E. V. Sharkov

The early Proterozoic Pechenga-Varzuga Belt: a case of Precambrian back-arc spreading

Abstract The Pechenga-Varzuga Belt (PVB) in the Kola Peninsula, Russia, comprises the western Pechenga and the eastern Imandra-Varzuga portions. These are two major asymmetric synform structures infilled with Proterozoic volcanogenic and sedimentary rocks dated between 2.45 and 1.9 Ga. Two main stages of tectonic-magmatic activity took place: (1) a ∼2.45-2.3 Ga basal siliceous high-Mg volcanic series, typical for the Sumian-Sariolian episodes; and (2) the Jutuli, Ludia and Kalevian episodes, which began ∼2.2 Ga ago. The lower level of the second sequence is made up of subaerial alkali basalts. The upper, 2.1-1.95 Ga old portions of the sequence consist of tholeiitic pillow-lavas, hyaloclastites and ferropicrite basalt flows associated with deep-water sediments such as phyllites, silicites and turbidites. The tholeiites exhibit REE distribution patterns similar to those of MORB, while the ferropicrite basalts resemble intraplate olivine basalts of continental and oceanic environments. Calc-alkaline subaerial volcanism took place along the south-western flank of the Pechenga zone. A final igneous stage is characterized by the emplacement of potassium granitic intrusions. The Main Lapland Thrust (MLT) occurs along the southern border of the Paleoproterozoic Lapland-Umba Granulite Belt, and is a narrow zone of compression, thrusting and folding accompanied by high-pressure granulite metamorphism. It is approximately coeval with the upper part of the Pechenga-Varzuga Belt, and is interpreted as representing a complementary structure, i.e. the zone of subduction of the Karelian-Belomorian craton beneath the Kola block. Thus, the upper part of the Pechenga-Varzuga Belt is considered to have originated as a back-arc basin in the rear of a zone of north-directed subduction and continent collision. It was eventually closed, with the appearance of igneous suites typical of such events. The Pechenga-Varzuga Belt-Main Lapland Thrust system thus provides an instance of an ancient (∼2.0-1.9 Ga ago) collision of lithospheric plates accompanied by back-arc spreading and then closure of the back-arc basin. The geodynamic development is similar that which occurred more recently within the Alpine-Himalayan Belt.

Early activity of the largest Cenozoic shield volcano in the circum-Mediterranean area: Mt. Karacadag, SE Turkey

Volcanic activity at Mt. Karacadag, SE Turkey, developed between ~11 and ~0.01 Ma. In this paper we investigate the oldest products (older than 2.6 Ma) that created a large volcanic plateau and a N-S aligned volcanic edifice in the form of a shield volcano. These igneous rocks are mildly alkaline to transitional olivine-clinopyroxene phyric basalts with minor hawaiites, basanites and very rare differentiated lithologies (mugearites and benmoreites). The poor correlation of major elements with MgO in these lavas is qualitatively consistent with polybaric depths of magma production, variable degrees of partial melting (from ~2 to ~10 %), heterogeneous mantle sources and differences in the fractionating crystal assemblage. Primitive mantle-normalized patterns resemble typical anorogenic magma compositions, with peaks at HFSE (Nb, Ta, Hf, Zr) and high HFSE/LILE ratios. REE contents are compatible with derivation of the basanites from a mixed garnet-spinel facies peridotite after ~2 % partial melting. Alkali basalts are compatible with higher degrees of melting (between 5 and 10 %) from the same type of source. Initial 87 Sr/ 86 Sr ratios range from 0.70349 to 0.70522 while those of 143 Nd/ 144 Nd range from 0.512853 to 0.512659. Early-stage lavas show higher 87 Sr/ 86 Sr and lower 143 Nd/ 144 Nd compared to plateau-stage lavas. The Sr-Nd isotopic variations and their relation with major and trace elements cannot be explained by AFC-like (Assimilation and Fractional Crystallization) processes involving average crustal lithologies. More likely, the Sr-Nd isotopic ratios are related to the existence of heterogeneous mantle sources with only minor involvement of AFC-like processes. The Cenozoic lavas in a 200 x 800 km area between the Karasu Valley and the Syria-Iraq-Turkey border in south-eastern Anatolia form a distinct igneous province which can be characterised on the basis of Sr-isotope signatures. The lithospheric mantle beneath this area is characterized by anomalously enriched 87 Sr/ 86 Sr compositions (up to 0.7055) as well as more isotopically depleted compositi o ns ( 87 Sr/ 86 Sr down to 0.7030).

Finds of young and ancient zircons in gabbroids of the Markov Deep, Mid-Atlantic Ridge, 5°54′–5°02.2′ N (Results of SHRIMP-II U-Pb Dating): Implication for deep geodynamics of modern oceans

Unusually ancient (ranging from ~100 to 330 and even ~2230 Ma [1, 2]) and young (~1.2‐1.4 Ma) [3]) zircons were discovered in the axial Mid-Atlantic Ridge (MAR) zone using U‐Pb dating. At first glance, finds of ancient zircons are inconsistent with the generally accepted plate tectonic model, which suggests the formation of new oceanic crust in the spreading zone of the World Ocean. However, they can be explained by specific geodynamic processes in the oceanic mantle. This paper presents results of zircon dating, which identified both ancient and young zircons in the same samples of MAR rocks.

Geochronology of Late Cenozoic Volcanism in the Area of Van Lake, Turkey: An Example of Development Dynamics for Magmatic Processes

An isotope-geochronological study has been performed to examine the products of Late Cenozoic collision volcanism on the northern coast of Van Lake, Turkey. We obtained 45 new K-Ar dates, based on which the principal time characteristics of volcanic activity in the region have been determined. The total duration of magmatic activity in the area of the northern coast of Van Lake has lasted ∼15 myr; it has had an expressed discrete nature, when periods of intense volcanic activity alternated with lasting breaks in eruptions. Four stages of Neogene-Quaternary volcanism have been identified: Middle Miocene (15.0–13.5 myr), Late Miocene (10–9 myr), Pliocene (5.8–3.7 myr), and Quaternary (1.0–0.4 Ma). The average duration of the stages has been 1–2 myr; the stages were separated from each other with periods of inactivity of approximately equal lengths (∼3 myr). For each of the Pliocene and Quaternary stages, three additional phases of volcanism have been identified, which were separated from each other with short time intervals (a few hundred thousand years). The last burst of volcanic activity in the area in question took place ∼400 ka; similar to Quaternary volcanism in general, it was not characterized by a high intensity. An important result of the studies performed was to confirm the existence of a separate Middle Miocene stage of collision volcanism for the Caucasian-Anatolian Segment of the Alpine Fold Belt. The data generated allow concluding that Neogene-Quaternary volcanism in this portion of the belt started much earlier (∼15 Ma) than assumed by the majority of the previous researchers.

Petrology and Ni-Cu-Cr-PGE Mineralization of the Largest Mafic Pluton in Europe: The Early Proterozoic Burakovsky Layered Intrusion, Karelia, Russia

The largest mafic pluton in Europe (area = 630 km2, thickness = 5 to 7 km) is the early Proterozoic (2445 ± 4 Ma; Pb-Pb) Burakovsky Layered Intrusion (BLI). It is located in the southern part of Russian Karelia, in the SE part of the Baltic Shield, within an Archean granite-greenstone terrain. The BLI is overlain by Quaternary deposits, and our present understanding of its character, composition, and internal structure is based on geophysical surveys and the nature of the rocks at depth, as sampled by diamond drill core. In order to better understand the petrogenesis of the BLI, we present geologic, petrographic, mineral-chemical, and whole-rock chemical analyses from throughout the stratigraphic sequence. The BLI is a lopolith-like body and is divided into two major units: the Layered Series (LS), which exhibits layering that is discordant to the contact, and the Border Group (BG), with layering that conforms to the contact surface. The LS constitutes most of the BLI and consists of, from bottom to top: ...

Geochronological scale and evolution of late Cenozoic magmatism within the Caucasian segment of the alpine belt

Results of the isotope-geochronological studies of the Late Cenozoic magmatism of Caucasus have been considered. The Neogene-Quaternary volcanic activity is found to have evolved during the last 15 m. y. being most intensive in the Middle-Late Pliocene. Within separate neovolcanic areas of the Caucasus region, magmatism was of a clearly discrete character when intense eruption periods interchanged with prolonged (up to several million years) times of quiet conditions. Four stages of young magmatism of the Caucasus are recognized: the Middle Miocene (15–13 Ma), the Late Miocene (9–5 Ma), the Pliocene (4.5–1.6 Ma), and the Quaternary (less than 1.5 Ma). However, for certain areas the time limits of these stages were shifted relative to each other and overlap the whole age range from the mid-Miocene to the end of the Quaternary period. Therefore, within the collision zone, the Neogene-Quaternary magmatism evolved almost continuously during almost the last 9 m. y., but in the time interval of 13–9 Ma in the Caucasian segment, volcanic activity was possibly low. No evidence of directed lateral migration of volcanic activity within the entire Caucasus region was found. At the same time, in the Lesser Caucasus the young magmatism commenced earlier (∼15 Ma), compared to the Greater Caucasus (∼8 Ma).

Zircon in gabbroids from the axial zone of the Mid-Atlantic ridge, Markov Deep, 6° N: Correlation of geochemical features with petrogenetic processes

This paper reports the results of detailed petrological-geochemical study of zircons and host rocks that were dredged from the Markov Deep area in the slow-spreading Mid-Atlantic ridge. The rocks are represented by variably cataclased gabbronorite with veinlets of oceanic plagiogranite (OPG) as well as leucocratic gabbro (primitive gabbro) and hornblende Fe-Ti oxide gabbronorite (ferrogabbro) without OPG. The studied zircons differ in morphology, inner structure, set of mineral inclusions (ingrowths), and content of trace elements. Compositional heterogeneity is also observed within individual grains. The REE distribution patterns in zircons are characterized by gentle growth from LREE to HREE, with prominent positive Ce anomaly and negative Eu anomaly, and in general fall in the range of zircons from magmatic rocks. Oceanic zircons clearly differ from continental populations in the U/Yb-Y and U/Yb-Hf discrimination diagrams, primarily, due to their lower U/Yb ratio at wide variations of Y and Hf contents. Zircons that contain inclusions of acid glass and hence, crystallized from OPG melt are relatively depleted in REE, especially HREE. This indicates that OPG was formed by partial melting of gabbro in the presence of concentrated water-salt fluid, which extracted REE from the plagiogranite melt. Zircons from gabbroids devoid of OPG inclusions have higher total REE contents than zircons from OPG. Late hydrothermal alterations of zircon are distinctly established by the formation of neogenic collomorphic (porous) texture and/or by composition of mineral inclusions and accompanied by significant enrichment in La. Heterogeneous distribution of Ti in zircon may be caused not only by a change in its crystallization temperature, but also variations in silica to titanium oxide activity ratios in the rocks during interaction with hydrothermal solution of variable acidity. A complex study of structural-morphological and geochemical features of oceanic zircons and phase composition of host rocks and inclusions provides insight into processes leading to the crystallization and subsequent evolution of this mineral in the rocks of oceanic lithosphere.

The Early Paleoproterozoic Monchegorsk layered mafite-ultramafite massif in the Kola Peninsula: Geology, petrology, and ore potential

AbstractThe Early Paleoproterozoic Monchegorsk Complex is exposed over an area of 550 km2 and comprises two layered mafite-ultramafite intrusions of different age: the Monchegorsk pluton of ultramafic and mafic rocks and the predominantly gabbroid Main Range Massif (also referred to as the Moncha-Chuna-Volch’i Tundras Massif), which are separated by a fault. Both massifs consists of intercalating cumulates (first of all, Ol ± Crt, Ol + Opx ± Crt, Opx, Opx + Pl ± Cpx, and Pl), they were produced by similar melts of siliceous high-Mg series but differ in the stratigraphy of their cumulates: while the Monchegorsk pluton is dominated by ultramafites, the Main Range Massif consists mostly of gabbroids, first of all, of gabbronorites. The complex is accompanied by PGE-Cu-Ni ore mineralization, low-sulfide Pt-Pd mineralization, and chromite mineralization. Judging from geological data and isotopic dates, the Monchegorsk Complex is a long-lived magmatic center, which evolved over a time span of 50 Myr at 2.50–2.46 Ga. The Main Range Massif is younger and likely truncates the western continuation of the Monchegorsk pluton. The complex is spatially restricted to the zone of the Middle Paleoproterozoic regional Central Kola Fault and is now tectonic collage whose rocks were variably affected by overprinted metamorphism in the course of deformations. These processes most significantly affected rocks along the peripheries of the Monchegorsk pluton in the south. These rocks were completely transformed under greenschist-facies conditions but often preserved their primary textures and structures. The processes overprinted both the marginal portions of the pluton itself and the rocks of its second phase, which are accompanied by economic low-sulfide PGE deposits. The PGE-Cu-Ni ore mineralization of the Monchegorsk Complex is genetically related to two distinct evolutionary episodes with a quiescence period in between: (1)The emplacement of large layered mafite-ultramafite intrusions at 2.5–2.45 Ga. Economic deposits of sulfide Cu-Ni ores with subordinate PGE mineralization occur within the Monchegorsk pluton, and the moderate-grade low-sulfide PGE ores are related to its second evolutionary phase (in the foothills of Vuruchuaivench and in the Moroshkovoe Lake, and Southern Sopcha areas). The primary magmatic ore mineralization is predominantly Cu-Fe-Ni sulfide with PGE bismuthides-tellurides.(2)The Monchegorsk Complex was involved in the zone of the Central Kola Fault at 2.0–1.9 Ga and was broken in a collage of tectonic blocks. The rocks were sheared along the boundaries of the blocks and were affected by overprinted metamorphism, which proceeded under greenschist-facies conditions in the structures surrounding the Monchegorsk pluton in the south. Thereby the primary PGE-Cu-Ni ore mineralization underwent metamorphic processes was recrystallized with the formation of Pt-Pd arsenides, stannides, antimonides, selenides, etc. This processes was associated with the partial redistribution of PGE with their local accumulation (up to economic concentrations), and the orebodies themselves acquired diffuse outlines. In other words, the second episode was marked by the transformation of the older primary magmatic ore mineralization.

The geochronology and origin of mantle sources for late cenozoic intraplate volcanism in the frontal part of the Arabian plate in the Karacadağ neovolcanic area of Turkey. Part 2. The results of geochemical and isotope (Sr-Nd-Pb) studies

A geochemical and isotope-geochemical (Sr-Nd-Pb) study has been carried out for the Karacadağ neovolcanic area, which is situated within the frontal part of the Arabian plate. The obtained data and the results of petrological modeling show that the petrogenesis of parental magmas in the Karacadağ neovolcanic area involved two compositionally different mantle sources; one consisted of garnet-bearing peridotites of the asthenosphere mantle and the other was spinel-bearing peridotites of the enriched subcontinental lithosphere mantle. During early stages in the evolution of the magmatic system, deep-seated asthenospheric magmas were ascending to the surface while intensively interacting with the melts that had been generated at upper mantle depths. The interaction gradually diminished, so that the later effusive rocks mostly have compositions that are similar to those of the primitive asthenospheric magmas. It is shown that a significant (up to 17–18 wt % of the mantle melt) assimilation of crustal material could take place only during the initial phases of the magmatism. Periodic replenishment of the magma chambers by primitive magmas, which resulted in an observable high degree of homogeneity in the composition of young effusive rocks, was also of importance in the petrogenesis of lavas during the evolution of volcanic activity.

Petrogenesis of the Fe-Ti intrusive complexes in the Sierra Leone region, Central Atlantic

The study of melt inclusions in Cr-spinels from melanocratic troctolites provided the first direct information on the physicochemical parameters of enriched magmatic systems that produced high-Fe and high-Ti intrusive complexes in the Sierra-Leone region (Central Atlantic, 6°N). These complexes are made up of predominating hornblende Fe-Ti oxide gabbronorites and gabbrodiorites with subordinate amount of ultramafics, diorites, quartz diorites, and trondhjemites. The study of melt inclusions and rocks showed that the majority of gabbroids of the Central Atlantic (Sierra Leone area and 15°20′ Fracture Zone) were derived from N-MORB-type melts, whereas differentiated Fe-Ti-oxide rocks were crystallized from other melts, which were preserved as inclusions in the Cr-spinels from the melanocratic troctolites of the Sierra Leone region. The ion-microprobe study of these inclusions yield direct evidence on the elevated water content (up to 1.24–1.77 wt %) in the parental melts of Fe-Ti oxide rocks. Data on trace and rare-earth element distribution together with high (La/Sm)N and (Ce/Yb)N ratios in the inclusions indicate the possible influence of deep plume source on the generation of these magmas. Simulation based on melt inclusion data testifies that high-Fe intrusions of the Sierra Leone area were crystallized from the water-saturated magmas at relatively low temperatures (1020–1240°C). It was shown that the geochemically enriched Fe-Ti melts were presumably formed regardless of N-MORB-type magmatism predominant in Central Atlantic, under the influence of new mantle plume that caused melting of hydrated oceanic lithosphere.