Drew P. Pulsifer

Optical sensing of analytes in aqueous solutions with a multiple surface-plasmon-polariton-wave platform

The commonly used optical sensor based on surface plasmon-polariton wave phenomenon can sense just one chemical, because only one SPP wave can be guided by the interface of a metal and a dielectric material contained in the sensor. Multiple analytes could be detected and/or the sensing reliability for a single analyte could be enhanced, if multiple SPP-wave modes could be excited on a single metal/dielectric interface. For that to happen, the partnering dielectric material must be periodically non-homogeneous. Using a chiral sculptured thin film (CSTF) as that material in a SPP-wave platform, we show that the angular locations of multiple SPP-wave modes shift when the void regions of the CSTF are infiltrated with a fluid. The sensitivities realized in the proof-of-concept experiments are comparable to state-of-research values.

Background and survey of bioreplication techniques

Bioreplication is the direct reproduction of a biological structure in order to realize at least one specific functionality. Current bioreplication techniques include the sol-gel technique, atomic layer deposition, physical vapor deposition, and imprint lithography and casting. The combined use of a focused ion beam and a scanning electron microscope could develop into a bioreplication technique as well. Some of these techniques are more suitable for reproducing surface features, others for bulk three-dimensional structures. Industrial upscaling appears possible only for imprint lithography and casting (which can be replaced by stamping).

Mass fabrication technique for polymeric replicas of arrays of insect corneas

Motivated to develop a technique for producing many high-fidelity replicas for the sacrifice of a single biotemplate, we combined a modified version of the conformal-evaporated-film-by-rotation technique and electroforming to produce a master negative made of nickel from a composite biotemplate comprising several corneas of common blowflies. This master negative can function as either a mold for casting multiple replicas or a die for stamping multiple replicas. An approximately 250 nm thick nickel film was thermally deposited on an array of blowfly corneas to capture the surface features with high fidelity and then a roughly 60 microm thick structural layer of nickel was electroformed onto the thin layer to give it the structural integrity needed for casting or stamping. The master negative concurrently captured the spatial features of the biotemplate at length scales ranging from 200 nm to a few millimeters. Polymer replicas produced thereafter by casting did faithfully reproduce features of a few micrometers and larger in dimension.

Surface plasmon resonance due to the interface of a metal and a chiral sculptured thin film

Multiple surface plasmon resonances are experimentally observed for p-polarized as well as s-polarized incident light at the planar interface of a metal and a chiral sculptured thin film. These experimental results confirm that four surface plasmon resonances can be supported at the interface of metal-chiral sculptured thin film. Multiple surface plasmon resonances may allow for multiple simultaneous measurements by devices that utilize surface plasmon resonance for detection.

Observation of the Dyakonov-Tamm wave.

A surface electromagnetic wave called the Dyakonov-Tamm wave has been theoretically predicted to exist at the interface of two dielectric materials at least one of which is both anisotropic and periodically nonhomogeneous. For experimental confirmation, a prism-coupled configuration was used to excite Dyakonov-Tamm waves guided by the interface of a dense thin film of magnesium fluoride and a chiral sculptured thin film of zinc selenide. The excitation was indicated by a reflection dip (with respect to the angle of incidence in the prism-coupled configuration) that is independent of the polarization state of the incident light as well as the thicknesses of both partnering materials beyond some thresholds. Applications to optical sensing and long-range on-chip communication are expected.

Solid-State Acquisition of Fingermark Topology using Dense Columnar Thin Films

Abstract:  Various vacuum techniques are employed to develop fingermarks on evidentiary items. In this work, a vacuum was used to deposit columnar thin films (CTFs) on untreated, cyanoacrylate‐fumed or dusted fingermarks on a limited selection of nonporous surfaces (microscope glass slides and evidence tape). CTF deposition was not attempted on fingermarks deposited on porous surfaces. The fingermarks were placed in a vacuum chamber with the fingermark side facing an evaporating source boat containing either chalcogenide glass or MgF2. Thermal evaporation of chalcogenide glass or MgF2 under a 1 μTorr vacuum for 30 min formed dense CTFs on fingermark ridges, capturing the topographical features. The results show that it is possible to capture fingermark topology using CTFs on selected untreated, vacuumed cyanoacrylate‐fumed or black powder–dusted nonporous surfaces. Additionally, the results suggested this might be a mechanism to help elucidate the sequence of deposition.

Detecting emerald ash borers (Agrilus planipennis) using branch traps baited with 3D-printed beetle decoys

Small visual-decoy-baited traps for the emerald ash borer (EAB), Agrilus planipennis Fairmaire (Coleoptera: Buprestidae), have been researched as an alternative to current technologies, but have relied on real beetles rather than synthetic materials. We hypothesized that visual decoys created by three-dimensional (3D) printing can provide such a substitute. Branch traps displaying decoys consisting of real EAB females or 3D-printed decoys were compared to controls without decoys. Traps of the three varieties were placed on neighboring branches along with one (Z)-3-hexen-1-ol lure per tree and checked daily. Both real and 3D-printed decoys similarly increased EAB trap captures compared to controls. The numbers of both sexes were higher on the decoy-baited traps, but the increase in male captures was more pronounced. Males were also ensnared closer to the decoys than females. Daily trap–capture patterns showed sparse activity of EAB adults before June 18, 2013 followed by a peak in captures of both males and females until June 28, 2013. Beginning at approximately July 1, 2013, there was a second peak of EAB captures, which consisted almost entirely of males caught on the decoy-baited traps. The native ash borer Agrilus subcinctus was found earlier in the season and was also significantly attracted to both the real EABs and the 3D-printed decoys compared with control traps. Four purple prism traps were also deployed concurrently and captures tallied on three different days within the season. The results demonstrate efficacy of a small, inexpensive, and fully synthetic decoy-based branch trap system for EAB.

Columnar-thin-film acquisition of fingerprint topology

Fingerprint visualization obtained from physical evidence taken from crime scenes for subsequent comparison typically requires the use of physical and chemical techniques. One physical technique to visualize or develop sebaceous fingerprints on various surfaces employs the deposition of metals such as gold and zinc thereon. We have developed a different vacuum technology: the conformal-evaporated-film-by-rotation technique to deposit dense columnar thin films (CTFs) on latent fingerprints on different types of surfaces. Sample fingerprints, acting as nonplanar substrates, deposited on different surfaces were placed in a vacuum chamber with the fingerprint side facing a boat containing an evaporant material such as chalcogenide glass. Thermal evaporation of the solid material led to the formation of a dense CTF on the fingerprint, thereby capturing the topographical texture with high resolution. Our results show that it is possible to acquire the topology of latent fingerprints on nonporous surfaces. Additionally, deposition of CTFs on overlapping fingerprints suggested ours may be a technique for elucidating the sequence of deposition of the fingerprints at the scene.

Improved conformal coatings by oblique-angle deposition for bioreplication

The conformal-evaporated-film-by-rotation (CEFR) technique, a bioreplication method to produce high-fidelity conformal coatings on biotemplates by oblique-angle deposition, was modified to improve the uniformity of coating thickness. The substrate holding the biotemplate was rocked, in addition to rotating it about an axis passing normally through it. With the compound eyes of the common blow fly as the biotemplate, quantitative comparison of coating thickness obtained by the original CEFR and the modified CEFR techniques showed the superiority of the latter.

Experimental excitation of the Dyakonov–Tamm wave in the grating-coupled configuration

The Dyakonov-Tamm wave was experimentally excited along the periodically corrugated interface of magnesium fluoride as the isotropic homogeneous partnering material and a zinc-selenide chiral sculptured thin film (STF) as the anisotropic and periodically nonhomogeneous partnering material. The total transmittance of a p-polarized 633 nm laser beam was measured as a function of the angle of incidence for several thicknesses of the chiral STF to identify those dips in total transmittance that are indicative of the excitation of a Dyakonov-Tamm wave.