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Dive into the research topics where Donald Zbinden is active.

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Featured researches published by Donald Zbinden.


Inorganica Chimica Acta | 1985

Proton nuclear magnetic resonance study of N,N-diethylformamide exchange on (N,N-diethylformamide)2,2′2″-tris(dimethylamino)triethylamine)cobalt(II) and its copper(II) analogue

Stephen F. Lincoln; Andrea M. Hounslow; Bruce G. Doddridge; John H. Coates; Andre E. Merbach; Donald Zbinden

Abstract Proton NMR studies of N,N-diethylformamide (def) exchange on [M(Me 6 tren)def] 2+ where M = Co and Cu yield: k ex (298.2K) = 26.3 ± 2.2, 980 ± 70 s −1 ; Δ H ≠ = 58.3 ± 1.7, 36.3 ± 0.9 kJ mol −1 ; Δ S ≠ = −22.2 ± 4.6, −65.9 ± 2.5 J K −1 mol −1 ; and Δ V ≠ = −1.3 ± 0.2, 5.3 ± 0.3 cm 3 mol −1 respectively. These data which are consistent with a and d activation modes operating when M = Co and Cu respectively are compared with data for related systems.


Magnetic Resonance in Chemistry | 1991

Variable-pressure oxygen-17 NMR study of water exchange on hexaaquarhodium(III)†

Gábor Laurenczy; Irina Rapaport; Donald Zbinden; Andre E. Merbach


Helvetica Chimica Acta | 1982

High-Pressure 17O-NMR. Study of Vanadium (II) in Water: A Second Example of an Associative Interchange Mechanism (Ia) for Solvent Exchange on an Octahedral Divalent Transition-Metal Ion†‡

Yves Ducommun; Donald Zbinden; André E. Murbach


Inorganic Chemistry | 1986

Solvent exchange in hexakis(methanol)copper(II) ion. Oxygen-17 NMR variable-temperature, pressure, and frequency study

Lothar Helm; Stephen F. Lincoln; Andre E. Merbach; Donald Zbinden


Organometallics | 1991

The first measurements of activation volumes for hydride fluxionality on metal clusters. Intramolecular exchange of hydrides on osmium and ruthenium complexes, H(m-H)Os3(CO)10(PPh3) and (m-H)2Ru3(m3-CHCO2Me)(CO)9

Jerome B. Keister; Urban Frey; Donald Zbinden; Andre E. Merbach


Inorganic Chemistry | 1984

Proton nuclear magnetic resonance study of N,N-dimethylformamide exchange on (N,N-dimethylformamide)(2,2",2""-tris(dimethylamino)triethylamine)manganese(II) and its cobalt(II) and copper(II) analogs

Stephen F. Lincoln; Andrea M. Hounslow; Dino Pisaniello; Bruce G. Doddridge; John H. Coates; Andre E. Merbach; Donald Zbinden


Helvetica Chimica Acta | 1983

A demonstrated example of competing D and Id mechanisms for dimethylformamide exchange on the octakis(dimethylformamide)erbium(III) ion

Dino Pisaniello; Lothar Helm; Donald Zbinden; Andre E. Merbach


Inorganica Chimica Acta | 1978

STRUCTURE IN SOLUTION AND ACETONITRILE INTERMOLECULAR EXCHANGE PROCESS OF THE ANTIMONY PENTACHLORIDE‐ACETONITRILE ADDUCT

Rene Good; Donald Zbinden; J.Etienne Kessler; Andre E. Merbach


ChemInform | 1986

Solvent Exchange on Hexakis(methanol)copper(II) Ion.17O NMR Variable-Temperature, -Pressure, and -Frequency Study

Lothar Helm; Stephen F. Lincoln; Andre E. Merbach; Donald Zbinden


ChemInform | 1984

PROTON NUCLEAR MAGNETIC RESONANCE STUDY OF N,N-DIMETHYLFORMAMIDE EXCHANGE ON (N,N-DIMETHYLFORMAMIDE)(2,2′,2′′-TRIS(DIMETHYLAMINO)TRIETHYLAMINE)MANGANESE(II) AND ITS COBALT(II) AND COPPER(II) ANALOGS

Stephen F. Lincoln; Andrea M. Hounslow; Dino Pisaniello; Bruce G. Doddridge; John H. Coates; Andre E. Merbach; Donald Zbinden

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Andre E. Merbach

École Polytechnique Fédérale de Lausanne

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Lothar Helm

École Polytechnique Fédérale de Lausanne

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Gábor Laurenczy

École Polytechnique Fédérale de Lausanne

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