Dušan Hemzal

Spectroscopic ellipsometry and polarimetry for materials and systems analysis at the nanometer scale: state-of-the-art, potential, and perspectives

This paper discusses the fundamentals, applications, potential, limitations, and future perspectives of polarized light reflection techniques for the characterization of materials and related systems and devices at the nanoscale. These techniques include spectroscopic ellipsometry, polarimetry, and reflectance anisotropy. We give an overview of the various ellipsometry strategies for the measurement and analysis of nanometric films, metal nanoparticles and nanowires, semiconductor nanocrystals, and submicron periodic structures. We show that ellipsometry is capable of more than the determination of thickness and optical properties, and it can be exploited to gain information about process control, geometry factors, anisotropy, defects, and quantum confinement effects of nanostructures.

Ultrasmooth metallic foils for growth of high quality graphene by chemical vapor deposition

Synthesis of graphene by chemical vapor deposition is a promising route for manufacturing large-scale high-quality graphene for electronic applications. The quality of the employed substrates plays a crucial role, since the surface roughness and defects alter the graphene growth and cause difficulties in the subsequent graphene transfer. Here, we report on ultrasmooth high-purity copper foils prepared by sputter deposition of Cu thin film on a SiO2/Si template, and the subsequent peeling off of the metallic layer from the template. The surface displays a low level of oxidation and contamination, and the roughness of the foil surface is generally defined by the template, and was below 0.6 nm even on a large scale. The roughness and grain size increase occurred during both the annealing of the foils, and catalytic growth of graphene from methane (≈1000 °C), but on the large scale still remained far below the roughness typical for commercial foils. The micro-Raman spectroscopy and transport measurements proved the high quality of graphene grown on such foils, and the room temperature mobility of the graphene grown on the template stripped foil was three times higher compared to that of one grown on the commercial copper foil. The presented high-quality copper foils are expected to provide large-area substrates for the production of graphene suitable for electronic applications.

Calibrating an Ultrasonic Computed Tomography System Using a Time-of-Flight Based Positioning Algorithm

This paper presents a method for geometrical and time-delay auto-calibration of an ultrasonic computed tomography (USCT) system. The algorithms used for the calibration are based on the principles similar to the global positioning system (GPS) navigation. Ultrasonic transmitters and receivers in USCT can be viewed like satellite transmitters and mobile receiver units in GPS. However, unlike in GPS, none of the positions of the transmitters or receivers in USCT are assumed to be known and all are the to-be-calibrated unknowns. The presented method is capable of calibrating the positions of all ultrasonic transducers and their individual time delays at once. No calibration phantoms are necessary.

Polarization anisotropy of the emission from type-II quantum dots

We study the polarization response of the emission from type-II GaAsSb capped InAs quantum dots. The theoretical prediction based on the calculations of the overlap integrals of the single-particle states obtained in the (k) over right arrow . (p) over right arrow framework is given. This is verified experimentally by polarization resolved photoluminescence measurements on samples with the type-II confinement. We show that the polarization anisotropy might be utilized to find the vertical position of the hole wave function and its orientation with respect to crystallographic axes of the sample. A proposition for usage in the information technology as a room temperature photonic gate operating at the communication wavelengths as well as a simple model to estimate the energy of fine-structure splitting for type-II GaAsSb capped InAs QDs are given.

Raman and interband optical spectra of epitaxial layers of the topological insulators Bi2Te3 and Bi2Se3 on BaF2 substrates

We report results of Raman and ellipsometric spectroscopy of the topological insulators Bi2Te3 and Bi2Se3 grown by molecular beam epitaxy on BaF2 (111) substrates. Surfaces and interfaces of the films are probed by Raman scattering from the front and back sides of the samples, which is possible owing to the transparent substrate. Surface modifications induced by intense illumination with exciting laser light have been detected, with excess tellurium at the surface during and after exposure. We also report data for thin epilayers containing a fractional number of unit cells and/or incomplete Bi2Te3 and Bi2Se3 quintuples. We have used spectroellipsometric measurements to obtain response functions and have derived the penetration depth of light in the 1.0–6.5 eV range.

Versatile low-pressure plasma-enhanced process for synthesis of iron and iron-based magnetic nanopowders

Using microwave low-pressure discharge, we synthesised magnetic iron-oxide nanopowder from the iron pentacarbonyl precursor. We were able to vary the size and chemical composition (especially the ratio between various iron oxides) by careful control of the process parameters. The nanoparticulate product was analysed by X-ray diffraction (XRD) and Raman spectroscopy. However, the XRD cannot reliably distinguish between the size-broadened peaks of γ-Fe2O3 (maghemite) and Fe3O4 (magnetite) due to their nearly identical crystalline structure. Hence we used a chemical method to determine the presence of Fe(II) and Fe(III) ions in the nanopowder samples. The results agree with those from the Raman spectroscopy.

Modified time-of-flight based calibration approach for ultrasonic computed tomography

In the previous paper [11], a method for geometrical and transducer-time-delay auto-calibration of an ultrasonic computed tomography (USCT) system has been described, aiming at calibration of individual ultrasonic (US) transducer positions. The present contribution describes a novel modification of the method utilizing the particular USCT system concept: the exactly known spatial relations among transducers grouped in each of the transducer array systems (TASes). The algorithms used for the calibration remain based on the principles similar to the global positioning system (GPS) navigation, however, the positions and orientations of complete TASes are calibrated, rather than individual positions of transducers. This way, the number of unknowns is substantially reduced while the number of available equations remains unchanged. Consequently, a solution substantially more robust with respect to measurement noise can be obtained based on this highly overdetermined equation system. The method is capable of calibrating the individual positions of all ultrasonic transducers via their positions in TASes as well as their individual time delays at once during sc. empty measurement, without a need for any particular arrangements, e.g. calibration phantoms.

3D simulation of diffraction in ultrasonic computed tomography

The contribution presents further results in developing the exact means for simulating the realistic situation in the USCT (ultrasonic computed tomography) imaging system, aiming both at evaluating the approximations used in the existing USCT image reconstruction methods as to their precision and also (in a longer perspective) at iterative improvement of the obtained images via continuum mechanics based feedback. The mathematical models, generalised in comparison with [1], emerging from the transparent physical background, are presented for inhomogeneous media incorporating both the object tissue and the surrounding fluid. The equations are already general enough to employ complex nonlinear phenomena in three-dimensional space; and linearised 3D simulations (giving rise to wave equation, WE) have been performed enabling first conclusions on the feasibility of this approach with respect to the available computing resources. Some of the results of the numerical solution of the WE in 3D by means of the finite-element method show in local detail the diffraction phenomena on acoustic-impedance inhomogeneities. The spatial extent of the simulations is basically limited only by the available computing resources. The hardware requirements and related practical limitations are mentioned together with a few examples of presently available results. Together with conclusions, further perspectives of this branch of the USCT research are suggested.

Simulation Checks in Ultrasonic Computed Tomography

The contribution presents some results obtained on the way to checking (and partly complementing) the standard reconstruction procedures in USCT by wave-equation based simulations. Mathematical models emerging from the transparent physical background for both the surrounding fluid and the object tissue are presented, followed by the present results of developing a realistic original finite-element- method based simulation. With respect to the need of comparison with the calibration measurements, a preliminary optimization of initial guesses to boundary conditions at the transducer array is discussed, based on a point-source model. The computational requirements of the procedures are also mentioned together with concrete examples of achieved results.

Comparison of Wave-Equation Versus Measurement-Processing Transducer Calibration for Ultrasonic Transmission Tomography

The contribution deals with the first step in using proper wave-equation based ultrasound propagation model in image reconstruction from the ultrasonic computed tomography data. Particularly, it compares the transducer calibration results obtained via direct measurement of the empty image field and consequential data processing based on a simple direct-propagation model with the simulation results obtained via solving the single-frequency wave equation under proper border conditions reflecting the realistic measurement geometry. The results show a reasonable qualitative agreement when a certain degree of phase-shifted coupling from the transmitting transducer elements to the neighbouring elements of the transducer field is admitted