Dong-Xu Bao
Sichuan Agricultural University
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Publication
Featured researches published by Dong-Xu Bao.
Journal of Coordination Chemistry | 2016
Dong-Xu Bao; Shuo Xiang; Jin Wang; Yun-Chun Li; Xiao-Qing Zhao
Abstract Single-molecule magnets (SMMs) have attracted attention due to their potential applications in quantum computation and information storage, and many SMMs have been reported in the past two decades. In this review, we summarize the structures and the magnetic exchange interactions of pyridine alcohol-based SMMs to give a possible relationship between structure and magnetic property, providing information to generate new molecule-based magnetic materials. According to the correlated metal centers, these SMMs are separated into three segments to discuss.
ChemistryOpen | 2018
Xiao-Qing Zhao; Shuo Xiang; Jin Wang; Dong-Xu Bao; Yun-Chun Li
Abstract Two 3d‐4f hetero‐metal pentanuclear complexes with the formula {[CrIII 2LnIII 3L10(OH)6(H2O)2]Et3NH} [Ln=Tb (1), Dy (2); HL=pivalic acid, Et3N=triethylamine] have been produced. The metal core of each cluster is made up of a trigonal bipyramid with three LnIII ions (plane) and two CrIII ions (above and below) held together by six μ 3‐OH bridges. Also reported with this series is the diamagnetic CrIII–YIII analogue (3). Fortunately, we successfully prepared AlIII–LnIII analogues with the formula {[AlIII 2LnIII 3L10(OH)6(H2O)2]Et3NH⋅H2O} [Ln=Tb (4), Dy (5)], containing diamagnetic AlIII ions, which can be used to evaluate the CrIII–LnIII magnetic nature through a diamagnetic substitution method. Subsequently, static (dc) magnetic susceptibility studies reveal dominant ferromagnetic interactions between CrIII and LnIII ions. Dynamic (ac) magnetic susceptibility studies show frequency‐dependent out‐of‐phase (χ′′) signals for [CrIII 2TbIII 3] (1), [CrIII 2DyIII 3] (2), and [AlIII 2DyIII 3] (5), which are derived from the single‐ion behavior of LnIII ions and/or the CrIII–LnIII ferromagnetic interactions.
Journal of Luminescence | 2017
Shuo Xiang; Dong-Xu Bao; Jin Wang; Yun-Chun Li; Xiao-Qing Zhao
Dalton Transactions | 2017
Xiao-Qing Zhao; Jin Wang; Dong-Xu Bao; Shuo Xiang; Ya-Jun Liu; Yun-Chun Li
Polyhedron | 2015
Xiao-Qing Zhao; Dong-Xu Bao; Jin Wang; Meng-Qiu Deng; Daibing Luo; Yun-Chun Li
Inorganic Chemistry Communications | 2015
Xiao-Qing Zhao; Jin Wang; Dong-Xu Bao; Shuo Xiang; Daibing Luo
Inorganica Chimica Acta | 2017
Xiao-Qing Zhao; Dong-Xu Bao; Jin Wang; Shuo Xiang; Yun-Chun Li
Archive | 2017
Xiao-Qing Zhao; Jin Wang; Dong-Xu Bao; Shuo Xiang; Ya-Jun Liu; Yun-Chun Li
Archive | 2017
Xiao-Qing Zhao; Jin Wang; Dong-Xu Bao; Shuo Xiang; Ya-Jun Liu; Yun-Chun Li
Archive | 2017
Xiao-Qing Zhao; Jin Wang; Dong-Xu Bao; Shuo Xiang; Ya-Jun Liu; Yun-Chun Li