Didier Kéravis

Soil organic matter (SOM) characterization by Rock-Eval pyrolysis : scope and limitations

Application of Rock-Eval pyrolysis to soil organic matter (SOM) quantitation and characterization has been explored by the study of about 100 soil samples taken from a variety of soil profiles from different ecosystems at different latitudes. A straightforward illustration of these possibilities can be obtained from a Hydrogen Index (HI in mg hydrocarbons g−1 TOC) vs. Total Organic Carbon (TOC) diagram that effectively allows one to follow simultaneously the main qualitative (SOM hydrogen richness given by HI values) and quantitative (TOC) changes that affect SOM with increasing depth and humification, in the soil profiles. In addition, abnormally high Oxygen Index (OI in mg CO, CO2 or O2 g−1 TOC) values are fully diagnostic of extensive SOM alteration, as frequently observed in podzol B horizons. More detailed information on the heterogeneity of SOM and on its degree of evolution, can be gained from the shape of the pyrolysis S2 peak recorded in the course of programmed pyrolysis in an inert atmosphere (N2) and/or from its maximum temperature “Tpeak”. All these parameters and others, all determined rapidly and automatically, are particularly useful to screen major SOM variations within large sets of samples.

Rapid ecosystem response to abrupt climate changes during the last glacial period in western Europe, 40-16 ka

We present a high-resolution and independently dated multiproxy lake sediment record from the paleolake at Les Echets in southeastern France that displays synchronous changes in independent limnic and terrestrial ecosystem proxies, in concert with millennial-scale climate oscillations during the last glacial period. Distinct lake-level fluctuations, low lake organic productivity, and open, treeless vegetation indicate cold and dry conditions in response to Heinrich events. Alternating phases of higher and low lake organic productivity, stratified surface waters and long-lasting lake ice cover, decreased or increased catchment erosion, and tree-dominated or herb-dominated vegetation resemble Dansgaard-Oeschger interstadialstadial variability. Transitions between different ecological states occurred in as little as 40–230 yr and seem to have been controlled by the position of the Polar Front. Ecosystem response after 30 ka suggests that local climate conditions became more important. Our results demonstrate that all parts of the terrestrial system responded to the abrupt and dramatic climatic changes associated with Dansgaard-Oeschger and Heinrich events, and that regional factors modulated ecosystem response.

Application de l'étude de la matière organique à l'analyse de l'érosion : exemple du bassin versant du Moulin, dans les terres noires des Alpes-de-Haute-Provence (France)

Abstract The present study is based on the optical (palynofacies) and geochemical (pyrolyse Rock–Eval) characterization of the organic matter occurring both in bedrock, soils, river sediments (suspended matter and bedload) in a Draix Erosional Research Basin (Cemagref). Results confirm firstly the contribution of reworked organic matter in modern fluxes. Numerous previous studies have shown that organic matter analysis can be an accurate tool to provide information concerning past climates and past environments. Present results suggests that such analysis can also give information concerning the characterization of eroded bedrocks and of erosional processes such as river bank erosion and runoff.