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Featured researches published by E. Jijy.


Organic Letters | 2013

Palladium/Lewis Acid Mediated Domino Reaction of Pentafulvene Derived Diazabicyclic Olefins: Efficient Access to Spiropentacyclic Motif with an Indoline and Pyrazolidine Fused to Cyclopentene

S. Sarath Chand; E. Jijy; Praveen Prakash; Jan Szymoniak; P. Preethanuj; B. P. Dhanya; K. V. Radhakrishnan

A palladium/Lewis acid mediated stepwise and one-pot transformation of pentafulvene derived diazabicyclic olefins is described. The reaction offers a facile strategy for the synthesis of novel spiropentacyclic motifs with indoline and pyrazolidine fused to the cyclopentene core.


RSC Advances | 2013

Mild rhodium(I) catalyzed ring opening of cyclopropane appended spirotricyclic olefins through C–H activation of arylboronic acids

Praveen Prakash; E. Jijy; M. Shimi; P. S. Aparna; Eringathodi Suresh; K. V. Radhakrishnan

Herein we describe a ligand free rhodium(I) catalyzed stereoselective ring-opening of cyclopropane appended spirotricyclic olefins through C–H bond cleavage of boronic acid. The developed methodology leads to the formation of aromatic molecules functionalized with trans-disubstituted spiro[2.4]hept-4-ene and cyclopropane appended spirotricyclic framework via 1,4-alkyl to aryl rhodium migration.


Chemical Communications | 2013

Rhodium catalyzed oxidative coupling of salicylaldehydes with diazabicyclic olefins: a one pot strategy involving aldehyde C–H cleavage and π-allyl chemistry towards the synthesis of fused ring chromanones

E. Jijy; Praveen Prakash; M. Shimi; Petri M. Pihko; Nayana Joseph; K. V. Radhakrishnan


Chemistry: A European Journal | 2013

Palladium‐Catalyzed Skeletal Rearrangement of Spirotricyclic Olefins: A Facile One‐Pot Strategy for the Synthesis of a Novel Motif with Cyclopentene Fused to Benzofuran and Pyrazolidine

Praveen Prakash; E. Jijy; P. Preethanuj; Petri M. Pihko; Sarngadharan Sarath Chand; K. V. Radhakrishnan


Tetrahedron Letters | 2014

Rhodium(III) catalyzed synthesis of isoquinolone fused azabicycles through C–H activation of N-pivaloyloxy benzamides

Praveen Prakash; E. Jijy; P. S. Aparna; S. Viji; K. V. Radhakrishnan


Tetrahedron Letters | 2013

Rhodium(III)-catalyzed ring-opening of strained olefins through C–H activation of O-acetyl ketoximes: an efficient synthesis of trans-functionalized cyclopentenes and spiro[2.4]heptenes

E. Jijy; Praveen Prakash; M. Shimi; S. Saranya; P. Preethanuj; Petri M. Pihko; Sunil Varughese; K. V. Radhakrishnan


Tetrahedron Letters | 2014

Ruthenium catalyzed desymmetrization of diazabicyclic olefins to access heteroaryl substituted cyclopentenes through C–H activation of phenylazoles

P. S. Aparna; B. Prabha; Praveen Prakash; E. Jijy; R. Luxmi Varma; K. V. Radhakrishnan


Organic and Biomolecular Chemistry | 2014

Trapping the Lewis acid generated transient species from pentafulvene derived diazanorbornenes with ortho-functionalized aryl iodides and aliphatic alcohols

S. Sarath Chand; S. Saranya; P. Preethanuj; B. P. Dhanya; E. Jijy; Praveen Prakash; B. S. Sasidhar; Jan Szymoniak; P. V. Santhini; K. V. Radhakrishnan


Tetrahedron | 2016

An easy access to fused chromanones via rhodium catalyzed oxidative coupling of salicylaldehydes with heterobicyclic olefins

Ajesh Vijayan; Thekke Veettil Baiju; E. Jijy; Praveen Prakash; M. Shimi; Nayana Joseph; Petri M. Pihko; Sunil Varughese; K. V. Radhakrishnan


Synthesis | 2013

Synthesis of Functionalized Indanes via Palladium-Catalyzed Carboannulation of Diazabicyclic Olefins with o-Iodostyrenes

E. Jijy; Praveen Prakash; S. Saranya; Eringathodi Suresh; K. V. Radhakrishnan

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K. V. Radhakrishnan

National Institute for Interdisciplinary Science and Technology

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Praveen Prakash

National Institute for Interdisciplinary Science and Technology

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M. Shimi

National Institute for Interdisciplinary Science and Technology

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P. Preethanuj

National Institute for Interdisciplinary Science and Technology

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P. S. Aparna

National Institute for Interdisciplinary Science and Technology

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Petri M. Pihko

University of Jyväskylä

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Eringathodi Suresh

Central Salt and Marine Chemicals Research Institute

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S. Saranya

National Institute for Interdisciplinary Science and Technology

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Sunil Varughese

National Institute for Interdisciplinary Science and Technology

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B. P. Dhanya

National Institute for Interdisciplinary Science and Technology

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