Dejiang Fan

Tracking historical lead pollution in the coastal area adjacent to the Yangtze River Estuary using lead isotopic compositions

The rapid economic development in the Yangtze River Delta (YRD), China in the last three decades has had a significant impact on the environment of the East China Sea (ECS). Lead isotopic compositions of a (210)Pb dated sediment core collected from the coastal ECS adjacent to the Yangtze River Estuary were analyzed to track the Pb pollution in the region. The baseline Pb concentration in the coastal ECS sediments before the industrialization in China was 32 microg g(-1), and the corresponding 206Pb/207Pb ratio was 1.195. The high-resolution profiles of Pb flux and 206Pb/207Pb ratios had close relationships with the economic development and the history of the use of leaded gasoline in China, and they were clearly different from those of most European countries and United States.

Grain size records reveal variability of the East Asian Winter Monsoon since the Middle Holocene in the Central Yellow Sea mud area, China

Three cores (ZY-1, ZY-2 and ZY-3) retrieved from the Central Yellow Sea mud (CYSM) were analyzed in sensitive grain size and AMS 14C dating to reconstruct the history of the East Asian Winter Monsoon (EAWM) since the Middle Holocene in the study area. The results show that these data provide a continuous history of the EAWM over the past 7.2 ka and that the EAWM can be divided into three periods: strong and highly fluctuating during 7.2–4.2 ka BP; moderate and relatively stable during 4.2–1.8 ka BP; and weakened during 1.8–0 ka BP. Compared with the East Asian Summer Monsoon (EASM) recorded in the previous studies, the evolutionary history of the EAWM broadly follows the orbital-derived winter insolation with a similar long-term step-decreased trend as the EASM. At the centennial scale, however, the EAWM intensified events correlate well with the EASM weakened events and the North Atlantic climatic variations (Bond events 0 to 5) within the dating error, most likely forced by the reduction of solar irradiance through changes in the oceanic-atmospheric circulation patterns.

Holocene shifts in riverine fine-grained sediment supply to the East China Sea Distal Mud in response to climate change

Holocene changes in fine-grained sediment supplies to the East China Sea outer shelf were uncovered, through the mineralogical and geochemical analysis of Core B3 in the East China Sea Distal Mud (ECSDM). Based on the lithology, accelerator mass spectrometry (AMS) 14C dating, and sea-level change, Core B3 can be divided into two major units: transgressive stage (Unit 1: 12.5–6.8 kyr) and highstand stage (Unit 2: 6.8–0 kyr). Significant discrepancy of dolomite/calcite ratio in the fine fractions (<16 µm) of Changjiang (dolomite/calcite = 3:1) and Huanghe (dolomite/calcite = 1:22) sediments was used as a new uniqueness provenance tracer to distinguish these two riverine sources. Both of the dolomite/calcite ratio and rare earth elements fractionation parameters in the fine-grained sediment indicated distinct provenance shifts of Core B3 during the Holocene. Unit 1 of Core 3 (12.5–6.8 kyr) mainly consists of the reworked and resuspension sediments of the East China Sea shelf during the Holocene transgression, while Unit 2 sediments (6.8–0 kyr) are most likely sourced from the Changjiang and Huanghe. Moreover, mixing curves of dolomite/calcite ratio reveal that the ECSDM continuously received the Changjiang sediment since 6.1 kyr with notable fluctuations, whereas the Huanghe sediment supply began in 6.8 kyr but abruptly stopped during 4.2–0.8 kyr and then appeared again since 0.8 kyr. Temporal changes of the Changjiang and Huanghe fine-grained sediment contribution to the ECSDM are closely related to the formation of modern oceanic circulation system since 6.8 kyr (shelf sea-level change), the ‘4.2 kyr’ climate event, and the followed transition to cold and dry climate condition in the northeastern China (global climate change), as well as the artificial shift of lower Huanghe course in ad 1128 in the war against invasion of the northern nomadic nation (human activities).

Spatio-temporal distribution and sources of Pb identified by stable isotopic ratios in sediments from the Yangtze River Estuary and adjacent areas

To understand the spatio-temporal distribution and sources of Pb in the sediments of the Yangtze River Estuary and its adjacent areas, 25 surface sediments and 1 sediment core were collected from the study areas. The concentrations of Al and Pb of these sediments exhibit a decreasing trend from the nearshore towards the offshore, with higher concentrations in the coastal areas of the East China Sea (ECS) and southwest of Jeju Island. According to the stable isotopic ratios of Pb, in combination with the elemental ratios and clay mineral data, it is inferred that sedimentary Pb in the surface sediments of the coastal areas of the ECS may come primarily from the Yangtze River, while the Pb southwest of Jeju Island is probably derived from both the Yangtze and Yellow Rivers. The particulate Pb derived from the Yangtze River was possibly dispersed along two paths: the path southward along the coastline of the ECS and the path eastward associated with the Changjiang Diluted Water (CDW), which crosses the shelf of the ECS towards the area southeast of Jeju Island. Although the Yangtze River Basin witnessed rapid economic development during the period from the late 1970s to the middle 1990s, the influence of human activity on Pb concentration remained weak in the Yangtze River Estuary. Since the early 2000s, however, sedimentary Pb has been significantly increasing in the coastal mud areas of the ECS due to the increasing influence of human activity, such as the increase in atmospheric emission of anthropogenic Pb in China, construction of the Three Gorges Dam (TGD), and the construction of smaller dams in the upper reaches of the Yangtze River. Coal combustion and the smelting of non-ferrous metals are possible anthropogenic sources for the sedimentary Pb in the Yangtze River Estuary.

Distribution and sources of polycyclic aromatic hydrocarbons in surface sediments from the Bering Sea and western Arctic Ocean

To analyze the distribution and sources of polycyclic aromatic hydrocarbons (PAHs) and evaluate their potential ecological risks, the concentrations of 16 PAHs were measured in 43 surface sediment samples from the Bering Sea and western Arctic Ocean. Total PAH (tPAH) concentrations ranged from 36.95 to 150.21 ng/g (dry weight). In descending order, the surface sediment tPAH concentrations were as follows: Canada Basin>northern Chukchi Sea>Chukchi Basin>southern Chukchi Sea>Aleutian Basin>Makarov Basin>Bering Sea shelf. The Bering Sea and western Arctic Ocean mainly received PAHs of pyrogenic origin due to pollution caused by the incomplete combustion of fossil fuels. The concentrations of PAHs in the sediments of the study areas did not exceed effects range low (ERL) values.

Water discharge variability of Changjiang (Yangtze) and Huanghe (Yellow) Rivers and its response to climatic changes

Infl uences of large-scale climatic phenomena, such as the El Niño/La Niña-Southern Oscillation (ENSO) and the Pacific Decadal Oscillation (PDO), on the temporal variations of the annual water discharge at the Lijin station in the Huanghe (Yellow) River and at the Datong station in the Changjiang (Yangtze) River were examined. Using the empirical mode decomposition-maximum entropy spectral analysis (EMDMESA) method, the 2- to 3-year, 8- to 14-year, and 23-year cyclical variations of the annual water discharge at the two stations were discovered. Based on the analysis results, the hydrological time series on the interannual to interdecadal scales were constructed. The results indicate that from 1950 to 2011, a significant downward trend occurred in the natural annual water discharge in Huanghe River. However, the changes in water discharge in Changjiang River basin exhibited a slightly upward trend. It indicated that the changes in the river discharge in the Huanghe basin were driven primarily by precipitation. Other factors, such as the precipitation over the Changjiang River tributaries, ice melt and evaporation contributed much more to the increase in the Changjiang River basin. Especially, the impacts of the inter-annual and inter-decadal climate oscillations such as ENSO and PDO could change the long-term patterns of precipitation over the basins of the two major rivers. Generally, low amounts of basin-wide precipitation on interannual to interdecadal scales over the two rivers corresponded to most of the warm ENSO events and the warm phases of the PDO, and vice versa. The positive phases of the PDO and ENSO could lead to reduced precipitation and consequently affect the long-term scale water discharges at the two rivers.

The satellite remotely-sensed analysis of the temporal and spatial variability of chlorophyll a concentration in the northern South China Sea

The semi-enclosed Bohai Sea has received large amount of pollutants from surrounding rivers and sewage channels along the densely populated and industrializing Bohai coasts, as well as the offshore oil exploration in the sea. The concentrations of heavy metals copper, cobalt, nickel, zinc, lead, chromium and cadmium in 25 surface sediment samples from the central Bohai Sea are obtained by ICP-MS analysis. The speciation of these heavy metals is extracted and their distribution, fractionation, pollution status and sources are presented. High concentrations of copper, cobalt, nickel, zinc and chromium are found in the sediments off the coastal area of the Bohai Bay and the central Bohai Sea mud, while high concentrations of cadmium and lead are found in the sediments in the whole study area. The residual fraction is the dominant form of copper, cobalt, nickel, zinc and chromium in the surface sediments, while cadmium and lead have large proportions in the nonresidual fractions. The ecological risk assessment shows that the sediments in the study area are unpolluted with respect to the heavy metals of cobalt, nickel and chromium and unpolluted to moderately polluted with respect to copper, zinc, cadmium and lead. Cobalt, nickel and chromium mainly have natural origin and their concentrations significantly vary with the composition of the sediments. The contents of copper, zinc, lead and especially cadmium in sediments are suggested to be influenced by pollutants of human activities. The heavy metals in the surface sediments at most sampling stations are mainly come from the Huanghe River; the heavy metals in the sediments in the northernmost part of the study area are significantly affected by the sediment from the Luanhe River; while in the Bohai Bay and the central region they were affected by the sediment from the Haihe River and aerosol deposition.

Normalization of excess 210Pb with grain size in the sediment cores from the Yangtze River Estuary and adjacent areas: Implications for sedimentary processes

The fallout radionuclide 210Pb has been widely used as an environment tracer for estimating deposition rates and revealing sedimentary processes. However, a comprehensive evaluation of different grain size fractions effects on the adsorption of 210Pb is a prerequisite for effective utilization of the tracer. In this paper, 11 cores were collected from different sub-sedimentary environments in the Yangtze Estuary and its adjacent area, x-radiographs of the sediment cores were taken, and the grain size and radioactive 210Pb levels were analyzed systematically; the relationship between grain size and 210Pb was discussed in detail. The results indicated that 226Ra was relatively stable, with no systematic variation from the Yangtze Estuary to inner shelf region or with depth and was unaffected by grain size. In contrast to 226Ra, significant positive correlations between the fine fraction (<32 µm) and 210Pbex were found, particularly between the clay component (<4 µm) and 210Pbex, in all the sediment cores. The 210Pbex profiles were improved significantly after using the linear relationships for quantitatively normalizing the activities to the <4 µm components, and the calibrating 210Pbex profiles of different zones matched the sub-sedimentary environments of the recent reduction in sediment discharge after Three Gorges Dam (TGD) impoundment very well. Also, through the normalization procedure, it was found that the Yangtze-derived clay component may play the most important role in the distribution of 210Pbex in sediments, especially in upper layer 10–15 cm of the cores. When applying 210Pb data to establish the geochronology or study sedimentary processes in the East China Sea or similar sedimentary environments, the grain size effect should be fully considered.

Source identification, geochemical normalization and influence factors of heavy metals in Yangtze River Estuary sediment

Sediment samples, including 40 surface samples and 12 sediment cores, were collected from 52 stations of the Yangtze River Estuary (YRE) in 2015 and 2016. The 95% linear prediction intervals (LPI) and principal components analysis (PCA), were conducted to evaluate the metal sources and grain-size effect (GSE). The in situ physico-chemical properties of pH, Eh, DO, salinity, temperature and turbidity were combined to elucidate the relationships between environmental factors and the fate of heavy metals in the river-estuary-shelf system. This study indicates a decreasing trend of metals in sediments from the estuary towards the adjacent shelf and the river channel and that Zn, Cu and Cr are mainly derived from natural processes throughout the catchment, whereas Pb appears to have anthropogenic inputs via atmospheric deposition. Furthermore, considering the best fit regression lines between the concentrations of Al and heavy metals as well as the deficiencies of the conventional Celements/CAl method, we introduce an approach (Al-SN: Al-scope normalization) that can eliminate the GSE on heavy metals and be applied to other estuaries. After Al-scope normalization, the relatively constant levels of Zn, Cu and Cr that remain in sediments from the river channel to the estuary and shelf confirmed that the variation of grain size in sediments almost entirely explained the distribution patterns of sediment toxicity in the YRE, while the enrichment of Pb in estuarine sediments could be attributed to its chemical species and physico-chemical properties. The results further suggest that the relationship between grain size and spatial behavior of sediment pollutants should be given priority over the contamination assessment and provenance discrimination in estuarine or similar environments with complex sediment compositions.

Crystals of suspended marine barite in the eastern equatorial Pacific: processes of dissolution and effects on crystal morphology

Suspended particulate substances were sampled in the eastern equatorial Pacific in water column from surface to near bottom in five stations in 2005, from which 868 barite crystals were recovered. The barite crystals were examined under scanning electron microscopy. About 61% of the total barites crystals contained detectable Sr by energy dispersive X-ray spectrometry. Barite crystals could be classified into four groups based on their morphology: 1) bladed; 2) ovoid or rounded; 3) arrow-like; and 4) irregularly shaped. The arrow-like barite crystals in natural environment has never been reported before. In addition, about a half of the studied crystals showed features of dissolution as cavities or holes inside of the crystals or around their edges. We found that differential dissolution of barite crystals is consequence of heterogeneous Sr distribution in barite crystals. Our results would help in understanding the biogeochemical processes of marine barite formation and preservation in seawater and marine sediments.