Debajyoti Bandyopadhyay

Development of fluxed micropellets for sintering utilising iron oxide waste fines

Abstract Ultrafine iron oxide wastes such as slime, blue dust and Linz–Donawitz (LD) converter sludge have very limited use in sintering of iron ore due to their excessive fineness (−50 μm). Pelletisation of these ultrafine materials for use in blast furnace involves high temperature curing, which is a highly energy intensive process. Briquetting of LD sludge requires costly binders and contains high moisture, which creates problem at high temperature of the downstream process. In order to alleviate these problems, the current study has developed a process for preparing micropellets of waste iron oxide fines (2–6 mm size) without using any binder. The strength of the micropellet has been increased by a novel CO2 treatment process at room temperature. Developed micropellets exhibit very suitable drop strength (125 Nos), tumbler properties and cold compressive strength (∼9 kg/pellet) to withstand cold handling. Low lime containing micropellets have the possibility of being used as a mixed material in usual sinter making, and high lime containing micropellets may be exploited for making super fluxed sinter that can be used as synthetic flux in the basic oxygen furnace process towards the formation of low melting oxidising slag at the early stage of blow.

Behavior of fluxed lime iron oxide pellets in hot metal bath during melting and refining

Lump lime as a flux material in a basic oxygen furnace (BOF) often creates problems in operation due to its high melting point, poor dissolution property, hygroscopic nature, and fines generation tendency. To alleviate these problems, fluxed lime iron oxide pellets (FLIP) containing 30% CaO were developed in this study using waste iron oxide fines and lime. The suitable handling strengths of the pellet (crushing strength: 300 N; drop strength: 130 times) of FLIP were developed by treating with CO2 or industrial waste gas at room temperature, while no separate binders were used. When the pellet was added into hot metal bath (carbon-containing molten iron), it was decomposed, melted, and transformed to produce low melting oxidizing slag, because it is a combination of main CaO and Fe2O3. This slag is suitable for facilitating P and C removal in refining. Furthermore, the pellet enhances waste utilization and use of CO2 in waste gas. In this article, emphasis is given on studying the behavior of these pellets in hot metal bath during melting and refining along with thermodynamics and kinetics analysis. The observed behaviors of the pellet in hot metal bath confirm that it is suitable and beneficial for use in BOF and replaces lump lime.

A Steady State Thermal and Material Balance Model for an Iron Making Blast Furnace and Its Validation with Operational Data

In view of scarcity and depletion in the quality of raw materials as well as stringent environmental regulations, judicious use of resource and adoption of optimal operating practices have become the prime concern in iron and steel industries. Real time forecasting and supervision of the process behavior is an important step in addressing these issues. As a part of the tool termed “Real Time Process Simulator (RTPS)”, containing several reduced order models for real time monitoring and prediction of the internal dynamics of iron making blast furnace, a mathematical model for material and thermal analysis has been developed, mainly to predict the top gas composition, raw material consumption and overall heat balance. The model predictions have been tested against actual plant data. The raceway adiabatic flame temperature has been calculated using data similar to that of an operating plant. The calculated heat distribution of the process has been presented in the form of a SHANKEY diagram. The RTPS, containing the present model has been implemented in an Indian integrated steel plant. Prior to implementation, the model has been tested and validated in the plant operational range with the help of a virtual platform.

Dissolution Characteristics of CO2-Treated Fluxed Pellets in Hot Metal Bath

Lump lime and iron ore are generally used in the basic oxygen furnace as flux and cooling material, respectively. Owing to high melting point, poor dissolution property, fines generation tendency, and hygroscopic nature of lump lime, delay in process and operational complexities are generally encountered. On the other hand, iron ore charging creates slag foaming. In order to alleviate the above problems and to utilize waste materials, fluxed lime–iron oxide pellets (FLIP) containing waste iron oxides and lime fines (10%–40%) were prepared and subsequently strengthened with CO2 gas treatment. FLIP may have the potential to partially replace scrap and lump lime in the conventional basic oxygen furnace charge. In order to assess the applicability of FLIP in steelmaking, the dissolution characteristics of these pellets were studied in a high-temperature pot furnace equipped with a charge-coupled device (CCD) camera under varying experimental conditions. It was found that the dissolution time decreased with increasing hot metal temperature, increasing specific surface area of the pellet, and decreasing lime content of the pellet. The melting of the pellet in the absence of hot metal took much higher time than its presence.

Theoretical Investigation on Deoxidation of Liquid Steel for Fe–Al–Si–O System

Deoxidation of liquid steel involves consumption of high energy materials like ferro alloys and generation of deoxidation products which could be entrapped into liquid steel as non-metallic inclusions. The present investigation is focused on deoxidation of liquid steel, considering mainly aluminium and silicon as deoxidizer. A simple and realistic mathematical model of deoxidation of liquid steel has been developed based on the thermodynamic principles and material balance approach for day to day industrial practice. One of the main aims of the theoretical study was to predict the amount of deoxidizers required for a given steel composition. A methodology has also been developed to predict the stability of different oxides expected to be present in liquid steel after deoxidation. Model predictions have been compared with the industrial data as well as results obtained from commercial thermodynamic software package FactSage 6.4, simulated under identical conditions. Model predictions are in reasonable agreement with the ferro alloy consumption in industrial steelmaking processes.

Performance Assessment of Partially Pre-fused Synthetic Flux in Basic Oxygen Steel Making

Lump lime as the most common flux and iron ore as a coolant are used in basic oxygen steel making. However, high melting point, poor dissolution property, fines generation tendency and hygroscopic nature of lump lime often create problems in operation. As the combination of both iron oxide (Fe2O3) and CaO shows eutectic at 1230 °C, a combined mass of iron oxide and lime melts at lower temperature and dissolves faster in a molten bath. A partially pre-fused synthetic flux (PSF) was prepared through an innovative way in combination of iron oxide fines viz. Linz Donawitz converter sludge and blast furnace flue dust and lime fines by micro-pelletization of the mix followed by coke breeze free sintering. The developed PSF shows good cold handling strength, low melting point (1 180 ºC), good thermal shock resistance, etc. As a low melting synthetic flux, its performance was assessed through dissolution/melting study in hot metal bath and refining of hot metal in a simulated bottom blown converter using (i) PSF, (ii) only lump lime and (iii) lump lime with iron ore when keeping other conditions identical. Very fast dissolution (27–80 s for 1–3 g lumps), enhanced removal of C and P (11–12 min), controlled slag foaming, and reduced oxygen consumption was obtained for using PSF.

A comparative study for smelting of chromite ore, pellets, briquettes and sinter

Abstract Ferrochrome (>62%Cr) and charge chrome (45–52%Cr) production using the submerged arc furnace (SAF) is an established practice in India. As the majority of Cr rich Indian chromite ore are friable in nature and available in fine form, utilisation of chromite fines for production of superior quality ferrochrome is essential. For this purpose, in the present study, the smelting of chromite pellets, briquettes, sinter and lump ore has been carried out in an electric arc furnace of 50 kVA. The energy consumption, yield, Cr recovery and quality of Fe–Cr produced have been compared for different Cr bearing materials. Sinters and pellets have found to be more suitable than briquettes and poor quality lump ore in terms of energy consumption and yield.

Characterization and Evolution of Non-metallic Inclusions in Fe–Al–Si–O System

Presence of non-metallic inclusions in steels are practically inevitable and deoxidation products are one of the main sources for such inclusions. The present investigation focuses on the study of non-metallic inclusions in Fe–Al–Si–O system by considering aluminium and silicon as deoxidizers. This investigation mainly deals with the amount, distribution and morphology of complex non-metallic inclusions in steel, generated during complex deoxidation of liquid steel by silicon and aluminium. Morphology and floatability of various complex non-metallic inclusions present in the system has been discussed based on the physical properties of these oxides. Dissolution of MgO from the refractory lining being unavoidable, the present paper also aims at understanding the mechanism, morphological and compositional evolution of ternary MgO–Al2O3–SiO2 type inclusions.

A reduced order mathematical model of the blast furnace raceway with and without pulverized coal injection for real time plant application

Abstract Pulverized coal is injected into blast furnace tuyeres to reduce coke consumption as well as to reduce hot metal production cost. Knowledge of the combustion behavior of pulverized coal in the blast furnace raceway zone and accumulation of unburnt char are of paramount importance. To alleviate the problem of high computational time of a multidimensional model, a reduced order raceway model of the blast furnace has been proposed for real time plant application. The model is capable of predicting radial temperature and gas composition profiles in the raceway zone with and without pulverized coal injection (PCI). Influence of all the key operating process parameters such as PCI rate, blast temperature, blast volume, oxygen enrichment and steam addition on the raceway combustion behavior, temperature and gas composition profiles as well as raceway depth have been investigated and validated with literature and plant database, wherever possible. It has been observed that with increasing PCI rate on a fixed fuel rate basis, the peak gas temperature (PGT) decreases and the location of PGT tends to shift toward tuyere nose. The present model is an efficient computational tool to predict the raceway process variables for online application, in synchronization with plant operation.