Dwarika Prasad
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Featured researches published by Dwarika Prasad.
Journal of Materials Science | 2018
Akhil Saxena; Dwarika Prasad; Rajesh Haldhar
The corrosion inhibition effect of Asparagus racemosus fruits extract, a species of asparagus common throughoutxa0Nepal,xa0Sri Lanka,xa0India,xa0and thexa0Himalayas, has been examined on mild steel corrosion in 0.5xa0M H2SO4 by using weight loss measurements, potentiodynamic polarization measurements, and electrochemical impedance spectroscopy techniques. The presence of this Sarsasapogenin-containing extract decreases the corrosion rate of mild steel in acidic solution. The maximum corrosion inhibition efficiency was observed at 100xa0mgxa0L−1 inhibitor concentration in 0.5xa0M H2SO4. The adsorption of A. racemosus extract on the surface of mild steel has been investigated by using AFM study, SEM study, and absorption spectroscopic techniques. Due to the existence of heteroatoms in the main components, A. racemosus extract is considered to be a good inhibitor.
Bioelectrochemistry | 2018
Akhil Saxena; Dwarika Prasad; Rajesh Haldhar
The corrosion inhibition nature of Cuscuta reflexa fruit extract, belonging to the family of Piperaceae, has been analyzed on mild steel in 0.5u202fM H2SO4 with the help of weight loss studies, potentiodynamic polarization, and electrochemical impedance spectroscopy techniques. The C. reflexa extract contains 3‑methoxy‑3,4,5,7‑tetrahydroxy flavone, which decreases the corrosion rate of mild steel in acidic medium. The maximum corrosion inhibition efficiency was observed at 500u202fmg/L inhibitor concentration. The adsorption study of C. reflexa extract on mild steel surface has been conducted using UV, FTIR, AFM, SEM, and DFT.
Materials Chemistry Frontiers | 2018
Rajesh Haldhar; Dwarika Prasad; Akhil Saxena; Priyanka Singh
Corrosion inhibition analysis and the adsorption behaviour of Valeriana wallichii root extract for mild steel in 0.5 M H2SO4 solution has been investigated utilizing weight loss, electrochemical impendence spectroscopy (EIS), potentiodynamic polarization, SEM, AFM UV-visible spectroscopy, FT-IR, and quantum chemical calculations. Both the electrochemical and weight loss estimations indicated that the root extract of Valeriana wallichii shows excellent inhibition performance of up to 93.47% for mild steel at 500 mg L−1 concentration in 0.5 M H2SO4 solution at 298 K. Naphthoic acid, iridoid and an iridoid analogue are the major phytochemical constituents in the extract of Valeriana wallichii, which possess oxygen atoms (lone pair electrons) and π electrons that facilitate adsorption onto the metal surface. The adsorption of this extract obeys the Langmuir adsorption isotherm. Polarization investigations confirmed that the root extract of Valeriana wallichii acts as a mixed type of inhibitor. The surface studies confirm corrosion retardation in the presence of the extract due to the formation of a protective layer on the surface of mild steel.
Journal of Failure Analysis and Prevention | 2018
Akhil Saxena; Dwarika Prasad; Rajesh Haldhar
The corrosion inhibition effect of Achyranthes aspera extract has been examined on mild steel corrosion in 0.5xa0M H2SO4 by using weight loss measurements, potentiodynamic polarization measurements and electrochemical impedance spectroscopy techniques. The presence of this oleanolic acid containing extract decreases the corrosion rate of mild steel in acidic solution. The best inhibition effect of Achyranthes aspera extract for mild steel in 0.5xa0M H2SO4 was obtained at 500xa0mgxa0L−1 using electrochemical and weight loss measurements. The adsorption of Achyranthes aspera extract on the surface of mild steel has been investigated by using AFM study, SEM study and absorption spectroscopic techniques. Due to the existence of heteroatoms in the main components, Achyranthes aspera extract is considered to be a good inhibitor.
Journal of Bio- and Tribo-Corrosion | 2018
Nishant Bhardwaj; Dwarika Prasad; Rajesh Haldhar
The current investigation presents the corrosion activity of Aegle marmelos fruit extract in 0.5xa0M H2SO4 as a corrosive medium. This plant belongs to the Rutaceae family. Tafel polarization, EIS measurements along with weight loss estimations were done to check the inhibition efficiency and AFM and SEM techniques were carried out to surface investigation of exposed mild steel. Electrochemical examination and weight reduction estimation say that the fruit extract for Aegle marmelos indicates the amazing restraint adequacy up to 83.08% at 500xa0mg/L inhibitor concentration in 0.5xa0M sulphuric acid solution for mild steel at 298xa0K.Graphical Abstract
RECENT ADVANCES IN FUNDAMENTAL AND APPLIED SCIENCES: RAFAS2016 | 2017
Vishal Koundal; Rajesh Haldhar; Akhil Saxena; Dwarika Prasad
Leaves extracts of Glycyrrhiza glabra was investigated as sustainable corrosion resister of mild steel in 3.5% NaCl by using polarization measurements, UV, IR and SEM study. This plant shows good corrosion inhibition efficiency at lower concentration of inhibitor. This plant extract act as a mixed type of inhibitor and form a defensive coat on the surface of mild steel and decreases the corrosion rate. Here, our main goal to find out the corrosion barricade characters of the plant extract saturated with 3.5% NaCl.
Journal of environmental chemical engineering | 2018
Akhil Saxena; Dwarika Prasad; Rajesh Haldhar; Gurmeet Singh; Akshay Kumar
Journal of Chemical & Engineering Data | 1996
R. Vijaya Kumar; M. Anand Rao; M. Venkateshwara Rao; Y. V. L. Ravi Kumar; Dwarika Prasad
Journal of Molecular Liquids | 2018
Akhil Saxena; Dwarika Prasad; Rajesh Haldhar; Gurmeet Singh; Akshay Kumar
Journal of Chemical & Engineering Data | 1996
S. Viswanathan; M. Anand Rao; Dwarika Prasad; M. Venkateshwara Rao