches and avenues for international collaboration

A five-day international workshop was recently convened at the Université des Sciences et Techniques de Masuku in Gabon to enhance international collaboration among Central African, US and European scientists, conservation professionals and policy makers. The overall aims of the workshop were to: (1) discuss emerging priorities in biodiversity and conservation genetics research across Central Africa, and (2) create new networking opportunities among workshop participants. Here we provide a brief overview of the meeting, outline the major recommendations that emerged from it, and provide information on new networking opportunities through the meeting web site.

Holocene evolution of a wetland in the Lower Seine Valley, Marais Vernier, France

Estuaries like that of the Seine River in NW Europe developed in incised fluvial valleys after the last glacial maximum. Since the 1940s, several authors have studied the largest wetland of the Seine estuary, the Marais Vernier, to understand depositional environments during Holocene infilling. We reinterpret previous research based on new and published data (for example fill thickness and material source) to (1) describe facies and depositional environments; (2) reconstruct palaeoenvironmental evolution; (3) show the influence of local and global forcing on depositional environments. Before 7000—6000 cal. BC, terrestrial material was deposited because of catchment erosion related to changes in climate. Just before 7000—6000 cal. BC, estuarine material began to be deposited in low-lying areas in response to sea-level rise, while terrestrial material still settled at higher elevations. After this, but before 5850—5710 cal. BC, estuarine material areas began to accumulate at both high and low elevations. This marked a general flooding of the Marais Vernier, synchronous with that at the Seine estuary mouth. Soon after, peat accumulated over a wide area as a response to a local change in accommodation and a worldwide drop in sea level. A tidal channel developed to the west of the Marais Vernier, providing minerogenic material. After 1130—900 cal. BC, human influence becomes increasingly clear in the record. This record of regional change during the Holocene can serve as a reference for further studies in the area.

Reply to Giresse et al.: No evidence for climate variability during the late Holocene rainforest crisis in Western Central Africa

Giresse et al. (1) criticize both our paleoclimatic reconstruction and our inferred anthropogenic origin of the late Holocene rainforest crisis (LHRC) (2). However, their argumentation, which is combined with alleged evidence for a climatic change during the LHRC, lacks strong support.nnCiting studies describing both brief (weeklong) and limited periods of leaf wax production in deciduous trees, Giresse et al. (1) conclude that leaf waxes cannot record the environmental variability of a full season. However, this argument is flawed, as evergreen and subtropical deciduous trees produce leaf waxes over much longer timescales—their δD (δDwax) values have been shown to capture environmental variability on even seasonal timescales (3, 4 … nn[↵][1]1To whom correspondence should be addressed. Email: yannickgarcin{at}yahoo.fr.nn [1]: #xref-corresp-1-1

Reply to Clist et al.: Human activity is the most probable trigger of the late Holocene rainforest crisis in Western Central Africa

Clist et al. (1) challenge our conclusions (2), criticizing our archaeological synthesis to maintain that the late Holocene rainforest crisis (LHRC) in Western Central Africa (WCA) was not triggered by human activity.nnClist et al. (1) claim that the archaeological 14C dates we used were not critically evaluated, as we were more concerned with the quantity of dates rather than their quality. However, a careful reading of our article (2) and its associated SI Appendix unambiguously documents that we cautiously weighted the radiometric dates by applying a binning in space and time to correct for investigator bias and oversampling at different sites, following refs. 3⇓–5; this … nn[↵][1]1To whom correspondence should be addressed. Email: yannickgarcin{at}yahoo.fr.nn [1]: #xref-corresp-1-1